Method for producing a valve seat ring
A valve seat ring and a method for producing the same may include a first material and a second material. The first material may be composed of approximately 15 to 30% by weight of Mo, approximately 5 to 30% by weight of chromium, approximately 0 to 5% by weight of Si, approximately 0 to 2% by weight of C, and up to 5% by weight of other elements and a portion of Co. The second material may be composed of approximately 10 to 12% by weight of Cr, approximately 0.5 to 0.8% by weight of Mn, approximately 0.5 to 1% by weight of Si, approximately 0.5 to 0.9% by weight of C, up to approximately 3% by weight of other elements and a reminder of Fe.
1. A method for producing a valve seat ring, comprising: providing a first material composed of approximately 15 to 30% by weight of molybdenum, approximately 5 to 30% by weight of chromium, approximately 0 to 5% by weight of silicon, approximately 0 to 2% by weight of carbon, and up to 5% by weight of other elements and a remainder of cobalt, and a second material composed of approximately 10 to 12% by weight of chromium, approximately 0.5 to 0.8% manganese, approximately 0.5 to 1% by weight of silicon, approximately 0.5 to 0.9% by weight of carbon, up to approximately 3% by weight of other elements and a remainder of iron,
processing the first materials and the second material to form a powder by atomising a metal melt so that the first material and the second material have a mean particle size of approximately 5 to 13 μm,
processing the powder of each of the first material and the second material into a flowable granulate with a granulate size of substantially smaller than 300 μm and greater than 15 μm,
admixing a proportion of 1 to 5% by weight of an organic pressing additive,
filling the granulate of the first material and of the second material into a press tool one after the other and subsequently uniaxially pressing the granulate in the press tool with a pressing pressure of 400<p<700 MPa,
removing the organic pressing additive by heating at a temperature 50° C.<t<700° C., and
performing at least one of a pre-sintering and finish-sintering.
2. The method according to claim 1 , wherein the pre-sintering is performed at a temperature of 1,110° C.<t<1,130° C. and the finish-sintering is performed at a temperature of approximately 1,240° C.
3. The method according to claim 1 wherein processing the powder of each of the first material and the second material includes at least one of fluidised bed granulation, spray drying and screen granulation.
4. The method according to claim 1 , wherein the first material includes an alloy having 22-24% by weight of Mo, 15-17% by weight of Cr, 0.5-1.5% by weight of Si, 1.5-2.5% by weight of Fe, 0.3-1% by weight of C, approximately 4% by weight of other elements and a remainder of Co.
5. The method according to claim 1 , wherein the second material includes a steel having 10-12% by weight of Cr, 0.4-0.8% by weight of Mn, 0.5-1% by weight of Si, 0.5-0.9% by weight of C, approximately 3% by weight of other elements and the remainder of Fe.
6. The method according to claim 1 , wherein the first material includes an alloy having 23% by weight of Mo, 16% by weight of Cr, 1% by weight of Si, 2% by weight of Fe, 0.5% by weight of C, approximately 3% by weight of other elements and a remainder of Co.
7. The method according to claim 1 , wherein the second material includes an alloy having 11% by weight of Cr, 0.6% by weight of Mn, 0.7% by weight of Si, 0.7% by weight of C, approximately 2% by weight of other elements and the remainder of Fe.
8. The method according to claim 1 , wherein pressing the granulate in the press tool includes compressing the granulate with a pressing pressure of 520 MPa, wherein the granulate of the first material is compressed to a density of approximately 5.85 g/m 3 and the granulate of the second material is compressed to a density of approximately 5.5 g/cm 3 .
9. The method according to claim 1 , wherein pressing the granulate in the press tool includes compressing the granulate in such a manner that a relative density of the first material before sintering deviates by a maximum of +/−3% from a relative density of the second material.
10. The method according to claim 1 , wherein performing the pre-sintering is for approximately 25 to 35 minutes in an N2-H2 atmosphere with a proportion of H2 to 5%<H2 <20%.
11. The method according to claim 1 , wherein performing the finish-sintering is for approximately 50 to 60 minutes in an N2-H2 atmosphere with a proportion of H2 of 5%<H2 <20%.
12. The method according to claim 1 , wherein performing the pre-sintering includes heating to a predetermined temperature at 3 to 5° C./min and cooling to room temperature at approximately 5 to 10° C./min.
13. The method according to claim 1 , wherein performing the finish-sintering includes heating to a predetermined temperature at 5 to 10° C./min and cooling to room temperature at approximately 10 to 20° C./min.
14. The method according to claim 1 , wherein performing the at least one of the pre-sintering and the finish-sintering includes heating to a temperature of 1,100° C. in an N2-H2 atmosphere and at a temperature of 1,100° C.<T<1,240° C. under vacuum.
15. The method according to claim 1 , wherein the granulate size is smaller than 150 μm and greater than 15 μm.