Process for the thickness growth of colloidal nanosheets and materials composed of said nanosheets
A process of growth in the thickness of at least one facet of a colloidal inorganic sheet, by sheet is meant a structure having at least one dimension, the thickness, of nanometric size and lateral dimensions great compared to the thickness, typically more than 5 times the thickness. The process allows the deposition of at least one monolayer of atoms on at least one inorganic colloidal sheet, this monolayer being constituted of atoms of the type of those contained or not in the sheet. Homostructured and heterostructured materials resulting from such process as well as the applications of the materials are also described. By homostructured is meant a material of homogeneous composition in the thickness and by heterostructured is meant a material of heterogeneous composition in the thickness.
1. An inorganic colloidal nanoparticle comprising an initial inorganic nanosheet partially or totally covered with at least one monolayer of inorganic material, wherein the initial inorganic nanosheet is an inorganic colloidal nanosheet, wherein the inorganic colloidal nanoparticle has a thickness of 0.5 nm to 10 mm, wherein the initial inorganic nanosheet comprises a material MxEy, wherein: M is Zn, Cd, Hg, Cu, Ag, Au, Ni, Pd, Pt, Co, Fe, Ru, Os, Mn, Tc, Re, Cr, Mo, W, V, Nd, Ta, Ti, Zr, Hf, Be, Mg, Ca, Sr, Ba, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or a mixture thereof, E is O, S, Se, Te, N, P, As, F, Cl, Br, I, or a mixture thereof, and x and y are independently a decimal number from 0 to 5, and wherein the initial inorganic nanosheet is partially or totally covered by a monolayer of a material M or E wherein: M is Zn, Cd, Hg, Cu, Ag, Au, Ni, Pd, Pt, Co, Fe, Ru, Os, Mn, Tc, Re, Cr, Mo, W, V, Nd, Ta, Ti, Zr, Hf, Be, Mg, Ca, Sr, Ba, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or a mixture thereof, and E is O, S, Se, Te, N, P, As, F, Cl, Br, I, or a mixture thereof.
2. The inorganic collodial nanoparticle according to claim 1 , whose lateral dimensions are at least 1.5 times its thickness.
3. The inorganic collodial nanoparticle according to claim 1 , wherein the initial inorganic nanosheet is partially or totally covered by at least two monolayers, where the monolayers are alternatively composed of M then E or conversely,
wherein M is Zn, Cd, Hg, Cu, Ag, Au, Ni, Pd, Pt, Co, Fe, Ru, Os, Mn, Tc, Re, Cr, Mo, W, V, Nd, Ta, Ti, Zr, Hf, Be, Mg, Ca, Sr, Ba, Al, Ga, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or a mixture thereof, and
E is O, S, Se, Te, N, P, As, F, Cl, Br, I, or a mixture thereof.
4. The inorganic colloidal nanoparticle according to claim 1 , wherein the inorganic colloidal nanoparticle has a core/shell structure.
5. A product comprising at least one inorganic colloidal nanoparticle according to claim 1 , wherein the product is a luminescent system, an electroluminescent system, an amplifying stage of a laser, a catalyst, a photovoltaic cell, or a transistor.