IP Library Granted Patent US 10,207,250
Granted Patent B2
US 10,207,250 · App. 15/122,095 · Granted Feb 19, 2019

Poly(meth)acrylic acid (salt)-based particulate absorbent

Inventors: Yoshitaka Ikeuchi (Himeji, JP); Yoshifumi Adachi (Himeji, JP)
Assignee: NIPPON SHOKUBAI CO., LTD.
B01J20/261A61L15/18A61L15/24A61L15/425A61L15/60B01J20/267B01J20/28004B01J20/28011B01J20/28016B01J20/28026B01J20/28045B01J20/3028B01J20/3085B01J2220/68
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Quick Facts
Patent No.
US 10,207,250
App. No.
15/122,095
Granted
Feb 19, 2019
Kind
B2
Abstract

A low cost, a disposable diaper is provided that presents no difficulties in disposable diaper manufacture in humid climates, and that has a minimal amount of flowback, and rapid absorption time. A particulate water-absorbing agent is provided having as the principal component a poly (meth)acrylic acid (salt)-based water absorbing resin, wherein the water-absorbing agent has a particle size distribution of a weight average particle diameter of 300 to 500 μm, a blocking ratio after moisture absorption when left for one hour at 25° C. and 90% relative humidity of 20% or less, a surface tension of 60 mN/m or more, and a gel capillary absorption (GCA) of 28.0 g/g or more.

Claims (20)

1. A particulate water-absorbing agent comprising a poly (meth)acrylic acid (salt)-based water-absorbing resin as a main component, wherein

the particulate water-absorbing agent has:

a weight average particle diameter (D50) of 300 to 500 μm,

a blocking ratio after moisture absorption when left for one hour at 25° C. and 90% relative humidity of 20% or less,

a surface tension of 60 mN/m or more, and

a gel capillary absorption (GCA) of 28.0 g/g or more.

2. The particulate water-absorbing agent according to claim 1 , wherein the particulate water-absorbing aunt is surface crosslinked.

3. The particulate water-absorbing agent according to claim 1 , wherein the particulate water-absorbing agent has a fluid retention capacity without pressure (CRC) of 28 g/g or more.

4. The particulate water-absorbing agent according to claim 1 , wherein the particulate water-absorbing agent has a fluid retention capacity under pressure (AAP) of 25 g/g or more.

5. The particulate water-absorbing agent according to claim 1 , wherein the particulate water-absorbing agent has a water absorption time by Vortex method of 40 seconds or less.

6. The particulate water-absorbing agent according to claim 1 , wherein the particulate water-absorbing agent has a surface tension of 65 mN/m or more.

7. The particulate water-absorbing agent according to claim 1 , wherein the particulate water-absorbing agent has a gel capillary absorption (GCA) of 30.0 g/g or more.

8. The particulate water-absorbing agent according to claim 1 , comprising water-insoluble inorganic fine particles.

9. The particulate water-absorbing agent according to claim 8 , wherein the water-insoluble inorganic fine particles content is from 0.01 to 1.0% V by weight per 100% by weight of the poly(meth)acrylic acid (salt)-based water-absorbing resin (solid content).

10. The particulate water-absorbing agent according to claim 8 , wherein the volume average particle diameter of the water-insoluble inorganic fine particles is from 0.01 to 3 μm.

11. The particulate water-absorbing agent according to claim 1 , comprising a chelating agent.

12. The particulate water-absorbing agent according to claim 11 , wherein the chelating agent content is from 0.001 to 1 part by weight per 100 parts by weight of the poly(meth)acrylic acid (salt)-based water-absorbing resin (solid content).

13. The particulate water-absorbing agent according to claim 11 , wherein the chelating agent is a compound selected from the group consisting of an organic phosphorus chelating agent and an amino carboxylic acid chelating agent.

14. The particulate water-absorbing agent according to claim 1 , wherein the shape of the water-absorbing agent is an irregularly-crushed shape or granules thereof.

15. An absorbent article formed by including the particulate water-absorbing agent according to claim 1 and a hydrophilic fiber.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 1, 2016
From: IKEUCHI, YOSHITAKA; ADACHI, YOSHIFUMI
To: NIPPON SHOKUBAI CO., LTD.
Reel/Frame 039611/0065 →
Priority Claims (1)
JP 2014-039599 · Feb 28, 2014 · national
Continuity (1)
Related Publication 20170014801A1 · Jan 19, 2017