IP Library › Granted Patent US 10,208,269
Granted Patent B2
US 10,208,269 · App. 14/546,509 · Granted Feb 19, 2019

Low viscosity ester lubricant and method for using

Inventors: Jason Z. Gao (Rose Valley, PA); Samuel C. Bainbridge (Philadelphia, PA); Dennis A. Gaal (Glassboro, NJ); Tomasz M. Young (Philadelphia, PA)
Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
C10M169/041C10M105/32C10M105/34C10M143/04C10M145/14C10M169/048C10M2205/022C10M2205/04C10M2207/2815C10M2207/2825C10M2209/084C10N2220/022C10N2230/02C10N2230/06C10N2230/08C10N2240/10
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Quick Facts
Patent No.
US 10,208,269
App. No.
14/546,509
Granted
Feb 19, 2019
Kind
B2
Abstract

According to the present disclosure, there is provided a high-temperature lubricant composition. The composition has an amount of an ester. The ester exhibits a kinematic viscosity at 100° C. of 1 to 4 centistokes and a kinematic viscosity ratio at 150° C./100° C. of 0.6 or higher. The composition is at a temperature of 100° C. to 150° C. There is also another lubricating composition having the ester and a polymeric viscosity modifier. There are also methods for using the lubricating compositions in the crankcase of an engine.

Claims (14)

1. A high-temperature lubricant composition, comprising an amount of a monoester of 90 wt % or more of the composition based on the total weight of the composition, wherein the monoester exhibits a kinematic viscosity at 100° C. of 1 to 4 centistokes and a kinematic viscosity ratio at 150° C./100°C. of 0.6 or higher, wherein the composition is at a temperature of 100° C. to 150° C., and

wherein the monoester is selected from the group consisting of 2-ethylhexyl laurate, isobutyl stearate, isobutyl oleate, ethylhexyl isononanoate, isodecyl pelargonate, isononyl heptanoate, isononyl otanoate, isononyl isononanoate, isodecyl isononanoate, and isodecyl ethylhexanoate.

2. The composition of claim 1 , wherein the monoester exhibits an average friction coefficient of 1.0 or lower at 140° C.

3. The composition of claim 1 , wherein the monoester exhibits an average friction coefficient of 0.8 or lower at 140° C.

4. A method for improving the operating efficiency of an engine having a crankcase lubricant, wherein the lubricant composition of claim 1 is added to the crankcase.

5. A lubricant composition, comprising a polymeric viscosity modifier in an amount of 5 wt % to 10 wt % and an amount of a monoester 95 wt % to 90 wt % based on the total weight of the composition, wherein the ester exhibits a kinematic viscosity at 100° C. of 1 to 4 centistokes and a kinematic viscosity ratio at 150° C./100° C. of 0.60 or higher, wherein the amount of the polymeric viscosity modifier and the amount of the monoester are present at 90 wt % or more of the composition based on the total weight of the composition, and

wherein the monoester is selected from the group consisting of 2-ethylhexyl laurate, isobutyl stearate, isobutyl oleate, ethylhexyl isononanoate, isodecyl pelargonate, isononyl heptanoate, isononyl otanoate, isononyl isononanoate, isodecyl isononanoate, and isodecyl ethylhexanoate.

6. The composition of claim 5 , wherein the composition is at a temperature of 100° C. to 150° C.

7. The composition of claim 5 , wherein the monoester exhibits an average friction coefficient of 1.0 or lower at 140° C.

8. The composition of claim 5 , wherein the monoester exhibits an average friction coefficient of 0.8 or lower at 140° C.

9. The composition of claim 5 , wherein the polymeric viscosity modifier is selected from the group consisting of polymethacrylates, copolymers of ethylene and propylene, hydrogenated block copolymers of styrene and isoprene or of styrene and butadiene.

10. The composition of claim 5 , wherein the polymeric viscosity modifier is a polymethacrylate.

11. The composition of claim 5 , wherein the composition the combination of polymeric viscosity modifier and monoester has a kinematic viscosity ratio at 150° C./100° C. of 0.55 or higher.

12. A method for improving the operating efficiency of an engine having a crankcase lubricant, wherein the lubricant composition of claim 5 added to the crankcase.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 19, 2014
From: GAO, JASON Z.; BAINBRIDGE, SAMUEL C.; GAAL, DENNIS A.; YOUNG, TOMASZ M.
To: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Reel/Frame 034281/0748 →
Continuity (2)
Provisional Application 61919931 · Dec 23, 2013
Related Publication 20160130524A1 · May 12, 2016