Method for producing porous polyimide film, and porous polyimide film
There is provided a method for producing a porous polyimide film, including a first step of forming a coating film containing a polyimide precursor solution where a polyimide precursor and an organic amine compound are dissolved in an aqueous solvent, and a resin particle incapable of dissolving in the polyimide precursor solution, followed by drying of the coating film to form a coat containing the polyimide precursor and the resin particle, and a second step of heating the coat to imidize the polyimide precursor and form a polyimide film, the second step including a treatment for removing the resin particle.
1. A porous polyimide film comprising:
a polyimide film,
an uncrosslinked resin except for a polyimide resin, wherein a content of the uncrosslinked resin except for a polyimide resin is from 0.1 mass % to 5 mass % relative to the entire porous polyimide film; and
a substantially spherical vacancy.
2. The porous polyimide film as claimed in claim 1 , wherein the uncrosslinked resin except for a polyimide resin is an uncrosslinked resin soluble in a solvent incapable of dissolving the polyimide resin.
3. A method for producing a resin particle-dispersed polyimide precursor solution, comprising polymerizing a tetracarboxylic acid dianhydride and a diamine compound in a resin particle dispersion liquid wherein resin particles are dispersed in an aqueous solvent, in the presence of an organic amine compound to form a polyimide precursor.
4. The method for producing a resin particle-dispersed polyimide precursor solution as claimed in claim 3 , wherein the resin particle dispersion liquid is a dispersion liquid wherein the resin particle is granulated in the aqueous solvent.
5. The method for producing a resin particle-dispersed polyimide precursor solution as claimed in claim 3 , wherein the organic amine compound is a tertiary amine compound.
6. The method for producing a resin particle-dispersed polyimide precursor solution as claimed in claim 3 , wherein the organic amine compound is an amine compound having a nitrogen-containing heterocyclic structure.
7. A resin particle-dispersed polyimide precursor solution obtained by the production method claimed in claim 3 .