Vacuum-assisted in-needle capplicary adsorption trap with multiwalled polyaniline/carbon nanotube nanocomposite sorbent
A vacuum-assisted in-needle capillary adsorption trap (VA-INCAT) device for sampling and delivering materials to an analytical device is disclosed. A sorbent is multiwall carbon nanotube/polyaniline (PANI/MWCNT) nanocomposite and is coated within an interior space of the needle between the second end and the side aperture to entrap an analyte within a sample. The VA-INCAT device also includes a vacuum device configured to vacuum the vacuum flask to improve the extraction of the analytes vapors from the sample matrix to the sorbent bed.
1. A vacuum-assisted in-needle capillary adsorption trap (VA-INACT) system comprising:
a first needle including a first end and a second end and a side aperture positioned between the first end and the second end, and the side aperture being configured to provide access to an interior space of the needle;
a second needle placed adjacent to the first needle and including a first end and a second end;
a sorbent coated between the second end and the side aperture within the interior space of the first needle and configured to entrap an analyte attached to a sample placed within a sample vial;
a vacuum flask including a first opening and a second opening and configured to house the sample vial;
a first cover configured to cover an opening of the sample vial;
a second cover configured to cover the first opening of vacuum flask and including three apertures, a first of the three apertures configured to receive the first needle within an interior space of the extraction vial, a second of the three apertures configured to receive the second needle within the interior space of the extraction vial, and a third of the three apertures configured to receive a wire for opening the first cover of the sample vial;
a peristaltic pump including an inlet and an outlet respectively coupled to the second ends of the first and second needles and configured to circulate the extracted analyte though the first needle and the second needle to improve analyte adsorption on the sorbent inside the first needle; and
a vacuum device configured to evacuate the interior space of the vacuum flask and improve the efficiency of the extracting the analyte, wherein:
the vacuum device includes a valve, a vacuum trap and a vacuum pump,
the vacuum flask is coupled to the vacuum trap via a connection tube,
the connection tube connect the vacuum trap to the second opening of the vacuum flask,
the vacuum pump is in communication with the vacuum trap and the vacuum flask and is configured to provide a vacuum within the interior space of the vacuum flask, and
the valve configured to operate between an open position and a closed position, wherein in the closed position the valve disables the communication between the vacuum pump and the vacuum flask and in the open position the valve enables the communication between the vacuum pump and the vacuum flask.
2. The system of claim 1 , wherein the third aperture of the three apertures in the second cover is configured to receive a mechanism for opening the first cover of the sample vial once the interior space of the vacuum flask reaches a vacuum state.
3. The system of claim 2 , wherein the second cover is configured to provide an airtight seal for the extraction vial.
4. The system of claim 3 , wherein the first and second needles are made of stainless steel.
5. The system of claim 4 , wherein the first needle is 21-G in diameter.
6. The system of claim 3 , wherein the sorbent is polyaniline/multi-wall carbon nanotube-composite.
7. The system of the claim 6 , wherein the sorbent is made by a 2-electrode electrochemical polymerization/electrophoretic deposition technique.
8. The system of the claim 7 , wherein the electrolyte is a mixture of multiwall carbon nanotube and aniline in an electrolyte.