Coated print media
View Patent ↗A coated print medium can include a base stock having a basis weight of 35 gsm to 250 gsm, and a coating layer applied to the base stock at from 1 gsm to 50 gsm by dry weight. The base stock can include from 65 wt % to 95 wt % cellulose fiber with 20 wt % to 100 wt % being mechanical pulp, and from 5 wt % to 35 wt % inorganic pigment filler. The coating layer can include inorganic pigment particles having an average equivalent spherical diameter from 0.2 μm to 3.5 μm; a fixative agent including metal salt, cationic amine polymer, quaternary ammonium salt, quaternary phosphonium salt, or mixture thereof; and a polymer blend including water soluble polymer and water dispersible polymer having a Zeta potential greater than −40 mV, wherein a weight ratio water soluble polymer to water dispersible polymer is from 1:25 to 1:1.
1. A coated print medium, comprising:
a base stock having a basis weight of 35 gsm to 250 gsm, comprising:
from 65 wt % to 95 wt % cellulose fiber, wherein from 20 wt % to 100 wt % of the cellulose fiber is mechanical pulp, and
from 5 wt % to 35 wt % inorganic pigment filler,
a coating layer applied to the base stock at from 1 gsm to 50 gsm by dry weight, the coating layer, comprising:
inorganic pigment particles having an average equivalent spherical diameter from 0.2 μm to 3.5 μm,
a fixative agent including a metal salt, a cationic amine polymer, a quaternary ammonium salt, a quaternary phosphonium salt, or mixture thereof, and
a polymer blend comprising a water soluble polymer and a water dispersible polymer having a Zeta potential greater than −40 mV, wherein a dry weight ratio water soluble polymer to water dispersible polymer is from 1:25 to 1:1.
2. The coated print medium of claim 1 , wherein the inorganic pigment filler in the base stock comprises precipitated calcium carbonate, ground calcium carbonate, clay, titanium dioxide, or combination thereof.
3. The coated print medium of claim 1 , wherein the base stock has an ISO brightness up to 85% and a PPS smoothness of 6 microns or less.
4. The coated print medium of claim 1 , wherein the base stock has an ISO brightness from 65% to 80%, and wherein from 30 wt % to 100 wt % of the cellulose fiber is mechanical pulp.
5. The coated print medium of claim 1 , wherein the inorganic pigment particles comprise calcium carbonate particles, said calcium carbonate particles in the form of ground calcium carbonate particles, precipitated calcium carbonate particles, calcium carbonate reacted with colloidal silica, titanium dioxide inter-calcined into calcium carbonate, silicon dioxide inter-calcined into calcium carbonate, aluminum trihydroxide inter-calcined into calcium carbonate, zirconium oxide inter-calcined into calcium carbonate, aragonite precipitated calcium carbonate, or mixtures thereof.
6. The coated print medium of claim 1 , wherein the inorganic pigment particles comprise fumed silica, silica gel, calcine clay, porous clay reacted with colloidal silica, titanium dioxide, silicon dioxide, aluminum trihydroxide, zirconium oxide, titanium dioxide inter-calcined into clay, silicon dioxide inter-calcined into clay, aluminum trihydroxide inter-calcined into clay, zirconium oxide inter-calcined into clay, or mixtures thereof.
7. The coated print medium of claim 1 , wherein the inorganic pigment particles comprise aluminum silicate having an average equivalent spherical diameter from 0.9 μm to 1.6 μm, with no more than 5 wt % greater than 4.5 μm and more than 10 wt % less than 0.3 μm, and wherein the aluminum silicate has a plate-like structure having an average equivalent spherical diameter to average thickness ratio from 10:1 to 50:1, where the thickness is measured at the shortest distance across the plate-like structure.
8. The coated print medium of claim 1 , wherein the weight ratio water soluble polymer to water dispersible polymer is from 1:5 to 9:10.
9. The coated print medium of claim 1 , wherein the water dispersible polymer has a glass transition temperature from −30° C. to 50° C.
10. The coated print medium of claim 1 , wherein the coated print medium has a porosity measured in air permeance at from 15 to 40 Sheffield units.
11. A printing system, comprising:
an inkjet ink; and
the coated print medium of claim 1 .
12. A method of preparing a coated print medium, comprising:
applying a coating composition to a base stock having a basis weight of 35 gsm to 250 gsm,
the base stock, comprising:
from 65 wt % to 95 wt % cellulose fiber with 20 wt % to 100 wt % of the cellulose fiber being a mechanical pulp, and
from 5 wt % to 35 wt % inorganic pigment filler,
the coating composition, comprising:
water,
inorganic pigment particles having an average equivalent spherical diameter from 0.2 μm to 3.5 μm,
a fixative agent including a metal salt, a cationic amine polymer, a quaternary ammonium salt, a quaternary phosphonium salt, or mixture thereof, and
a polymer blend comprising a water soluble polymer and a water dispersible polymer having a Zeta potential greater than −40 mV, wherein a weight ratio water soluble polymer to water dispersible polymer is from 1:25 to 1:1; and
drying the coating composition on the base stock to leave a 1 gsm to 50 gsm coating layer by dry weight.
13. The method of claim 12 , wherein the inorganic pigment filler in the base stock comprises precipitated calcium carbonate, ground calcium carbonate, clay, titanium dioxide, or combination thereof.
14. The method of claim 12 , wherein the inorganic pigment particles comprise ground calcium carbonate particles, precipitated calcium carbonate particles, calcium carbonate reacted with colloidal silica, titanium dioxide inter-calcined into calcium carbonate, silicon dioxide inter-calcined into calcium carbonate, aluminum trihydroxide inter-calcined into calcium carbonate, zirconium oxide inter-calcined into calcium carbonate, aragonite precipitated calcium carbonate, fumed silica, silica gel, calcine clay, porous clay reacted with colloidal silica, titanium dioxide, silicon dioxide, aluminum trihydroxide, zirconium oxide, titanium dioxide inter-calcined into clay, silicon dioxide inter-calcined into clay, aluminum trihydroxide inter-calcined into clay, or zirconium oxide inter-calcined into clay, aluminum silicate, or mixtures thereof.
15. The method of claim 12 , further comprising calendering the coating layer on the base stock at a pressure from 500 psi to 2500 psi and at a temperature from room temperature to 250° C.
16. The method of claim 12 , wherein the base stock has an ISO brightness up to 85% and a PPS smoothness of 6 microns or less.
17. The method of claim 12 , wherein the base stock has an ISO brightness from 65% to 80%, and wherein from 30 wt % to 100 wt % of the cellulose fiber is mechanical pulp.
18. The method of claim 12 , wherein the inorganic pigment particles comprise aluminum silicate having an average equivalent spherical diameter from 0.9 μm to 1.6 μm, with no more than 5 wt % greater than 4.5 μm and more than 10 wt % less than 0.3 μm, and wherein the aluminum silicate has a plate-like structure having an average equivalent spherical diameter to average thickness ratio from 10:1 to 50:1, where the thickness is measured at the shortest distance across the plate-like structure.
19. The method of claim 12 , wherein the weight ratio water soluble polymer to water dispersible polymer is from 1:5 to 9:10, and wherein the water dispersible polymer has a glass transition temperature from −30° C. to 50° C.
20. The printing system of claim 11 , wherein the coated print medium has a porosity measured in air permeance at from 15 to 40 Sheffield units.