Synthesis and processing of pure and NV nanodiamonds and other nanostructures
Using processes disclosed herein, materials and structures are created and used. For example, processes can include melting boron nitride or amorphous carbon into an undercooled state followed by quenching. Exemplary new materials disclosed herein can be ferromagnetic and/or harder than diamond. Materials disclosed herein may include dopants in concentrations exceeding thermodynamic solubility limits. A novel phase of solid carbon has structure different than diamond and graphite.
1. A method comprising:
depositing an amorphous carbon film on a substrate by pulsed laser deposition;
adding N 2 + ions to the deposited amorphous carbon film;
after the adding, melting a portion of the film with the added N 2 + ions into an undercooled state;
quenching the melted portion from the undercooled state to create nitrogen-vacancy (NV) doped (NV-doped) diamond having substitutional nitrogen atoms and vacancies incorporated therein.
2. The method of claim 1 , wherein the quenching includes quenching from the undercooled state to create the NV-doped diamond with NV-dopant concentrations that exceed thermodynamic solubility limits.
3. The method of claim 2 , wherein the quenching from the undercooled state to create the NV-doped diamond with NV-dopant concentrations that exceed thermodynamic solubility limits includes using solute trapping to create the NV-doped diamond with NV-dopant concentrations that exceed thermodynamic solubility limits.
4. The method of claim 1 , wherein the NV-doped diamond has transitions between NV − and NV 0 .
5. The method of claim 1 , further comprising:
configuring the substrate to deterministically place the created NV-doped diamond on the substrate.
6. The method of claim 1 , wherein the NV-doped diamond has transitions between NV − and NV 0 , and the transitions can be controlled electrically and/or optically by laser illumination.
7. The method of claim 1 , wherein the duration of the quenching is between 200-250 nanoseconds.
8. The method of claim 1 , further comprising:
epitaxially growing the created NV-doped diamond by using the substrate as a template for epitaxial growth.
9. The method of claim 1 , wherein the created NV-doped diamond is a nanodot, microcrystal, nanoneedle, microneedle, or large area single crystal film.