IP Library › Granted Patent US 10,224,201
Granted Patent B2
US 10,224,201 · App. 15/675,230 · Granted Mar 5, 2019

C-plane GaN substrate

Inventors: Kenji Iso (Tokyo, JP); Yuuki Enatsu (Tokyo, JP); Hiromitsu Kimura (Tokyo, JP)
Assignee: MITSUBISHI CHEMICAL CORPORATION
H01L21/02389C30B25/04C30B25/18C30B29/406H01L21/0254H01L21/0257H01L21/0262H01L21/02576H01L21/02609H01L21/02647
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Quick Facts
Patent No.
US 10,224,201
App. No.
15/675,230
Granted
Mar 5, 2019
Kind
B2
Abstract

Provides is a C-plane GaN substrate which, although formed from a GaN crystal grown so that surface pits are generated, is free from any inversion domain, and moreover, has a low spiral dislocation density in a gallium polar surface. Provides is a C-plane GaN substrate wherein: the substrate comprises a plurality of facet growth areas each having a closed ring outline-shape on a gallium polar surface; the spiral dislocation density is less than 1×10 6 cm −2 anywhere on the gallium polar surface; and the substrate is free from any inversion domain. The C-plane GaN substrate may comprise a high dislocation density part having a dislocation density of more than 1×10 7 cm −2 and a low dislocation density part having a dislocation density of less than 1×10 6 cm −2 on the gallium polar surface.

Claims (26)

1. A C-plane GaN substrate comprising:

a plurality of facet growth areas each having a closed ring outline-shape on a gallium polar surface, wherein

a spiral dislocation density is less than 1×10 6 cm −2 anywhere on the gallium polar surface, and

the gallium polar surface is free from any inversion domain.

2. The C-plane GaN substrate according to claim 1 , wherein the spiral dislocation density is less than 8×10 5 cm −2 anywhere on the gallium polar surface.

3. The C-plane GaN substrate according to claim 1 , wherein the substrate comprises a high dislocation density part having a dislocation density of more than 1×10 7 cm −2 and a low dislocation density part having a dislocation density of less than 1×10 6 cm −2 on the gallium polar surface.

4. The C-plane GaN substrate according to claim 3 , wherein, when the entire gallium polar surface is comparted into 100-μm square compartments, 1% or more of all the compartments each have a dislocation density of less than 1×10 5 cm −2 .

5. The C-plane GaN substrate according to claim 1 , wherein the substrate is doped with oxygen.

6. The C-plane GaN substrate according to claim 1 , wherein the substrate is doped with either or both of silicon and germanium.

7. The C-plane GaN substrate according to claim 1 , wherein the substrate has an electrical resistivity of 0.1 Ω·cm or less.

8. The C-plane GaN substrate according to claim 1 , wherein the plurality of facet growth areas are at least partially regularly arranged on the main surface.

9. A method for producing a nitride semiconductor device, comprising a step of preparing the C-plane GaN substrate according to claim 1 , and a step of epitaxially growing at least one nitride semiconductor layer on the prepared C-plane GaN substrate.

10. A method for producing an epitaxial wafer, comprising a step of preparing the C-plane GaN substrate according to claim 1 , and a step of epitaxially growing at least one nitride semiconductor layer on the prepared C-plane GaN substrate.

11. A C-plane GaN substrate having a gallium polar surface, the substrate comprising:

a plurality of facet growth areas each having a closed ring outline-shape on the gallium polar surface, wherein

when a virtual square grid of 2 cm×2 cm is drawn on the gallium polar surface, each cell of the grid comprises at least one 1 cm×1 cm square area in which a spiral dislocation density is anywhere less than 1×10 6 cm −2 , and

the gallium polar surface is free from any inversion domain.

12. The C-plane GaN substrate according to claim 11 , wherein each cell of the grid comprises at least one 1 cm×1 cm square area in which a spiral dislocation density is anywhere less than 8×10 5 cm −2 .

13. The C-plane GaN substrate according to claim 11 , wherein the substrate comprises a high dislocation density part having a dislocation density of more than 1×10 7 cm −2 and a low dislocation density area having a dislocation density of less than 1×10 6 cm −2 on the gallium polar surface.

14. The C-plane GaN substrate according to claim 13 , wherein, when the entire gallium polar surface is comparted into compartments of 100 μm-square, 1% or more of all the compartments each have a dislocation density of less than 1×10 5 cm −2 .

15. The C-plane GaN substrate according to claim 11 , wherein the substrate is doped with oxygen.

16. The C-plane GaN substrate according to claim 11 , wherein the substrate is doped with either or both of silicon and germanium.

17. The C-plane GaN substrate according to claim 11 , wherein the substrate has an electrical resistivity of 0.1 Ω·cm or less.

18. The C-plane GaN substrate according to claim 11 , wherein the plurality of facet growth areas are at least partially regularly arranged on the main surface.

19. A method for producing a nitride semiconductor device, comprising a step of preparing the C-plane GaN substrate according to claim 11 , and a step of epitaxially growing at least one nitride semiconductor layer on the prepared C-plane GaN substrate.

20. A method for producing an epitaxial wafer, comprising a step of preparing the C-plane GaN substrate according to claim 11 , and a step of epitaxially growing at least one nitride semiconductor layer on the prepared C-plane GaN substrate.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 11, 2017
From: ISO, KENJI; ENATSU, YUUKI; KIMURA, HIROMITSU
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043271/0860 →
Priority Claims (1)
JP 2015-032949 · Feb 23, 2015 · national
Continuity (2)
Continuation PCTJP2016054539 · Feb 17, 2016
Related Publication 20170338112A1 · Nov 23, 2017