Electrostatic charge image developing toner
An electrostatic charge image developing toner includes toner particles including a particulate toner matrix and an external additive adhering to a surface of the particulate toner matrix. The particulate toner matrix includes a crystalline polyester resin. The external additive includes silica particles. The silica particles are secondary particles including primary particles having a diameter in the range of 30 to 90 nm. The secondary particles have an average circularity in the range of 0.25 to 0.50. The secondary particles have an average aspect ratio of 3.0 or more.
1. An electrostatic charge image developing toner comprising toner particles comprising a particulate toner matrix, and an external additive adhering to a surface of the particulate toner matrix, wherein
the particulate toner matrix comprises a crystalline polyester resin,
the external additive comprises silica particles,
the silica particles are secondary particles comprising primary particles having a diameter in the range of 30 to 90 nm,
the secondary particles have an average circularity in the range of 0.25 to 0.50, and
the secondary particles have an average aspect ratio of 3.0 or more.
2. The electrostatic charge image developing toner according to claim 1 , wherein
the particulate toner matrix has an average circularity in the range of 0.945 to 0.965.
3. The electrostatic charge image developing toner according to claim 1 , wherein
the external additive further comprises titanium oxide particles having an average aspect ratio of 3.0 or more.
4. The electrostatic charge image developing toner according to claim 3 , wherein
the titanium oxide particles have an average major axis diameter in the range of 30 to 70 nm.
5. The electrostatic charge image developing toner according to claim 1 , wherein
the silica particles have surfaces modified with silicone oil.
6. The electrostatic charge image developing toner according to claim 1 , wherein
the silica particles have surfaces modified with a trimethylsilyl group.
7. The electrostatic charge image developing toner according to claim 1 , wherein
a content of the silica particles is within the range of 2.0 to 5.0 mass % relative to 100 mass % of the particulate toner matrix.
8. The electrostatic charge image developing toner according to claim 3 , wherein
a content of the titanium oxide particles is within the range of 0.10 to 0.80 mass % relative to 100 mass % of the particulate toner matrix.
9. The electrostatic charge image developing toner according to claim 3 , wherein
the titanium oxide particles have a rutile crystal structure.
10. The electrostatic charge image developing toner according to claim 3 , wherein
the titanium oxide particles have surfaces modified with a coupling agent having a linear alkyl group having 6 to 10 carbon atoms.
11. The electrostatic charge image developing toner according to claim 3 , wherein
the titanium oxide particles have surfaces modified with an octylsilyl group.
12. The electrostatic charge image developing toner according to claim 1 , wherein
the crystalline polyester resin comprises a hybrid crystalline polyester resin prepared through chemical bond of at least a crystalline polyester polymer segment and a second polymer segment.
13. The electrostatic charge image developing toner according to claim 1 , wherein
the particulate toner matrix has a core-shell structure comprising a core particle and a shell coating the surface of the core particle, and
the shell comprises an amorphous polyester resin.
14. The electrostatic charge image developing toner according to claim 13 , wherein
the amorphous polyester resin comprises a hybrid amorphous polyester resin prepared through chemical bond of at least an amorphous polyester polymer segment and a second polymer segment.