Cathode, lithium battery including the same, and method of preparing the cathode
A cathode and method of preparing the cathode are disclosed. The cathode includes a current collector, and a cathode active material layer disposed on the current collector, wherein the current collector includes a metal substrate, and a conductive protective layer disposed on at least a portion of the metal substrate, and the conductive protective layer includes one or more of a protrusion and a recess which react with base, a lithium battery including the cathode, and a method of preparing the cathode.
1. A cathode comprising:
a current collector;
a cathode active material layer disposed on the current collector; and
a plurality of pin-holes that penetrate through the cathode active material layer, wherein the current collector comprises a metal substrate and a conductive protective layer disposed on at least a portion of the metal substrate,
wherein (i) the conductive protective layer comprises a plurality of protrusions and the plurality of recesses which react with base, (ii) the plurality of protrusions and the plurality of recesses have a predetermined pattern, (iii) the plurality of recesses are through-holes which are in contact with the metal substrate by penetrating through the conductive protective layer, and (iv) the plurality of protrusions of the conductive protective layer comprise metal.
2. The cathode of claim 1 , wherein the conductive protective layer comprises a plurality of through-holes which are in contact with the metal substrate and are disposed and spaced apart by a predetermined spacing.
3. The cathode of claim 1 , wherein the conductive protective layer comprises a non-metallic material.
4. The cathode of claim 1 , wherein the conductive protective layer comprises a carbon-based material.
5. The cathode of claim 1 , wherein the plurality of protrusions and the metal substrate comprises the same metal.
6. The cathode of claim 1 , wherein the conductive protective layer comprises a plurality of metal dots which are disposed and spaced apart by a predetermined spacing on the conductive protective layer that is formed of a carbon-based material.
7. The cathode of claim 1 , wherein the plurality of pin-holes have a predetermined pattern.
8. The cathode of claim 1 , wherein the cathode active material layer is formed from a cathode active material slurry including a cathode active material and a water-based solvent, and wherein the cathode active material slurry is basic.
9. The cathode of claim 8 , wherein the cathode active material slurry reacts with metal included in the plurality of protrusions of the conductive protective layer and metal exposed by the plurality of recesses to form a metal oxide.
10. A lithium battery comprising the cathode of claim 1 .