Method for producing a polyolefin structure
The production method for a polyolefin-based structure of the present invention produces a polyolefin-based structure from a mixed source material containing a polyolefin (A), an acid-modified polyolefin (B) and a gas barrier resin (C) using a molding machine 10 , under the condition mentioned below. The molding machine 10 is equipped with a single-screw extruder 11 , a die head 12 , and an adaptor 13 for feeding the mixed source material from the single-screw extruder 11 to the die head 12 . Am+10° C.≤T 1 ≤Cm−10° C. (1), Cm−30° C.≤T 2 ≤Cm+30° C. (2), Cm−10° C.≤T 3 ≤Cm+50° C. (3), Cm−30° C.≤T 4 ≤Cm+30° C. (4). T 1 is a cylinder temperature in a section corresponding to a supply zone 21 A and a compression zone 21 B, T 2 is a cylinder temperature in a section corresponding to a metering zone 21 C, T 3 is a temperature of an adaptor 13 , T 4 is a temperature of a die head, Am is the melting point of the component (A), and Cm is the melting point of the component (C).
1. A method for producing a polyolefin-based structure from a mixed source material comprising 60 to 90% by mass of a polyolefin (A), 5 to 35% by mass of an acid-modified polyolefin (B) and 5 to 35% by mass of a gas barrier resin (C) composed of polyamide, using a molding machine, wherein:
the molding machine is equipped with a single-screw extruder which has a screw running inside a cylinder, a die head, and a communication portion for feeding the mixed source material from the single-screw extruder to the die head, and
the mixed source material is extruded out through the molding machine under the temperature condition satisfying the following (1) to (4) to give a polyolefin-based structure in which the gas barrier resin (C) is dispersed in a form of layers in the polyolefin (A):
Am+ 10° C.≤ T 1 ≤Cm− 10° C. (1)
Cm− 30° C.≤ T 2≤ Cm+ 30° C. (2)
Cm− 10° C.≤ T 3 ≤Cm+ 50° C. (3)
Cm− 30° C.≤ T 4 ≤Cm+ 30° C. (4)
wherein T 1 is a cylinder temperature in a section corresponding to a supply zone and a compression zone of the screw in the single-screw extruder; T 2 is a cylinder temperature in a section corresponding to a metering zone of the screw in the single-screw extruder; T 3 is a temperature of the communication portion; T 4 is a temperature of the die head; Am is a melting point of the polyolefin (A); and Cm is a melting point of the gas barrier resin (C).
2. The method for producing a polyolefin-based structure according to claim 1 , wherein the temperature T 2 is lower than the melting point Cm of the gas barrier resin (C).
3. The method for producing a polyolefin-based structure according to claim 1 , wherein the melting point (Cm) of the gas barrier resin (C) is higher than the melting point (Am) of the polyolefin (A) and the melting point difference (Cm−Am) is 20 to 150° C.
4. The method for producing a polyolefin-based structure according to claim 1 , wherein a temperature T 5 of the resin being extruded out through the discharge port of the die head satisfies the following formula (5):
Cm− 30° C.≤ T 5 ≤Cm− 5° C. (5).
5. The method for producing a polyolefin-based structure according to claim 1 , wherein the screw has a barrier-type mixing section in the metering zone, and the temperature T 2 satisfies the following condition:
Cm− 30° C.≤ T 2 ≤Cm− 5° C.
6. The method for producing a polyolefin-based structure according to claim 1 , wherein the die head has two or more die holes.
7. The method for producing a polyolefin-based structure according to claim 1 , wherein the mixed source material contains 1 to 60% by mass of a recycled resin obtained from a resin solid generated in a production step for the polyolefin-based structure.
8. The method for producing a polyolefin-based structure according to claim 1 , wherein a melt flow rate of the polyolefin (A) is 0.01 to 10 (g/10 min).
9. The method for producing a polyolefin-based structure according to claim 1 , wherein a melt flow rate of the acid-modified polyolefin (B) is 0.1 to 10 (g/10 min).
10. The method for producing a polyolefin-based structure according to claim 1 , wherein an acid value of the acid-modified polyolefin (B) is 2 to 30 mg/g.
11. The method for producing a polyolefin-based structure according to claim 1 , wherein the gas barrier resin (C) is a metaxylylene group-containing polyamide.
12. The method for producing a polyolefin-based structure according to claim 11 , wherein a relative viscosity of the metaxylylene group-containing polyamide is 1.5 to 4.5.
13. The method for producing a polyolefin-based structure according to claim 11 , wherein a water content of the metaxylylene group-containing polyamide is 0.001 to 0.5%.
14. The method for producing a polyolefin-based structure according to claim 11 , wherein a free volume of the metaxylylene group-containing polyamide, as measured according to a positron annihilation technique, is 0.045 to 0.060 nm 3 .
15. The method for producing a polyolefin-based structure according to claim 1 , wherein the polyolefin-based structure is a hollow molded article.
16. The method for producing a polyolefin-based structure according to claim 1 , wherein the polyolefin-based structure is a sheet-molded article or a thermoformed article thereof.