Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.
1. An oxidant dopant agent for preparing a conductive polymer, comprising:
ferric naphthalenesulfonate; and
at least one compound selected from the group consisting of phosphate, phosphite, borate, thiophosphate, and dithiophosphate.
2. The oxidant dopant agent for preparing the conductive polymer according to claim 1 , further comprising a glycidyl group containing compound or its ring-opening compound.
3. The oxidant dopant agent for preparing the conductive polymer according to claim 1 , wherein the ferric naphthalenesulfonate has a molar ratio of iron to an organic sulfonic acid, wherein the molar ratio is lower than 1:3 in view of the organic sulfonic acid.
4. The oxidant dopant agent for preparing the conductive polymer according to claim 1 , wherein said at least one compound is contained at an amount of 1 to 100% by mass standard with respect to the ferric naphthalenesulfonate.
5. The oxidant dopant agent for preparing the conductive polymer according to claim 1 , wherein the conductive polymer obtained by using the oxidant dopant agent serves as an electrolyte of an electrolyte capacitor having a leak current of 100 μA or less.
6. The oxidant dopant agent for preparing the conductive polymer according to claim 5 , wherein the conductive polymer obtained by using the oxidant dopant agent serves as an electrolyte of an electrolyte capacitor having an ESR of 30 mΩ or less.