Nonaqueous electrolyte secondary battery and method for manufacturing the same
A nonaqueous electrolyte secondary battery includes a prismatic housing having an opening and a sealing member sealing the opening. The prismatic housing contains a flat-wound electrode assembly and a nonaqueous electrolyte. The flat-wound electrode assembly includes a positive electrode and a negative electrode. The positive electrode includes a positive electrode substrate and a positive electrode active material mixture layer formed on the positive electrode substrate. The positive electrode active material mixture layer contains lithium carbonate and lithium phosphate. The nonaqueous electrolyte contains lithium fluorosulfonate.
1. A nonaqueous electrolyte secondary battery comprising:
an electrode assembly comprising a positive electrode and a negative electrode, the positive electrode comprising a positive electrode active material, lithium carbonate, and lithium phosphate, the negative electrode comprising a negative electrode active material; and a nonaqueous electrolyte containing lithium fluorosulfonate.
2. The nonaqueous electrolyte secondary battery according to claim 1 , further comprising:
a housing having an opening and containing the electrode assembly and the nonaqueous electrolyte;
a sealing member sealing the opening;
a terminal attached to the sealing member and electrically connected to the positive electrode or the negative electrode; and
a current-interrupting mechanism disposed on a conduction path between the positive electrode or the negative electrode and the terminal, the current-interrupting mechanism being activated to break the conduction path and thereby interrupt a current therethrough when the internal pressure of the battery reaches a predetermined level or higher.
3. The nonaqueous electrolyte secondary battery according to claim 1 , further comprising:
a housing having an opening and containing the electrode assembly and the nonaqueous electrolyte;
a sealing member sealing the opening;
a terminal attached to the sealing member and electrically connected to the positive electrode or the negative electrode; and
a short-circuiting mechanism that is activated to forcedly short-circuit the positive electrode and the negative electrode when the internal pressure of the battery reaches a predetermined level or higher.
4. The nonaqueous electrolyte secondary battery according to claim 3 , further comprising:
a fusible portion disposed on a conduction path between the positive electrode or the negative electrode and the terminal, the fusible portion being blown by a short-circuit current upon activation of the short-circuiting mechanism.
5. The nonaqueous electrolyte secondary battery according to claim 1 , wherein
the positive electrode active material is a lithium transition metal oxide, and
the negative electrode active material is a carbonaceous material.
6. The nonaqueous electrolyte secondary battery according to claim 1 , wherein
the lithium carbonate is 0.1% to 5% by mass relative to a total amount of the positive electrode active material,
the lithium phosphate is 0.1% to 5% by mass relative to a total amount of the positive electrode active material, and
the lithium fluorosulfonate is 0.25% to 2.5% by mass relative to a total amount of the nonaqueous electrolyte.