Glass composition, glass frit containing same, glass paste containing same, and electrical/electronic component obtained using same
The present invention aims at providing a lead-free glass composition that can be soften and flowed at a firing temperature that is equal to or lower than that of conventional low melting point lead glass. Furthermore, the present invention aims at providing a lead-free glass composition having fine thermal stability and fine chemical stability in addition to that property. The lead-free glass composition according to the present invention is characterized by comprising at least Ag 2 O, V 2 O 5 and TeO 2 when the components are represented by oxides, wherein the total content ratio of Ag 2 O, V 2 O 5 and TeO 2 is 75 mass % or more. Preferably, the lead-free glass composition comprises 10 to 60 mass % of Ag 2 O, 5 to 65 mass % of V 2 O 5 , and 15 to 50 mass % of TeO 2 .
1. A lead-free glass composition, comprising
10 to 60 mass % of Ag 2 O, 5 to 65 mass % of V 2 O 5 , and 15 to 50 mass % of TeO 2 when the components are represented by oxides,
wherein the total content ratio of Ag 2 O, V 2 O 5 and TeO 2 is 75 mass % or more and less than 100 mass %, and
further comprising one or more selected from the group consisting of P 2 O 5 , BaO, K 2 O, WO 3 , Fe 2 O 3 , MnO 2 , Sb 2 O 3 and ZnO as a remnant by more than 0 mass % and 25 mass % or less,
wherein (content ratio of Ag 2 O)/(content ratio of V 2 O 5 ) is 2.6 or less.
2. The glass composition according to claim 1 , wherein the sum of the content ratio of Ag 2 O and the content ratio of V 2 O 5 is 40 to 80 mass %.
3. A glass frit for sealing, comprising 50 to 100 vol % of the glass composition according to claim 1 , and comprising more than 0 and less than or equal to 50 vol % of an oxide filler material other than the oxides that constitute the glass composition.
4. The glass frit for sealing according to claim 3 , wherein the oxide filler material is one or more selected from the group consisting of SiO 2 , ZrO 2 , Al 2 O 3 , Nb 2 O 5 , ZrSiO 4 , Zr 2 (WO 4 )(PO 4 ) 2 , cordierite, mullite and eucryptite.
5. A glass paste for sealing, comprising the glass composition according to claim 1 , an oxide filler material other than the oxides that constitute the glass composition, and a solvent.
6. The glass paste for sealing according to claim 5 , wherein
the oxide filler material is one or more selected from the group consisting of SiO 2 , ZrO 2 , Al 2 O 3 , Nb 2 O 5 , ZrSiO 4 , Zr 2 (WO 4 )(PO 4 ) 2 , cordierite, mullite and eucryptite,
the solvent is butylcarbitol acetate or α-terpineol, and
the glass paste for sealing further comprises nitrocellulose as a resin binder.
7. An electroconductive glass paste, comprising the glass composition according to claim 1 , metal particles, an oxide filler material other than the oxides that constitute the glass composition, and a solvent.
8. The electroconductive glass paste according to claim 7 , wherein
the metal particles are silver, a silver alloy, aluminum, an aluminum alloy, copper or a copper alloy,
the oxide filler material is one or more selected from the group consisting of SiO 2 , ZrO 2 , Al 2 O 3 , Nb 2 O 5 , ZrSiO 4 , Zr 2 (WO 4 )(PO 4 ) 2 , cordierite, mullite and eucryptite,
the solvent is butylcarbitol acetate or α-terpineol, and
the electroconductive glass paste further comprises nitrocellulose as a resin binder.
9. The electroconductive glass paste according to claim 7 , wherein the metal particles have an average particle size of 0.5 to 10 μm, and have a spherical shape and/or a flaky shape.
10. The electroconductive glass paste according to claim 7 , wherein the metal particles are a mixture of a group of particles having an average particle size of 0.5 to 3 μm and a group of particles having an average particle size of 5 to 10 μM.
11. An electrical component having a sealing unit comprising a lead-free glass phase, wherein
the sealing unit comprises 50 to 100 vol % of the glass phase, and
the glass phase comprises 10 to 60 mass % of Ag 2 O, 5 to 65 mass % of V 2 O 5 and 15 to 50 mass % of TeO 2 when the components are represented by oxides,
wherein the total content ratio of Ag 2 O, V 2 O 5 and TeO 2 is 75 mass % or more and less than 100 mass %,
the glass phase further comprises one or more selected from the group consisting of P 2 O 5 , BaO, K 2 O, WO 3 , Fe 2 O 3 , MnO 2 , Sb 2 O 3 and ZnO as a remnant by more than 0 mass % and 25 mass % or less, and
wherein (content ratio of Ag 2 O)/(content ratio of V 2 O 5 ) is 2.6 or less.
12. An electrical component having an electrode or wiring comprising a lead-free glass phase and metal particles, wherein
the electrode or wiring comprises 5 to 30 vol % of the glass phase and 70 to 95 vol % of the metal particles,
the metal particles are silver, a silver alloy, aluminum, an aluminum alloy, copper or a copper alloy, and
the glass phase comprises 10 to 60 mass % of Ag 2 O, 5 to 65 mass % of V 2 O 5 and 15 to 50 mass % of TeO 2 when the components are represented by oxides,
wherein the total content ratio of Ag 2 O, V 2 O 5 and TeO 2 is 75 mass % or more and less than 100 mass %, and
the glass phase further comprises one or more selected from the group consisting of P 2 O 5 , BaO, K 2 O, WO 3 , Fe 2 O 3 , MnO 2 , Sb 2 O 3 and ZnO as a remnant by more than 0 mass % and 25 mass % or less, and
wherein (content ratio of Ag 2 O)/(content ratio of V 2 O 5 ) is 2.6 or less.
13. The electrical component according to claim 12 , wherein the electrode/wiring has an electrical resistance rate of lower than 10 −5 Ωcm.
14. The electrical component according to claim 13 , wherein the sum of the content ratio of Ag 2 O and the content ratio of V 2 O 5 is 40 to 80 mass %.