Method for producing aqueous perfluoroelastomer dispersion, and method for producing perfluoroelastomer
An aqueous perfluoroelastomer dispersion and method for producing a perfluoroelastomer using a specific fluorosurfactant and capable of achieving a sufficient number of particles and a sufficient polymerization rate. The method includes providing an aqueous dispersion containing perfluoroelastomer particles by emulsion-polymerizing a perfluoromonomer in an aqueous medium in the presence of a specific fluorosurfactant in an amount of 2 parts by mass or more for 100 parts by mass of the aqueous medium.
1. A method for producing an aqueous perfluoroelastomer dispersion containing perfluoroelastomer particles, which process comprises emulsion-polymerizing a perfluoromonomer in an aqueous medium in the presence of a fluorosurfactant in an amount of 2 parts by mass or more for 100 parts by mass of the aqueous medium and represented by the following formula (1):
X—(CF 2 ) m1 —Y (1)
wherein X is H or F; m1 is an integer of 3 to 6; and Y is —SO 3 M, —SO 4 M, —SO 3 R, —SO 4 R, —COOM, —PO 3 M 2 , or —PO 4 M 2 , where M is H, NH 4 , or an alkali metal; and R is a C1-C12 alkyl group,
wherein the perfluoroelastomer has a glass transition temperature of 20° C. or lower and has a melting peak (ΔH) of 4.5 J/g or lower or no melting peak and is at least one selected from the group consisting of the following copolymer (i)-(iv):
(i) a tetrafluoroethylene (TFE)/perfluoro(methyl vinyl ether) (PMVE) copolymer wherein the composition thereof is (45 to 90)/(10 to 55) (mol %),
(ii) a copolymer of TFE/PMVE/monomer that gives a crosslinking site wherein the composition thereof is (45 to 89.9)/(10 to 54.9)/(0.01 to 4) (mol %),
(iii) a copolymer of TFE/C4-C12 fluoromonomer represented by the following formula (10) or (11) wherein the composition thereof is (50 to 90)/(10 to 50) (mol %), and
(iv) a copolymer of TFE/C4-C12 fluoromonomer represented by the following formula (10) or (11)/monomer that gives a crosslinking site wherein the composition thereof is (50 to 89.9)/(10 to 49.9)/(0.01 to 4) (mol %),
CF 2 ═CFOCF 2 ORf 101 (10)
wherein Rf 101 is a C1-C6 linear or branched perfluoroalkyl group, a C5-C6 cyclic perfluoroalkyl group, or a C2-C6 linear or branched perfluorooxyalkyl group having 1 to 3 oxygen atoms, and
CF 2 ═CFO(CF 2 CF(Y 11 )O) m (CF 2 ) n F (11)
wherein Y 11 is a fluorine atom or a trifluoromethyl group; m is an integer of 1 to 4; and n is an integer of 1 to 4; m and n are selected so that the formula (11) has a carbon number of 5-12,
wherein the emulsion polymerization is performed in the absence of a fluorine-containing compound represented by the following formula (2):
X—(CF 2 ) m2 —Y (2)
(wherein X is H or F; m2 is an integer of 7 or greater; Y is —SO 3 M, —SO 4 M, —SO 3 R, —SO 4 R, —COOM, —PO 3 M 2 , or —PO 4 M 2 (where M is H, NH 4 , or an alkali metal; and R is a C1-C12 alkyl group)).
2. The production method according to claim 1 ,
wherein the aqueous dispersion containing perfluoroelastomer particles contains 5×10 14 or more perfluoroelastomer particles per cc.
3. A method for producing a perfluoroelastomer comprising
providing a perfluoroelastomer by removing the aqueous medium from the aqueous dispersion containing perfluoroelastomer particles produced by the production method according to claim 1 .