Lubricant compositions containing hexene-based oligomers
Disclosed herein are oligomerization processes using feedstocks containing 1-hexene to produce an oligomer product, and methods for recovering a heavy 1-hexene oligomer from the oligomer product and hydrogenating the heavy 1-hexene oligomer. The resultant hydrogenated heavy 1-hexene oligomer can be blended with other PAO's to form 100 cSt and 40 cSt lubricant compositions, which have viscosity index and pour point properties that are equivalent to or better than respective 100 cSt and 40 cSt 1-decene PAO's.
1. A base oil or lubricant composition comprising:
(i) a hydrogenated oligomer composition comprising at least 80 wt. % monomer units derived from 1-hexene, and characterized by a 100° C. kinematic viscosity in a range from 75 to 150 cSt, a viscosity index in a range from 150 to 180, and a pour point in a range from −20 to −40° C.; and
(ii) a low viscosity PAO having a 100° C. kinematic viscosity in a range from 1 to 20 cSt;
wherein a weight ratio of the hydrogenated oligomer composition:low viscosity PAO is in a range from 25:75 to 90:10; and
wherein the base oil or lubricant composition has a 100° C. kinematic viscosity in a range from 30 to 50 cSt.
2. The base oil or lubricant composition of claim 1 , wherein:
the hydrogenated oligomer composition comprises at least 98 wt. % monomer units derived from 1-hexene, and has no discernable crystallization according to DSC using ASTM 3418-97; and
the hydrogenated oligomer composition is characterized by:
a 100° C. kinematic viscosity in a range from 85 to 115 cSt;
a viscosity index in a range from 155 to 165; and
a pour point in a range from −25 to −35° C.
3. The base oil or lubricant composition of claim 1 , wherein the base oil or lubricant composition has:
a 100° C. kinematic viscosity in a range from 35 to 45 cSt;
a viscosity index in a range from 130 to 180; and
a pour point of less than −32° C.
4. The base oil or lubricant composition of claim 1 , wherein the base oil or lubricant composition has:
a 100° C. kinematic viscosity in a range from 37 to 43 cSt;
a viscosity index in a range from 140 to 165; and
a pour point in a range from −30 to −50° C.
5. The base oil or lubricant composition of claim 1 , wherein:
the base oil or lubricant composition has a 40° C. kinematic viscosity in a range from 375 to 425 cSt; and
the weight ratio of the hydrogenated oligomer composition:low viscosity PAO is in a range from 35:65 to 80:20.
6. The base oil or lubricant composition of claim 1 , wherein the low viscosity PAO has:
a 100° C. kinematic viscosity in a range from 1 to 15 cSt;
a viscosity index in a range from 90 to 200; and
a pour point in a range from −23 to −80° C.
7. The base oil or lubricant composition of claim 1 , wherein the low viscosity PAO comprises monomer units derived from a C 6 to C 18 normal alpha olefin.
8. The base oil or lubricant composition of claim 1 , wherein the base oil or lubricant composition comprises less than 10 wt. % of a PAO comprising at least 80 wt. % of monomer units derived from 1-decene.
9. A base oil or lubricant composition comprising:
(i) a hydrogenated oligomer composition comprising at least 80 wt. % monomer units derived from 1-hexene, and characterized by a 100° C. kinematic viscosity in a range from 75 to 150 cSt, a viscosity index in a range from 150 to 180, and a pour point in a range from −20 to −40° C.; and
(ii) a high viscosity PAO having a 100° C. kinematic viscosity in a range from 75 to 150 cSt;
wherein a weight ratio of the hydrogenated oligomer composition:high viscosity PAO is in a range from 25:75 to 80:20; and
wherein the base oil or lubricant composition has a 100° C. kinematic viscosity in a range from 80 to 120 cSt.
10. The base oil or lubricant composition of claim 9 , wherein:
the hydrogenated oligomer composition comprises at least 95 wt. % monomer units derived from 1-hexene, and has no discernable crystallization according to DSC using ASTM 3418-97; and
the hydrogenated oligomer composition is characterized by:
a 100° C. kinematic viscosity in a range from 80 to 125 cSt;
a viscosity index in a range from 150 to 170; and
a pour point in a range from −25 to −40° C.
11. The base oil or lubricant composition of claim 9 , wherein the base oil or lubricant composition has:
a 100° C. kinematic viscosity in a range from 85 to 115 cSt;
a viscosity index in a range from 160 to 190; and
a pour point of less than −25° C.
12. The base oil or lubricant composition of claim 9 , wherein the base oil or lubricant composition has:
a 100° C. kinematic viscosity in a range from 90 to 110 cSt;
a viscosity index in a range from 165 to 180; and
a pour point in a range from −28 to −38° C.
13. The base oil or lubricant composition of claim 9 , wherein:
the base oil or lubricant composition has a 40° C. kinematic viscosity in a range from 1100 to 1300 cSt; and
the weight ratio of the hydrogenated oligomer composition:high viscosity PAO is in a range from 40:60 to 60:40.
14. The base oil or lubricant composition of claim 9 , wherein the high viscosity PAO has:
a 100° C. kinematic viscosity in a range from 85 to 115 cSt;
a viscosity index in a range from 155 to 250; and
a pour point in a range from −26 to −50° C.
15. The base oil or lubricant composition of claim 9 , wherein the high viscosity PAO comprises monomer units derived from a C 8 to C 18 normal alpha olefin.
16. The base oil or lubricant composition of claim 9 , wherein the base oil or lubricant composition comprises less than 5 wt. % of a PAO comprising at least 95 wt. % of monomer units derived from 1-decene.