IP Library › Granted Patent US 10,266,416
Granted Patent B2
US 10,266,416 · App. 14/898,656 · Granted Apr 23, 2019

Method for producing zeolites and zeotypes

Inventors: Søren Kegnæs (Limhamn, SE); Jacob Oskar Abildstrøm (København K, DK); Jerrik Jørgen Mielby (Vanløse, DK)
Assignee: DANMARKS TEKNISKE UNIVERSITET
C01B39/08B01J29/041B01J29/042B01J29/043B01J29/044B01J29/045B01J29/89B01J35/109B01J35/1061B01J35/1066B01J37/0018C01B39/085C07C2/66C07C5/2772B01J2229/183B01J2229/60C07C2529/04C07C2529/89
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,266,416
App. No.
14/898,656
Granted
Apr 23, 2019
Kind
B2
Abstract

The invention relates to a method for producing zeolite, zeolite-like or zeotype particles comprising the steps of: 1) Adding one or more metal precursors to a silica or alumina source; 2) Reducing the one or more metal precursors to form metal nanoparticles on the surface of the silica or alumina source; 3) Passing a gaseous hydrocarbon, alkyl alcohol or alkyl ether over the silica or alumina supported metal nanoparticle to form a carbon template coated zeolite, zeolite-like or zeotype precursor composition; 4a) Adding a structure directing agent to the carbon template coated zeolite, zeolite-like or zeotype precursor composition thereby creating a zeolite, zeolite-like or zeotype gel composition; 4b) Crystallizing the zeolite, zeolite-like or zeotype gel composition by subjecting said composition to a hydrothermal treatment; 5) Removing the carbon template and structure directing agent and isolating the resulting zeolite, zeolite-like or zeotype particles.

Claims (15)

1. A method for producing zeolite, zeolite-like or zeotype particles comprising:

1) Adding one or more metal precursors to a silica or alumina source;

2) Reducing the one or more metal precursors to form metal nanoparticles supported on the surface of the silica or alumina source;

3) Passing a gaseous hydrocarbon, alkyl alcohol or alkyl ether over the metal nanoparticles supported on the surface of the silica or alumina source to form a zeolite, zeolite-like or zeotype precursor composition comprising carbon template coated metal nanoparticles;

4a) Dissolving the zeolite, zeolite-like or zeotype precursor composition comprising carbon template coated metal nanoparticles in an aqueous alkaline media and adding a structure directing agent thereby creating a zeolite, zeolite-like or zeotype gel composition;

4b) Crystallising the zeolite, zeolite-like or zeotype gel composition by subjecting said composition to a hydrothermal treatment; and

5) Removing the carbon template and structure directing agent and isolating the resulting zeolite, zeolite-like or zeotype particles;

wherein the zeolite, zeolite-like or zeotype precursor composition comprising carbon template coated metal nanoparticles of step 3 is used directly in step 4a without removing the silica or alumina source.

2. The method for producing zeolite, zeolite-like or zeotype particles according to claim 1 , wherein the one or more metal(s) is selected from the group consisting of group 4 elements, group 6 elements, group 7 elements, group 8 elements, group 9 elements, group 10 elements, group 11 elements and group 12 elements or mixtures thereof.

3. The method for producing zeolite, zeolite-like or zeotype particles according to claim 1 , wherein the one or more metal(s) is selected from the group consisting of titanium, osmium, iridium, platinum, ruthenium, palladium, rhodium, rhenium, copper, nickel, iron, cobalt, silver, gold, cadmium, and molybdenium or mixtures thereof.

4. The method of producing a zeolite, zeolite-like or zeotype particle according to claim 1 , the method further comprising adding an Al, Sn Ti, Zr or Ge source during step 4a.

5. The method for producing zeolite, zeolite-like or zeotype particles according to claim 1 , wherein the hydrocarbon is selected from the group consisting of aliphatic hydrocarbons having 1 to 8 carbon atoms, aliphatic hydrocarbons having 1 to 3 carbon atoms, alkenes having 2 to 6 carbon atoms, aromatic hydrocarbons having 6 to 10 carbon atoms and cyclic hydrocarbons having 3 to 8 carbon atoms.

6. The method for producing zeolite, zeolite-like or zeotype particles according to claim 5 , wherein the hydrocarbon is methane, propene, xylene or benzene.

7. The method for producing zeolite, zeolite-like or zeotype particles according to claim 1 , wherein the hydrothermal treatment comprises that the zeolite, zeolite-like or zeotype gel composition is heated to temperatures between 70 and 300° C., or at 180° C., under an autogeneous pressure in an autoclave or open flask for 24 hours or more.

8. The method for producing zeolite, zeolite-like or zeotype particles according to claim 1 , wherein the one or more metal precursors is added to the silica or alumina source in an amount of 5 to 20 wt %, from 0.5 to 5 wt %, from 0.5 to 2 wt %, or 1 wt % during step 1.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 4, 2016
From: KEGNÆS, SØREN; ABILDSTRØM, JACOB OSKAR; MIELBY, JERRIK JØRGEN
To: DANMARKS TEKNISKE UNIVERSITET
Reel/Frame 037668/0360 →
Priority Claims (1)
EP 13175325 · Jul 5, 2013 · regional
Continuity (1)
Related Publication 20160137516A1 · May 19, 2016
Cited By (1)
US 12,714,988