High strength and high toughness magnesium alloy and method of producing the same
View Patent ↗A high strength and high toughness magnesium alloy, characterized in that it is a plastically worked product produced by a method comprising preparing a magnesium alloy cast product containing a atomic % of Zn, b atomic % of Y, a and b satisfying the following formulae (1) to (3), and the balance amount of Mg, subjecting the magnesium alloy cast product to a plastic working to form a preliminary plastically worked product, and subjecting the preliminary plastically worked product to a heat treatment, and it has a hcp structure magnesium phase and a long period stacking structure phase at an ordinary temperature; (1) 0.5≤a<5.0 (2) 0.5<b<5.0 (3) ⅔a−⅚≤b.
1. A method of producing a high strength and high toughness magnesium alloy comprising:
preparing a magnesium alloy casting product comprising “a” atomic % of Zn, “b” atomic % of Y and a residue of Mg, wherein “a” and “b” satisfy the following expressions (1) to (3),
(1) 0.5≤a≤5.0;
(2) 0.5<b<5.0; and
(3) ⅔a−⅚≤b,
casting the magnesium alloy casting product having a cooling rate at the casting of 1000K/second or less, and
producing a plastically worked product by subjecting the magnesium alloy casting product to plastic working, wherein an amount of strain per one working is 0.002 to 4.6 and a total amount of strain is 1.15 or more and 15 or less;
to obtain the high strength and high toughness magnesium alloy having a hcp structured magnesium phase, a long period stacking ordered structure phase, and at least one precipitate selected from the group consisting of a compound of Mg and rare-earth element, a compound of Mg and Zn, a compound of Zn and rare-earth element and a compound of Mg, Zn and rare-earth element.
2. The method of producing a high strength and high toughness magnesium alloy according to claim 1 , wherein Mg contains larger than 0 atomic % to 2.5 atomic % or less, in a total amount, of at least one element selected from the group consisting of Al, Th, Ca, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B, C, Sn, Au, Ba, Ge, Bi, Ga, In, Ir, Li, Pd, Sb and V.
3. The method of producing a high strength and high toughness magnesium alloy according to claim 1 , wherein the plastic working is carried out by at least one process selected from the group consisting of a rolling, a extrusion, an Equal Channel Angular Extrusion (ECAE) working, a drawing, a forging, a press, a form rolling, a bending, a Friction Stir Welding (FSW) working and a cyclic working of the workings.
4. The method of producing a high strength and high toughness magnesium alloy according to claim 1 , wherein a total strain amount when the plastic working is carried out is 2.3 or more and 15 or less.
5. The method of producing a high strength and high toughness magnesium alloy according to claim 1 , wherein a total strain amount when the plastic working is carried out is 4 or more and 10 or less.
6. The method of producing a high strength and high toughness magnesium alloy according to claim 1 , further comprising heat-treating the plastically worked product after producing the plastically worked product.
7. The method of producing a high strength and high toughness magnesium alloy according to claim 6 , wherein the heat-treating is carried out under a condition of a temperature of 200° C. to less than 500° C. and a treating period of 10 minutes to less than 24 hours.