Phosphor powder and method of manufacturing the same
There is provided a phosphor powder which includes a wavelength converting material and a silica-based inorganic substance surrounding the wavelength converting material and represented by the following Formula 1, wherein a content of a hydrosilyl group (Si—H) is greater than or equal to 10 ppm by weight, based on the total weight of the silica-based inorganic substance: wherein X represents oxygen (O) or an amine group (NH), Y represents hydrogen (H), a hydroxyl group (OH), an amino group (NH 2 ), or an alkyl group containing heteroelements, and the heteroelements include at least one selected from the group consisting of phosphorus (P), nitrogen (N), sulfur (S), oxygen (O), and a halogen element.
1. A phosphor powder comprising:
a wavelength converting material; and
a silica-based inorganic substance surrounding the wavelength converting material and represented by the following Formula 1,
wherein the silica-based inorganic substance is derived from perhydropolysilazane, and
wherein a content of a hydrosilyl group (Si—H) is greater than or equal to 10 ppm by weight, based on the total weight of the silica-based inorganic substance:
wherein X represents oxygen (O) or an amine group (NH), Y represents hydrogen (H), a hydroxyl group (OH), or an amino group (NH 2 ).
2. The phosphor powder of claim 1 , wherein the content of the wavelength converting material is in a range of 0.0001 to 95% by weight, based on the total weight of the phosphor powder.
3. The phosphor powder of claim 1 , wherein the wavelength converting material comprises a lanthanide compound or a transition metal compound.
4. The phosphor powder of claim 3 , wherein each of the lanthanide compound and the transition metal compound comprises at least one selected from the group consisting of a nitrate-based compound, a carbonate-based compound, a halogen-based compound, a sulfate-based compound, an oxide-based compound, a phosphate-based compound, an acetate-based compound, an acetoacetyl-based compound, and a coordinated organic compound.
5. The phosphor powder of claim 1 , wherein the wavelength converting material comprises an organic phosphor.
6. The phosphor powder of claim 5 , wherein the organic phosphor comprises at least one selected from the group consisting of an organic monomer, a polymer of the organic monomer, and a combination thereof, and
the organic monomer comprises at least one selected from the group consisting of an aromatic hydrocarbon, an alicyclic hydrocarbon, a halogenated hydrocarbon, an ether functional group, and a terpene functional group.
7. The phosphor powder of claim 1 , wherein the wavelength converting material comprises semiconductor nanocrystals having a particle size of 2 to 40 nm.
8. The phosphor powder of claim 7 , wherein the semiconductor nanocrystals comprise at least one selected from the group consisting of CdTe/CdSe, CdS(Se)/CdTe, CdS(Se)/ZnTe, CuInS(Se)/ZnS(Se), Cu(GaIn)S(Se)/ZnS(Se), ZnTe/CdS(Se), GaSb/GaAs, GaAs/GaSb, Ge/Si, Si/Ge, PbSe/PbTe, PbTe/PbSe, CdTe, CdSe, ZnTe, CuInS 2 , CuGaS 2 , Cu(Ga,In)S 2 , CuGaSnS(Se), CuGaS(Se), CuSnS(Se), ZnS, CuInSe 2 , CuGaSe 2 , ZnSe, ZnTe, GaSb, GaAs, Ge, Si, PbSe, PbTe, and PbTe and PbSe.
9. The phosphor powder of claim 1 , wherein the wavelength converting material comprises an inorganic phosphor powder.
10. The phosphor powder of claim 9 , wherein the inorganic phosphor powder comprises at least one selected from the group consisting of oxide-based, halogen-based, nitrogen-based and silicate-based phosphor powders.
11. The phosphor powder of claim 1 , which has a spherical shape.
12. The phosphor powder of claim 1 , which has an amorphous shape.
13. The phosphor powder of claim 1 , which has a particle size of 0.01 to 500 μm.
14. The phosphor powder of claim 1 , wherein the wavelength converting material and the silica-based inorganic substance are bonded by a functionalized silane-based coupling agent.
15. The phosphor powder of claim 1 which has a surface made hydrophobic to be non-polar.