Surface doping of nanostructures
This disclosure provides systems, methods, and apparatus related to surface doping of nanostructures. In one aspect a plurality of nanostructures is fabricated with a solution-based process using a solvent. The plurality of nanostructures comprises a semiconductor. Each of the plurality of nanostructures has a surface with capping species attached to the surface. The plurality of nanostructures is mixed in the solvent with a dopant compound that includes doping species. During the mixing the capping species on the surfaces of the plurality of nanostructures are replaced by the doping species. Charge carriers are transferred between the doping species and the plurality of nanostructures.
1. A material comprising:
a plurality of tellurium nanowires, the plurality of tellurium nanowires comprising a p-type semiconductor, the plurality of tellurium nanowires consisting essentially of tellurium; and
S 2− or SH − species disposed on surfaces of each of the plurality of tellurium nanowires, charge carriers comprising electrons being transferred between the S 2− or SH − species and the plurality of tellurium nanowires, the S 2− or SH − species shifting the Fermi level of each the plurality of tellurium nanowires towards the conduction band, and the S 2− or SH − species changing the plurality of tellurium nanowires to an n-type semiconductor.
2. The material of claim 1 , wherein S 2− species are disposed on surfaces of each of the plurality of tellurium nanowires, and wherein each of the plurality of nanowire has a sulfur atomic concentration of about 2.4%.
3. The material of claim 1 , wherein the doping species do not desorb from the plurality of tellurium nanowires in a time period of over about 1 year.
4. The material of claim 1 , wherein each of the plurality of tellurium nanowires has a diameter of about 10 nanometers to 500 nanometers and a length of about 100 nanometers to 50 microns.
5. A method comprising:
(a) fabricating a plurality of tellurium nanowires with a solution-based process using a solvent, the plurality of tellurium nanowires comprising a p-type semiconductor, the plurality of tellurium nanowires consisting essentially of tellurium, each of the plurality of tellurium nanowires having a surface with capping species attached to the surface; and
(b) mixing the plurality of tellurium nanowires in the solvent with a dopant compound that includes S 2− or SH − species, during the mixing the capping species on the surfaces of each of the plurality of tellurium nanowires being replaced by the S 2− or SH − species, charge carriers comprising electrons being transferred between the S 2− or SH − species and each of the plurality of tellurium nanowires, the S 2− or SH − species shifting a Fermi level of each of the plurality of tellurium nanowires towards the conduction band, and the plurality of tellurium nanowires being changed to an n-type semiconductor.
6. The method of claim 5 , further comprising:
depositing the plurality of nanowires on a substrate.
7. The method of claim 5 , wherein the doping species have a larger binding energy to the surfaces of the plurality of nanowires than the capping species.
8. The method of claim 5 , wherein all of the capping species are replaced by the doping species.
9. The method of claim 5 , wherein a portion of the capping species are replaced by the doping species.
10. The method of claim 5 , wherein operation (b) includes agitating the plurality of nanowires and the dopant compound in the solvent for about 24 hours to 48 hours.
11. The method of claim 5 , wherein the doping species do not desorb from the plurality of nanowires in a time period of over about 1 year.
12. The method of claim 5 , wherein each of the plurality of tellurium nanowires has a diameter of about 10 nanometers to 500 nanometers and a length of about 100 nanometers to 50 microns.
13. The method of claim 5 , wherein the solvent comprises water.
14. The method of claim 5 , wherein the dopant compound comprises a salt.
15. The method of claim 5 , wherein the dopant compound is selected from a group consisting of Na 2 S, NaHS, (NH 4 ) 2 S, K 2 S, and KHS.
16. The method of claim 5 , wherein the plurality of tellurium nanowires is solution-processable after operation (b).
17. The method of claim 5 , wherein the dopant compound includes S 2− species, and wherein each of the plurality of nanowire has a sulfur atomic concentration of about 2.4%.