Method for preparing noble metal catalyst
The present invention discloses a method for preparing a catalyst, comprising the following steps: (1) taking a noble metal salt solution A, adding a modified alumina support material, stirring until uniform and standing; (2) drying the material obtained in step (1) in a vacuum, and calcining at 500° C.-600° C. for 1-4 hours to obtain a powder material containing the noble metal; (3) mixing the noble metal powder material, an adhesive and other components to be added, and ball-milling to obtain a uniform slurry; (4) preparing a noble metal solution B and adjusting pH to 0.5-1; and (5) mixing the slurry of the step (3) with the noble metal solution B, coating the mixture on a support, drying, and calcining at 500° C.-600° C. for 1-2 hours to obtain the target product. The method for preparing the catalyst of the present invention is simple, the conditions of the preparation process are easy to control and the preparation method has strong practicality. The prepared catalyst has a good quality, a low ignition temperature and a high catalytic conversion rate for methane at a relatively low temperature.
1. A method for preparing a catalyst, comprising the following steps:
(1) taking a noble metal salt solution A, adding a modified alumina support material, stirring until uniform and standing;
(2) drying the material obtained in step (1) in a vacuum, and calcining at 500° C.-600° C. for 1-4 hours to obtain a powder material containing the noble metal;
(3) mixing the powder material containing the noble metal prepared in step (2) with an adhesive and performing ball-milling, to obtain a uniform slurry;
(4) preparing a noble metal solution B and adjusting pH to 0.5-1; and
(5) mixing the slurry obtained in step (3) with the noble metal salt solution B, coating the mixture on a support, drying, and calcining at 500° C.-600° C. for 1-4 hours to obtain a target product; wherein the noble metal in the noble metal salt solution A and the noble metal salt solution B is one or more of palladium, platinum and rhodium.
2. The method for preparing a catalyst according to claim 1 , characterized in that the noble metal salt solutions A and B are noble metal soluble salt solutions, the noble metal is palladium and/or platinum, and the soluble salt is nitrate, hydrochloride or ammonia salt.
3. The method for preparing a catalyst according to claim 2 , characterized in that a concentration of the noble metal salt solution A is 0.1-2.0 wt %, wherein a weight ratio of Pt to Pd is 1:0-0:1.
4. The method for preparing a catalyst according to claim 2 , characterized in that a concentration of the noble metal salt solution B is 0.1-2.0%, wherein a weight ratio of Pt to Pd is 1:0-0:1.
5. The method for preparing a catalyst according to claim 1 , characterized in that the noble metal salt solution A includes palladium and/or platinum, a concentration of the noble metal salt solution A is 0.1-2.0 wt %, and a weight ratio of Pt to Pd is 1:0-0:1.
6. The method for preparing a catalyst according to claim 5 , wherein the noble metal salt solution B includes palladium and/or platinum, a concentration of the noble metal salt solution B is 0.1-2.0%, and a weight ratio of Pd to Pt is 1:0-0:1.
7. The method for preparing a catalyst according to claim 6 , wherein the weight ratio of Pt to Pd in the noble metal solution A is 1:7-1:4.2, and the weight ratio of Pd to Pt in the noble metal solution B is 6.5:1-1:7.
8. The method for preparing a catalyst according to claim 6 , wherein a weight ratio of noble metal components in the noble metal solution A to noble metal components in the noble metal solution B is 1:9-9:1.
9. The method for preparing a catalyst according to claim 6 , wherein each of the noble metal salt solutions A and B comprise a soluble noble metal salt solution, and the soluble noble metal salt is a nitrate or chloride salt of palladium and/or platinum.
10. The method for preparing a catalyst according to claim 6 , further comprising allowing the stirred noble metal salt solution A to which the modified alumina support material has been added in step (1) to stand for more than 1 hour.
11. The method for preparing a catalyst according to claim 6 , wherein step (2) comprises drying the material obtained in step (1) in a vacuum at a temperature of 80° C. to 100° C.
12. The method for preparing a catalyst according to claim 1 , characterized in that a weight ratio of noble metal components contained in the noble metal solution A and in the noble metal solution B is 1:9-9:1.
13. The method for preparing a catalyst according to claim 1 , characterized in that the noble metal salt solution B includes palladium and/or platinum, a concentration of the noble metal salt solution B is 0.1-2.0%, and a weight ratio of Pt to Pd is 1:0-0:1.
14. The method for preparing a catalyst according to claim 1 , characterized in that the modified alumina support material is La—Al 2 O 3 or γ-Al 2 O 3 .
15. The method for preparing a catalyst according to claim 1 , characterized in that in step (1), the stirred noble metal salt solution A to which the modified alumina support material has been added stands for more than 0.5 hours.
16. The method for preparing a catalyst according to claim 1 , characterized in that water content in the noble metal salt solution A in step (1) is 90% to 100% of a water absorption capacity of the modified alumina support material.
17. The method for preparing a catalyst according to claim 1 , characterized in that step (2) comprises drying the material obtained in step (1) in a vacuum at a temperature of 80° C. to 100° C.
18. The method for preparing a catalyst according to claim 1 , characterized in that after the slurry obtained in step (3) is mixed with the noble metal salt solution B, the mixture stands for 0.5 to 2 hours.
19. The method for preparing a catalyst according to claim 1 , further comprising allowing the slurry mixed with the noble metal salt solution B to stand for 0.5 to 2 hours.
20. The method for preparing a catalyst according to claim 1 , wherein the support comprises a ceramic honeycomb support or a metal honeycomb support.