Copper alloy for electronic and electrical equipment, plastically worked copper alloy material for electronic and electrical equipment, and component and terminal for electronic and electrical equipment
The present invention provides a copper alloy for electronic and electronic device which has excellent mechanical properties and is capable of suppressing generation of defects even in a case in which the copper alloy is worked to a thin plate thickness or a smaller wire diameter than in the related art, a plastically-worked copper alloy material, and a component and a terminal for electronic and electronic device. The copper alloy for electronic and electronic device of the present invention includes Mg in a range of 1.3 mass % to 2.8 mass % with a remainder substantially being Cu and inevitable impurities, in which a content of H is set to 10 mass ppm or lower, a content of O is set to 100 mass ppm or lower, a content of S is set to 50 mass ppm or lower, and a content of C is set to 10 mass ppm or lower.
1. A copper alloy for electronic and electrical devices, comprising:
Mg in a range of 1.3 mass % to 2.8 mass %; and
a remainder substantially being Cu and inevitable impurities,
wherein a content of H is set to 10 mass ppm or lower, a content of O is set to 100 mass ppm or lower, a content of S is set to 50 mass ppm or lower, and a content of C is set to 10 mass ppm or lower, and
wherein, R{220} is 0.9 or lower, where an X-ray diffraction intensity from a {111} plane on a plate surface is represented by I{111}, an X-ray diffraction intensity from a {200} plane on the plate surface is represented by I{200}, an X-ray diffraction intensity from a {220} plane on the plate surface is represented by I{220}, an X-ray diffraction intensity from a {311} plane on the plate surface is represented by I{311}, and a fraction {220} of the X-ray diffraction intensity from the {220} plane on the plate surface is R{220}=I{220}/(I{111}+I{200}+I{220}+I{311}).
2. The copper alloy for electronic and electrical devices according to claim 1 ,
wherein, in a scanning electron microscopic observation, an average number of intermetallic compounds which have a particle diameter of 0.1 μm or larger and include Cu and Mg as major components is set to 1 compound/μm 2 or less.
3. The copper alloy for electronic and electrical devices according to claim 1 ,
wherein, in a case where a content of Mg is defined as A atomic %, a conductivity σ (% IACS) is set in a range of σ≤1.7241/(−0.0347×A 2 +0.6569×A+1.7)×100.
4. The copper alloy for electronic and electrical devices according to claim 1 , comprising:
one or more of Sn, Zn, Al, Ni, Si, Mn, Li, Ti, Fe, Co, Cr, Zr, and P in a range of 0.01 mass % to 3.0 mass % in total.
5. The copper alloy for electronic and electrical devices according to claim 1 ,
wherein the copper alloy for electronic and electrical devices has mechanical properties such that a 0.2% yield strength is 400 MPa or higher.
6. The copper alloy for electronic and electrical devices according to claim 1 ,
wherein R{220} is set in a range of 0.3 to 0.9.
7. The copper alloy for electronic and electrical devices according to claim 1 ,
wherein a yield ratio YS/TS, which is calculated from a strength TS and a 0.2% yield strength YS obtained in a tensile test carried out in a direction parallel to a rolling direction, exceeds 90%.
8. The copper alloy for electronic and electrical devices according to claim 7 ,
wherein an average crystal grain size is set to 50 μm or smaller.
9. A plastically-worked copper alloy material for electronic and electrical devices formed by plastically working a copper material made of the copper alloy for electronic and electrical devices according to claim 1 .
10. The plastically-worked copper alloy material for electronic and electrical devices according to claim 9 , wherein the copper alloy material is metal-formed by a manufacturing method including a heat treatment step of heating a copper material to a temperature in a range of 400° C. to 900° C. and cooling the heated copper material to 200° C. or lower at a cooling rate of 60° C./min or greater and a plastic working step of plastically working the copper material.
11. The plastically-worked copper alloy material for electronic and electrical devices according to claim 9 ,
wherein Sn plating is carried out on a surface of the plastically-worked copper alloy material for electronic and electrical devices.
12. A component for electronic and electrical devices made of the plastically-worked copper alloy material for electronic and electrical devices according to claim 9 .
13. A terminal made of the plastically-worked copper alloy material for electronic and electrical devices according to claim 9 .