Smart optical materials, formulations, methods, uses, articles, and devices

1. An optical device that is configured with a smart optical material that is opaque according to the Opaqueness Test Method 1 at a temperature less than 30 degrees Celsius (° C.) and optically transparent at a temperature of from 80° to 200° C. and the smart optical material has an elongation-at-break, according to the Elongation-at-Break Test Method, before thermal aging at day 0 of at least 15% and after thermal aging in air at 200° C. for 7 days at day 7 of at least 12% and the elongation-at-break of the thermally aged smart optical material would decrease from day 0 to day 7 by less than 50%; the device comprising a light emitting element; a heat generating element, which may be the same as or different than the light emitting element and which is in thermal communication with the smart optical material; a wavelength converter in independent optical communication with the light emitting element and the smart optical material; and the smart optical material, which hides the wavelength converter when the smart optical material is at a temperature less than 30° C. and transmits light from the light emitting element and/or from the wavelength converter when the smart optical material is at a temperature from 80° to 200° C.

2. The optical device of claim 1 wherein the optical device comprises a wavelength converter comprising at least one wavelength converting element or a wavelength converting layer comprising a plurality of wavelength converting elements.

3. The optical device of claim 1 wherein the wavelength converter comprises a phosphor or a phosphor layer comprising a plurality of phosphors.

4. The optical device of claim 1 wherein the light emitting element is a light emitting diode (LED).

5. The optical device of claim 1 further comprising a power supply and thereby having an unpowered off-state and a powered on-state such that in the powered on-state the smart optical material is heated to a temperature of from 80° to 200° C.

6. A method of blocking and/or transmitting light using the optical device of claim 1 , the method comprising:

Exposing the optical device to visible light when the smart optical material is at a temperature of from −40° to 30° C. such that the smart optical material blocks enough visible light from reaching the wavelength converter and/or blocks enough converted light from the wavelength converter from exiting the optical device so as to hide the wavelength converter; or

Powering the optical device when the smart optical material is at a temperature of at least 80° C. such that the light emitting element is emitting light at a first wavelength, which is then transmitted to the wavelength converter, which responsively emits a light at a second wavelength, which is transmitted through at least a portion of the smart optical material to a light receiver, wherein the first wavelength is different than the second wavelength; or

Performing both the exposing and powering steps at different times.

7. A smart optical material as described in claim 1 .

8. The smart optical material of claim 7 comprising a first composition of a thermo-optical matrix and a second composition of an athermo-optical filler as a finely divided solid particulate that is dispersed in the thermo-optical matrix at a loading of from >5 to 40 weight percent (wt %) based on total weight of the smart optical material; wherein the athermo-optical filler is a treated particulate filler that has been prepared by treating an untreated particulate filler with a filler treating agent, wherein the athermo-optical filler has an average particle size (diameter) of from >8 nm to 500 nm, with the proviso that when the athermo-optical filler comprises treated silica, it is at least 50% equivalent of a treated precipitated silica or a treated fumed silica; wherein the first composition of the thermo-optical matrix has a thermo-optic coefficient, (dn/dT) M , and the second composition of the athermo-optical filler has a thermo-optic coefficient, (dn/dT) F , and the first and second compositions are mismatched such that the ratio (dn/dT) M /(dn/dT) F is from >2 to 20; and wherein the first composition of the thermo-optical matrix has at 23 degrees Celsius (° C.) using light at 633 nm a refractive index, n 23/q M , and the second composition of the athermo-optical filler has at 23° C. using light at 633 nm a refractive index, n 23/q F , and the first and second compositions are mismatched such that n 23/q M -n 23/q F ≥0.020 and the ratio n 23/q M /n 23/q F is from 1.009 to 1.094; and therefore for the second composition of the athermo-optical filler having known values of n 23/q F and (dn/dT)F, the first composition of the thermo-optical matrix is formulated to have a mismatched value for n 23/q M having a predetermined difference greater than n 23/q F such that when a test sample of the smart optical material is at 25° C. and has a thickness of 5.0 millimeters (mm), the smart optical material is opaque to light at wavelength 600 nanometers (nm) according to the Opaqueness Test Method 1 and when the test sample of the smart optical material is at an elevated temperature, T Z , of 80° to 200° C., the thermo-optical matrix has a refractive index, n z/q M , and the athermo-optical filler has a refractive index, n z/q F , and n z/q M and n z/q F are matched such that the ratio n z/q M /n z/q F is 1.000±0.008 and the smart optical material is optically transparent to light at wavelength 600 nm; and with the proviso that the smart optical material does not contain an untreated silica.

9. The smart optical material of claim 8 :

wherein the thermo-optical matrix comprises an organic polymer having n 23/q M of 1.470 to 1.54 and the athermo-optical filler comprises a treated precipitated or treated fumed silica having n 23/q F of 1.450 to 1.465 and an average particle size from 8.5 to 300 nm; or

wherein the thermo-optical matrix comprises a poly(vinyl acetate) having n 23/q M of 1.470 to 1.54 and the athermo-optical filler comprises a treated precipitated silica or a treated fumed silica having n 23/q F of 1.450 to 1.465 and an average particle size from 8.5 to 300 nm.

10. The smart optical material of claim 8 :

wherein the thermo-optical matrix is a Si-aryl and Si-alkyl functional poly(organosiloxane) that has n 23/q M of 1.475 to 1.55; or

wherein the athermo-optical filler comprises a treated precipitated silica or a treated fumed silica having n 23/q F of 1.450 to 1.465 and an average particle size from 8.5 to 300 nm; or

wherein the loading of athermo-optical filler is from >5 to 35 wt % based on total weight of the smart optical material;

wherein the ratio n 23/q M /n 23/q F is from 1.010 to 1.090; or

wherein the ratio (dn/dT) M /(dn/dT) F is from >2 to 20; or

wherein T Z is from 100° to 200° C.; or

wherein the thermo-optical matrix is a Si-aryl and Si-alkyl functional poly(organosiloxane) that has n 23/q M of 1.475 to 1.55; the athermo-optical filler comprises a treated precipitated silica or a treated fumed silica having n 23/q F of 1.450 to 1.465 and an average particle size from greater than 8.5 to 300 nm; the loading of from >5 to 35 wt % based on total weight of the smart optical material; the ratio n 23/q M /n 23/q F is from 1.010 to 1.090; the ratio (dn/dT) M /(dn/dT) F is from >2 to 20; and T Z is from 100° to 200° C.

11. The smart optical material of claim 10 wherein the Si-aryl and Si-alkyl functional poly(organosiloxane) of the thermo-optical matrix is represented by the general formula (I): R n Si (4-n)/2 (I), wherein subscript n is 1 or 2 and each R independently is (C 6 -C 12 )aryl or (C 1 -C 12 )alkyl, with the proviso that at least some R is the (C 6 -C 12 )aryl and at least some R is the (C 1 -C 12 )alkyl.

12. The smart optical material of claim 10 :

wherein the thermo-optical matrix is a Si-phenyl and Si-methyl functional poly(organosiloxane) that has n 23/q M of 1.475 to 1.54 and (dn/dT) M is from −2.5×10 −4 /Kelvin to −5×10 −4 /Kelvin; or

wherein the athermo-optical filler comprises a treated fumed silica having n 23/q F of 1.450 to 1.465, an average particle size from 9 to 300 nm, and (dn/dT) F of from −1.5×10 −5 /Kelvin to +1.5×10 −5 /Kelvin; or

wherein the loading of athermo-optical filler is from >5 to 30 wt % based on total weight of the smart optical material; or

wherein the ratio n 23/q M /n 23/q F is from 1.020 to 1.050; or

wherein the ratio (dn/dT) M /(dn/dT) F is from >2 to 10; or

wherein T Z is from 120° to 200° C.; or

wherein the thermo-optical matrix is a Si-phenyl and Si-methyl functional poly(organosiloxane) that has n 23/q M of 1.475 to 1.54 and (dn/dT) M of from −2.5×10 −4 /Kelvin to −5×10 −4 /Kelvin; the athermo-optical filler comprises a treated fumed silica having n 23/q F of 1.450 to 1.465, an average particle size from 9 to 300 nm, and (dn/dT) F of from 0.5×10 −5 /Kelvin to 2×10 −5 /Kelvin; the loading of from >5 to 30 wt % based on total weight of the smart optical material; the ratio n 23/q M /n 23/q F is from 1.020 to 1.050; the ratio (dn/dT) M /(dn/dT) F is from >2 to 10; and T Z is from 120° to 200° C.

13. The smart optical material of claim 10 comprising a reaction product of hydrosilylation curing a curable organosiloxane composition comprising constituents (A)-(D): (A) a Si-aryl and Si-alkyl functional organopolysiloxane containing an average, per molecule, of at least two silicon-bonded alkenyl groups; (B) a Si-aryl and/or Si-alkyl functional organosilicon compound containing an average of at least two silicon-bonded hydrogen atoms per molecule; (C) a hydrosilylation catalyst; and (D) the athermo-optical filler; wherein the athermo-optical filler is pre-formed prior to being contacted with constituents (A) to (C); wherein the athermo-optical filler is at a concentration from 1 to 45 weight percent (wt %) based on total weight of the curable organosiloxane composition.

14. A method of making the smart optical material of claim 7 , the method comprising subjecting a curable formulation comprising a uniform mixture of the athermo-optical filler widely dispersed in a mixture of two or more matrix-forming precursors to a curing condition sufficient to convert the matrix-forming precursors to the thermo-optical matrix, and thereby make the smart optical material.

15. A lens comprising the smart optical material of claim 7 configured in a shape for converging or diverging light rays.