Perovskite nanocrystalline particles and optoelectronic device using same
Provided are perovskite nanocrystalline particle and an optoelectronic device using the same. The perovskite nanocrystalline particle may include a perovskite nanocrystalline structure while being dispersible in an organic solvent. Accordingly, the perovskite nanocrystalline particle in accordance with the present invention has therein a perovskite nanocrystal having a crystalline structure in which FCC and BCC are combined; can form a lamellar structure in which an organic (or A site) plane and an inorganic plane are alternately stacked; and can show high color purity since excitons are confined to the inorganic plane.
1. A perovskite nanocrystal particle capable of being dispersible in an organic solvent and comprising a perovskite nanocrystal structure,
wherein the perovskite nanocrystal particle is an organic-inorganic-hybrid perovskite or an inorganic metal halide perovskite, and
the perovskite nanocrystal particle has a diameter greater than a Bohr exciton diameter on an area that is not affected by a quantum confinement effect.
2. The perovskite nanocrystal particle of claim 1 , wherein a light emitting body of the perovskite nanocrystal particle has a diameter of 20 nm to 30 nm.
3. The perovskite nanocrystal particle of claim 1 , wherein the organic solvent comprises a polar solvent and a non-polar solvent,
the polar solvent comprises dimethylformamide, gamma butyrolactone, N-methylpyrrolidone, dimethylsulfoxide or isopropyl alcohol, and
the non-polar solvent comprises dichloroethylene, trichlorethylene, chloroform, chlorobenzene, dichlorobenzene, styrene, xylene, toluene, or cyclohexene.
4. The perovskite nanocrystal particle of claim 1 , wherein the light-emitter has an emission wavelength of 200 nm to 1300 nm.
5. The perovskite nanocrystal particle of claim 1 , wherein the perovskite nanocrystal particle has a spherical, cylindrical, cylindroid, polyprism or two-dimensional shape.
6. The perovskite nanocrystal particle of claim 1 , wherein the perovskite nanocrystal particle has bandgap energy determined by the crystal structure without depending on the particle size.
7. The perovskite nanocrystal particle of claim 1 , wherein the perovskite nanocrystal particle has bandgap energy of 1 eV to 5 eV.
8. The perovskite nanocrystal particle of claim 1 , wherein the nanocrystal particle has a core-shell structure.
9. The perovskite nanocrystal particle of claim 1 , wherein the nanocrystal particle has a structure with a gradient composition.
10. A light emitting device comprising:
a first electrode;
a second electrode; and
a light emitting layer disposed between the first electrode and the second electrode and comprising the perovskite nanocrystal particle of claim 1 .
11. A solar cell comprising:
a first electrode;
a second electrode; and
a photoactive layer disposed between the first electrode and the second electrode and comprising the perovskite nanocrystal particle of claim 1 .
12. The perovskite nanocrystal particle of claim 1 , wherein the perovskite has a structure of ABX 3 , A 2 BX 4 , ABX 4 , or A n−1 BnX 3n+1 (where n is an integer between 2 to 6), and
the A is an organic ammonium or alkali material, the B is a metal material, the X is a halogen element.
13. The perovskite nanocrystal particle of claim 12 , wherein the organic ammonium is amidinium group ((CH(NH 2 ) 2 ), C x H 2x+1 (CNH 3 ), organic ions, (CH 3 NH 3 ) n , ((C x H 2x+1 ) n NH 3 ) n (CH 3 NH 3 ) n , R(NH 2 ) 2 (R=alkyl), (C n H 2n+1 NH 3 ) n , CF 3 NH 3 , (CF 3 NH 3 ) n , ((C x F 2x+1 ) n NH 3 ) n (CF 3 NH 3 ) n , ((C x F 2x+1 ) n NH 3 ) n , (C n F 2n+1 NH 3 ) n ) or a combination or a derivative thereof (where n is an integer equal to or greater than 1, and x is an integer equal to or greater than 1),
the alkali metal material is Na, K, Rb, Cs, or Fr or a combination thereof,
the B is a divalent transition metal, a rare earth metal, an alkali earth metal, Pb, Sn, Ge, Ga, In, Al, Sb, Bi, Po, or a combination thereof, and
the X is Cl, Br, I, or a combination thereof.
14. The perovskite nanocrystal particle of claim 1 , further comprising a plurality of organic ligands surrounding a surface of the perovskite nanocrystal particle.
15. The perovskite nanocrystal particle of claim 14 , wherein each of the organic ligands comprises alkyl halide or a carboxylic acid.
16. The perovskite nanocrystal particle of claim 14 , wherein an alkyl structure of the alkyl halide comprises acyclic alkyl having a structure of C n H 2n+1 , primary alcohol, secondary alcohol, tertiary alcohol, alkylamine, p-substituted aniline, phenyl ammonium, or fluorine ammonium, and
the carboxylic acid comprises a 4,4′-Azobis(4-cyanovaleric acid), an acetic acid, a 5-aminosalicylic acid, an acrylic acid, an L-aspentic acid, a 6-bromohexanoic acid, a bromoacetic acid, a dichloro acetic acid, an ethylenediaminetetraacetic acid, an isobutyric acid, an itaconic acid, a maleic acid, an r-maleimidobutyric acid, an L-malic acid, a 4-Nitrobenzoic acid, a 1-pyrenecarboxylic acid, or an oleic acid.
17. The perovskite nanocrystal particle of claim 1 , wherein the perovskite is a doped perovskite.
18. The perovskite nanocrystal particle of claim 17 , wherein the doped perovskite comprises a structure of ABX 3 , A 2 BX 4 , ABX 4 , or A n−1 BnX 3n+1 (where n is an integer between 2 to 6), where a portion of the A is substituted with A′, a portion of the B is substituted with B′, or a portion of the X is substituted with X′, and
the A and A′ are organic ammonium, and the B and B′ are metal materials, and X and X′ are halogen elements.
19. The perovskite nanocrystal particle of claim 18 , wherein the A and A′ are (CH 3 NH 3 ) n , ((C x H 2x+1 ) n NH 3 ) n (CH 3 NH 3 ) n , R(NH 2 ) 2 (R=alkyl), (C n H 2n+1 NH 3 ) n , CF 3 NH 3 , (CF 3 NH 3 ) n , ((C x F 2x+1 ) n NH 3 ) n (CF 3 NH 3 ) n , ((C x F 2x+1 ) n NH 3 ) n , (C n F 2n+1 NH 3 ) n or a derivative thereof (where n is an integer equal to or greater than 1, and x is an integer equal to or greater than 1),
each of the B and B′ is a divalent transition metal, a rare earth metal, an alkali earth metal, Pb, Sn, Ge, Ga, In, Al, Sb, Bi, or Po, and
the X and X′ are Cl, Br, or I.
20. The perovskite nanocrystal particle of claim 18 , wherein a ratio at which a portion of the A is substituted with A′, a portion of the B is substituted with B′, or a portion of the X is substituted with X′ is 0.1% to 5%.