Current collector for secondary battery and electrode using same
The present invention relates to a battery technology, and more particularly, to a current collector that may be widely used in secondary batteries and an electrode employing the same. The current collector includes a conductive fiber layer including a plurality of conductive fibers. Each of the conductive fibers includes a conductive core consisting of a plurality of metal filaments; and a conductive binder matrix surrounding the outer circumferential surfaces of the conductive core.
1. A current collector for a secondary battery comprising a conductive fiber layer, the conductive fiber layer comprising a conductive network formed from a plurality of conductive fibers and a plurality of auxiliary filaments:
wherein each of the conductive fibers is a composite fiber of core-sheath structure comprising a conductive core comprised of a plurality of long metal filaments and a sheath comprised of a conductive binder matrix surrounding the core, and
wherein the auxiliary filaments are short metal filaments having lengths of about 1% to about 50% lengths of the long metal filaments and are bare metal filaments without a conductive binder matrix.
2. The current collector of claim 1 , wherein the conductive fiber layer further comprises a non-woven fabric structure including pores formed from a surface of the conductive fiber layer to an interior of the conductive fiber layer.
3. The current collector of claim 1 , further comprising a substrate combined with a surface of the conductive fiber layer.
4. The current collector of claim 3 , wherein the substrate is combined with the conductive fiber layer via fusion of the conductive binder matrix.
5. The current collector of claim 3 , wherein the substrate comprises a metal foil, a mesh, a polymer resin-based insulation film, a metal thin-film layer, or a stacked structure thereof.
6. The current collector of claim 1 , wherein the long metal filaments comprise a stainless steel, aluminum, nickel, copper, titanium, platinum, gold, silver, ruthenium, tantalum, niobium, hafnium, zirconium, vanadium, indium, cobalt, tungsten, tin, beryllium, molybdenum, an alloy thereof, or a stacked structure thereof.
7. The current collector of claim 1 , wherein the conductive binder matrix is coated onto each of the conductive cores.
8. The current collector of claim 1 , wherein the auxiliary filaments comprise a stainless steel, aluminum, nickel, copper, titanium, platinum, gold, silver, ruthenium, tantalum, niobium, hafnium, zirconium, vanadium, indium, cobalt, tungsten, tin, beryllium, molybdenum, an alloy thereof, or a stacked structure thereof.
9. The current collector of claim 8 , wherein the conductive binder matrix comprises polyaniline, polyoxyphenylene, polyphenylene sulfide, polythiophene, polyfuran, polypyrrole, polymethylpyrrole, polystyrene, a derivative thereof, or a copolymer thereof.
10. The current collector of claim 1 , wherein the conductive binder matrix is a mixed composition of a polymer binder material and a conductive material dispersed in the polymer binder material.
11. The current collector of claim 10 , wherein the polymer binder material comprises carboxy methyl cellulose (CMC), polybutadiene, polyisoprene, polybutyl acrylate, polybutyl methacrylate, polyhydroxyethyl methacrylate, polyacrylamide, polyisobutylene, isobutylene-isoprene rubber, polyvinylidenefluoride-hexafluoropropylene copolymer (PVDF-co-HFP), polyvinylidenefluoride (PVDF), polyacrylonitrile, polymethylmethacrylate, polytetrafluoroethylene (PTFE), styrenebutadiene rubber (SBR), butyl acrylate-styrene copolymer, butyl acrylate-acrylic nitrile copolymer, butyl acrylate-acrylic nitrile-glycidyl methacrylate copolymer, isobutylene-styrene copolymer, ethylene-propylene-diene copolymer: EPDM, a derivative thereof, a homopolymer thereof, a condensation polymer thereof, a copolymer thereof, a block polymer thereof, or a combination thereof.
12. The current collector of claim 10 , wherein the conductive material comprises carbon black, superfine graphite particles, acetylene black, fine carbon, a metal particle, metal indium tin oxide (ITO), carbon nanotubes, or a combination thereof.
13. The current collector of claim 1 , wherein the conductive binder matrix is gelated.
14. An electrode comprising:
a current collector for a secondary battery comprising a conductive fiber layer, the conductive fiber layer comprising a conductive network formed from a plurality of conductive fibers and a plurality of auxiliary filaments:
wherein each of the conductive fibers is a composite fiber of core-sheath structure comprising a conductive core comprised of a plurality of long metal filaments and a sheath comprised of a conductive binder matrix surrounding the core, and
wherein the auxiliary filaments are short metal filaments having lengths of about 1% to about 50% lengths of the long metal filaments and are bare metal filaments without a conductive binder matrix.
15. The electrode of claim 14 , wherein a thickness of the conductive binder matrix is from about 10% to about 90% of an average particle size of the electrically active material.
16. The electrode of claim 14 , wherein the conductive binder matrix is gelated.
17. The electrode of claim 14 , wherein the conductive fiber layer further comprises a non-woven fabric structure.
18. The electrode of claim 17 , wherein the non-woven fabric structure includes pores formed from a surface of the conductive fiber layer to an interior of the conductive fiber layer.
19. The current collector of claim 1 , wherein the conductive fibers constitute a skeleton structure of the conductive fiber layer and determine overall conductivity and a mechanical strength of the current collector and the auxiliary filaments determine internal resistance of a battery by improving electron transferring paths between an electrically active material and the metal filaments or electrical connections between the conductive fibers.