Condensation-curable silicone resin composition sheet, method of manufacturing condensation-curable silicone resin composition sheet, and method of manufacturing light-emitting apparatus
The present invention provides a condensation-curable silicone resin composition sheet that is in a plastic solid state or a semi-solid state at ordinary temperature, including: (A) organopolysiloxane having a weight average molecular weight of 5,000 or more and 1,000,000 or less in terms of polystyrene shown by the following formula (1): (R 1 3 SiO 1/2 ) a′ (R 1 2 SiO 2/2 ) b′ (R 2 SiO 3/2 ) c′ (SiO 4/2 ) d′ (OR 3 ) e′ (1); together with (B) organopolysiloxane having a molecular weight of 10,000 or more and 1,000,000 or less in terms of polystyrene shown by the following formula (2): (R 1 3 SiO 1/2 ) a (R 1 2 SiO 2/2 ) b (R 2 SiO 3/2 ) c (SiO 4/2 ) d (OR 3 ) e (HSi(OR 3 ) 2 O 1/2 ) f (2) in an amount of 5 to 100 parts by mass based on 100 parts by mass of the component (A). This condensation-curable silicone resin composition sheet is easy to be handled and has high heat resistance and ultraviolet light resistance while being excel in curing characteristics.
1. A condensation-curable silicone resin composition sheet, comprising:
(A) organopolysiloxane having a weight average molecular weight of 5,000 or more and 1,000,000 or less in terms of polystyrene and being in a plastic solid state or a semi-solid state at ordinary temperature, with the molecule having at least two silicon atom-bonded alkoxy groups or silicon atom-bonded hydroxy groups, shown by the following formula (1):
(R 1 3 SiO 1/2 ) a′ (R 1 2 SiO 2/2 ) b′ (R 2 SiO 3/2 ) c′ (SiO 4/2 ) d′ (OR 3 ) e′ (1)
wherein each R 1 independently represents a hydrogen atom, a monovalent aliphatic hydrocarbon group having 1 to 6 carbon atoms, or an aromatic hydrocarbon group having 6 to 12 carbon atoms; R 2 represents a monovalent aliphatic hydrocarbon group having 1 to 6 carbon atoms or an aromatic hydrocarbon group having 6 to 12 carbon atoms; R 3 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxyalkyl group having 2 to 6 carbon atoms; each of “a′”, “b′”, “c′”, and “d′” is an integer of 0 or more; “e′” is an integer of 2 or more; and b′+c′+d′ is an integer of 1 or more; and
(B) organopolysiloxane having a molecular weight of 10,000 or more and 1,000,000 or less in terms of polystyrene, with the molecule having at least two silicon atoms, each of which has one hydrogen atom and two alkoxy groups or hydroxy groups, shown by the following formula (2):
(R 1 3 SiO 1/2 ) a (R 1 2 SiO 2/2 ) b (R 2 SiO 3/2 ) c (SiO 4/2 ) d (OR 3 ) e (HSi(OR 3 ) 2 O 1/2 ) f (2)
wherein, R 1 , R 2 and R 3 have the same meanings as described above, each of “a”, “b”, “c”, “d”, and “e” is an integer of 0 or more; c+d is an integer of 2 or more; and “f” is an integer of 2 or more;
wherein the condensation-curable silicone resin composition sheet is in a plastic solid state or a semi-solid state at ordinary temperature and comprises the component (B) in an amount of 5 to 100 parts by mass based on 100 parts by mass of the component (A).
2. The condensation-curable silicone resin composition sheet according to claim 1 , further comprising a fluorescent substance as a component (C).
3. The condensation-curable silicone resin composition sheet according to claim 2 , wherein the content of the component (C) is 0.1 to 1,000 parts by mass with respect to 100 parts by mass of a sum total of the component (A) and the component (B).
4. The condensation-curable silicone resin composition sheet according to claim 2 , wherein the component (C) has an average particle diameter of 1 to 50 μm.
5. The condensation-curable silicone resin composition sheet according to claim 3 , wherein the component (C) has an average particle diameter of 1 to 50 μm.