Methods of separating molecules
Disclosed herein are new methods, machines, processes, and systems for separating molecules by determining better materials and process optimization conditions. As a result of these advances, this disclosure provides improved carbon dioxide capture, better flue gas treatments, and more efficient methods of purifying gases have been developed. Optimal sorbents can be obtained by using a computational screening method that selects microporous structures (e.g. zeolites and metal-organic frameworks) from a database of materials with the greatest potential for cost-effective separations. The disclosed methods are the first to consider both the size and shape of the adsorbent material. This is also the first disclosure to consider the process application and cost when selecting which material to use.
1. A process for separating carbon dioxide from a mixture of molecules comprising:
treating the mixture of molecules with a sorbent at a pressure of between about 0.5 to 15 bars, wherein the sorbent is a zeolite having one of the following framework types: ABW, AEN, AHT, APC, AWO, BIK, ERI, IHW, ITW, JBW, LTF, LTJ, MON, MVY, NAB, NSI, OFF, TON, VNI, and WEI, the zeolite comprising tetrahedrally-coordinated atoms of silicon and aluminum connected with oxygen atoms;
adsorbing carbon dioxide gas from the mixture of molecules;
reducing the pressure of the environment surrounding the carbon dioxide enriched sorbent.
2. The process of claim 1 , where the adsorbing takes place at a pressure of between about 1-10 bars.
3. The process of claim 1 , wherein the mixture comprises two or more gases chosen from carbon dioxide, nitrogen, water, oxygen, or hydrocarbon gases.
4. The process of claim 1 , comprising reducing the pressure of the environment surrounding the carbon dioxide enriched sorbent to between 0.005-0.5 bars.
5. The process of claim 4 , comprising reducing the pressure of the environment surrounding the carbon dioxide enriched sorbent to between 0.01-0.1 bars.
6. The process of claim 1 comprising dehydrating the mixture.
7. The process of claim 1 , wherein the material is chosen from AHT, NAB, MVY, ABW, AWO, WEI, VNI, TON, OFF, ITW, LTF, ERI, and IHW.
8. The process of claim 1 , wherein the material is chosen from WEI, AHT, AEN, ABW, APC, BIK, JBW, LTJ, MON, and NSI.
9. The process of claim 1 , having a cycle time of between 40-500 seconds.
10. The process of claim 1 , having a cycle time of between 100-250 seconds.
11. The process of claim 1 , comprising compressing carbon dioxide gas at a pressure of between 1-250 bar.
12. The process of claim 1 , wherein the mixture comprises two or more gases selected from the group consisting of carbon dioxide, nitrogen, water, and oxygen gases.
13. The process of claim 1 , wherein the mixture comprises two or more gases selected from the group consisting of carbon dioxide, nitrogen, and oxygen gases.
14. The process of claim 1 , wherein the mixture comprises is a flue gas.