IP Library Granted Patent US 10,174,196
Granted Patent B2
US 10,174,196 · App. 15/651,583 · Granted Jan 8, 2019

Resin composition and molded article

Inventor: Toru Yamaguchi (Tokyo, JP)
Assignee: ASAHI KASEI KABUSHIKI KAISHA
C08L71/123C08J5/00C08L71/12C08L91/00C08J2371/12C08J2409/06C08J2425/06C08L25/06C08L2201/02C08L2205/03F21S41/37F21S41/50
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Quick Facts
Patent No.
US 10,174,196
App. No.
15/651,583
Granted
Jan 8, 2019
Kind
B2
Abstract

A resin composition contains: 60 to 95% by mass of polyphenylene ether (A); 35 to 0% by mass of styrene-based resin (B); and 15 to 5% by mass of elastomer component (C). The component (C) is present as dispersion particles in the resin composition. The dispersion particles have a number average particle size of 0.04 to 0.25 μm.

Claims (31)

1. A molded article for a light-reflecting part comprising a resin composition comprising:

60 to 93% by mass of polyphenylene ether (A);

35 to 0% by mass of styrene-based resin (B); and

15 to 7% by mass of elastomer component (C),

wherein the composition comprising no rubber;

wherein

a reduced viscosity of the polyphenylene ether (A), measured in a 0.5 g/dl solution under a temperature condition of 30° C. using a chloroform solvent, is 0.25 to 0.45 dl/g;

the styrene-based resin (B) is a non-rubber-reinforced styrene-based resin;

the elastomer component (C) comprises a block copolymer having a styrene block and a hydrogenated conjugated diene compound block, and has a hydrogen addition rate of 50% or more;

the elastomer component (C) is present as dispersion particles in the resin composition; and

the dispersion particles have a number average particle size of 0.04 to 0.25 μm; and the dispersion particles having a particle size of greater than 1.0 μm are not present and the number of the dispersion particles having a particle size of 0.5 to 1.0 μm is 3 or less in an area corresponding to 396 μm 2 as measured by transmission electron microscopy.

2. The molded article for the light-reflecting part according to claim 1 , wherein the elastomer component (C) comprises an oil-extended styrene block-hydrogenated conjugated diene compound block copolymer.

3. The molded article for the light-reflecting part according to claim 2 , wherein the elastomer component (C) comprises an oil-extended styrene block-hydrogenated conjugated diene compound block copolymer having an oil-extended amount of 20 to 50% by mass.

4. The molded article for the light-reflecting part according to claim 2 , wherein the elastomer component (C) comprises the oil-extended styrene block-hydrogenated conjugated diene compound block copolymer having an oil-extended amount of 20 to 50% by mass and an olefin-based elastomer in a mass ratio of (the oil-extended styrene block -hydrogenated conjugated diene compound block copolymer having an oil-extended amount of 20 to 50% by mass : the olefin-based elastomer) =9:1 to 3:7.

5. The molded article for the light-reflecting part according to claim 2 , wherein the resin composition comprises 15 to 100 parts by mass of an oil based on 100 parts by mass of the styrene block-hydrogenated conjugated diene compound block copolymer.

6. The resin composition according to claim 1 , wherein the component (C) comprises a styrene block-hydrogenated conjugated diene compound block copolymer and/or an oil-extended styrene block-hydrogenated conjugated diene compound block copolymer and an olefin-based elastomer in a mass ratio of (the styrene block-hydrogenated conjugated diene compound block copolymer and/or the oil-extended styrene block-hydrogenated conjugated diene compound block copolymer/the olefin-based elastomer) =9:1 to 3:7, and

the resin composition comprises 15 to 100 parts by mass of an oil based on 100 parts by mass of the styrene block-hydrogenated conjugated diene compound block copolymer.

7. A molded article for an automotive lamp extension comprising a resin composition comprising:

60 to 93% by mass of polyphenylene ether (A);

35 to 0% by mass of styrene-based resin (B); and

15 to 7% by mass of elastomer component (C),

wherein the composition comprising no rubber;

wherein

a reduced viscosity of the polyphenylene ether (A), measured in a 0.5 g/dl solution under a temperature condition of 30° C. using a chloroform solvent, is 0.25 to 0.45 dl/g;

the styrene-based resin (B) is a non-rubber-reinforced styrene-based resin;

the elastomer component (C) comprises a block copolymer having a styrene block and a hydrogenated conjugated diene compound block;

the elastomer component (C) is present as dispersion particles in the resin composition; and

the dispersion particles have a number average particle size of 0.04 to 0.25 μm; and the dispersion particles having a particle size of greater than 1.0 μm are not present and the number of the dispersion particles having a particle size of 0.5 to 1.0 μm is 3 or less in an area corresponding to 396 μm 2 as measured by transmission electron microscopy.

8. The molded article for the light-reflecting part according to claim 2 , wherein the component (C) comprises a styrene block-hydrogenated conjugated diene compound block copolymer and/or an oil-extended styrene block-hydrogenated conjugated diene compound block copolymer and an olefin-based elastomer in a mass ratio of (the styrene block-hydrogenated conjugated diene compound block copolymer and/or the oil-extended styrene block-hydrogenated conjugated diene compound block copolymer/the olefin-based elastomer) =9:1 to 3:7, and

the resin composition comprises 15 to 100 parts by mass of an oil based on 100 parts by mass of the styrene block-hydrogenated conjugated diene compound block copolymer.

9. The molded article for the automotive lamp extension according to claim 8 , wherein the elastomer component (C) comprises an oil-extended styrene block-hydrogenated conjugated diene compound block copolymer.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE'S ADDRESS PREVIOUSLY RECORDED AT REEL: 046772 FRAME: 0843. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Oct 15, 2018
From: ASAHI KASEI CHEMICALS CORPORATION
To: ASAHI KASEI KABUSHIKI KAISHA
Reel/Frame 047231/0112 →
MERGER Recorded Aug 10, 2018
From: ASAHI KASEI CHEMICALS CORPORATION
To: ASAHI KASEI KABUSHIKI KAISHA
Reel/Frame 046772/0843 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2017
From: YAMAGUCHI, TORU
To: ASAHI KASEI CHEMICALS CORPORATION
Reel/Frame 043032/0675 →
Priority Claims (1)
JP 2013-086736 · Apr 17, 2013 · national
Continuity (3)
Continuation 15380103 · Dec 15, 2016
Division 14783122
Related Publication 20170313877A1 · Nov 2, 2017