High concentration low VOC liquid gibberellin
The invention relates generally to a liquid solution formulation including gibberellic acid (“GA 3 ”), gibberellin 4 (“GA 4 ”), gibberellin 4/7 (“GA 4/7 ”), or combinations thereof, and a low-volatile, organic solvent, and methods of their use. Specifically, the liquid solution formulations of the present invention are directed toward agricultural liquid solution formulations including at least one gibberellin and a low-volatile, organic solvent selected from polyethylene glycol, propylene glycol, and/or a non-polymeric glycol.
1. A non-aqueous liquid solution formulation comprising:
a) 10.5 to about 20 wt. % of at least one gibberellin selected from the group consisting of GA 3 , GA 4 , and GA 4/7 as the only gibberellins present in said non-aqueous liquid solution,
b) 69.5 to 74.9 wt. % of a low-volatile, organic solvent selected from the group consisting of at least one polyethylene glycol with a molecular weight from about 190-420;
c) 10 to about 20 wt. % of at least one non-aqueous co-solvent selected from a group of polar solvents;
d) 0 to about 5 wt. % at least one surfactant, and
e) optionally, at least one mineral,
wherein said liquid solution formulation has a low level of volatile organic chemicals such that the vapor pressure of said liquid solution formulation is greater than 0.08 mm Hg at 20° C. or said liquid solution formulation has a volatile organic chemical (VOC) emission potential of ≤25%.
2. The formulation of claim 1 , comprising about 15-20 wt. % of said at least one gibberellin and about 69.5-74.9 wt. % of said at least one polyethylene glycol.
3. The formulation of claim 2 , wherein the at least one gibberellin consists of GA 3 .
4. The formulation of claim 2 wherein polyethylene glycol has a molecular weight from about 190 to 210.
5. The formulation of claim 1 comprising about 12.5 to about 15.8 GA 3 .
6. The formulation of claim 1 wherein said at least one non-aqueous co-solvent is selected from the group consisting of ethanol, propylene glycol, hexanol, isopropanol, 3-hydoxybutyrate, 3-butyl lactate, and 2-ethylhexyl lactate.
7. The formulation of claim 1 wherein said at least one non-aqueous co-solvent have dielectric constants greater than 10 @ 20° C.
8. The formulation of claim 1 wherein said at least one non-aqueous co-solvent is selected from the group consisting of alcohols, dialkyl ketones, alkylene carbonates, alkyl esters, pyrollidones and aryl esters.
9. The formulation of claim 1 wherein said at least one surfactant is a non-ionic or anionic surfactant selected from the group consisting of carboxylates, sulfonates, natural oils, alkylamides, arylamides, alkylphenols, arylphenols, ethoxylated alcohols, polyoxygethylene, carboxylic esters, polyalkylglycol esters, anhydrosorbitols, glycol esters, carboxylic amides, monoalkanolamine, poloxyethylene fatty acid amides, polysorbates, cyclodextrins, sugar based, silicone based, polyalkylated alcohols, and alkylaryl ethoxylates.
10. The formulation of claim 1 , comprising less than 5 wt. % water.
11. The formulation of claim 1 , comprising about 12-20 wt. % of at least one gibberellin selected from the group consisting of GA 3 , GA 4 , and GA 4/7 as the only gibberellins present in said non-aqueous liquid solution.