Secondary battery
Provided is a secondary battery, which includes a separator having excellent air permeability such that the separator is adhered to a positive electrode plate and/or a negative electrode plate at a low temperature under a low pressure and swelling in an electrolyte solution is relatively suppressed. The secondary battery includes an electrode assembly including a positive electrode plate, a negative electrode plate and a separator interposed between the positive electrode plate and the negative electrode plate, wherein the separator further includes an adhesive layer formed on its surface, the adhesive layer includes a binder, and a gel-sol transition temperature of the binder is in a range of 70° C. to 90° C.
1. A secondary battery comprising:
an electrode assembly, said assembly including a positive electrode plate, a negative electrode plate and a separator interposed between the positive electrode plate and the negative electrode plate, wherein the separator further includes an adhesive layer formed on its surface, where the adhesive layer includes a binder, wherein the binder includes a polyvinylidene fluoride-hexafluoropropyl (PVdF-HFP) copolymer having a molecular weight in a range of 1000K g/mol to 1500K g/mol and a gel-sol transition temperature of the binder is in a range of 70° C. to 90° C.,
wherein the separator and the positive electrode plate or the negative electrode plate are adhered to each other with a binding strength in a range of 0.05 gf/mm to 1.10 gf/mm, and
wherein the HFP content of the PVdF-HFP copolymer ranges from 3 wt % to 7 wt %.
2. The secondary battery of claim 1 , further comprising an electrolyte solution, wherein the electrolyte solution includes an organic solvent selected from the group consisting of ethylene carbonate (EC), propylene carbonate (PC), ethylpropionate (EP) and propyl propionate (PP) and mixtures of two or more compounds.
3. The secondary battery of claim 2 , wherein the binder has a gel-sol transition temperature in a range of 74° C. to 88° C.
4. The secondary battery of claim 2 , wherein the binder has a sol-gel transition temperature in a range of 28° C. to 51° C.
5. The secondary battery of claim 1 , wherein the adhesive layer further includes inorganic particles, which are selected from the group consisting of BaTiO 3 ,
Pb(Zr x Ti 1-x )O 3 (PZT), where 0<x<1, Pb 1-x La x Zr 1-y Ti y O 3 (PLZT), where 0<x<1 and 0<y<1, Pb(Mg 1/3 Nb 2/3 )O 3-x PbTiO 3 (PMN-PT), where 0<x<1, hafnia (HfO 2 ), SrTiO 3 , SnO 2 , CeO 2 , MgO, NiO, CaO, ZnO, ZrO 2 , SiO 2 , Y 2 O 3 , Al 2 O 3 , SiC, TiO 2 and mixtures of two or more of these materials.
6. The secondary battery of claim 1 , wherein the binder and the inorganic particles are contained in the adhesive layer in a weight ratio of 1:2 to 1:5.