IP Library Granted Patent US 10,301,564
Granted Patent B2
US 10,301,564 · App. 14/374,574 · Granted May 28, 2019

Fuel processing

Inventors: Michael Martella (London, GB); Matthew Martella (Bunbury, AU)
Assignee: ANERGY LIMITED
C10L3/08C10K1/06C10K3/023C10B47/30C10B53/02C10K1/02C10K3/005C10K3/006C10L3/104C10L2290/02C10L2290/04Y02E50/14Y02P20/145
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Quick Facts
Patent No.
US 10,301,564
App. No.
14/374,574
Granted
May 28, 2019
Kind
B2
Abstract

A system for processing carbonaceous in-feed material has a pyrolyzer kiln for pyrolysis the carbonaceous in-feed material, the kiln operating in a slow pyrolysis process in which the in-feed material is pyrolyzed in the kiln for a period of minutes in order to produce primarily a gaseous output fraction; a steam reformer positioned downstream of the kiln to which combustion gasses from the pyrolyzer kiln are fed; a water scrubber positioned gas flow-wise downstream of the steam reformer; a methanation stage; a CO2 scrubbing stage. The system includes means for splitting the gas and directing a portion of the split gas back to the pyrolyzer kiln.

Claims (35)

1. A system for processing carbonaceous in-feed material, the system comprising:

an indirect fired horizontal rotary pyrolyzer kiln configured to generate a pyrolyzing temperature between 600 C and 950 C for pyrolysis of the carbonaceous in-feed material, wherein the kiln, when so configured, generates an off-gas in a slow pyrolysis process in which the in-feed material is pyrolyzed in the kiln at the pyrolyzing temperature for a period of minutes in order to produce the off-gas, wherein the off-gas comprises dust and tar components;

a steam reformer positioned downstream of the kiln and configured to produce at least hydrogen from the off-gas, wherein oxygen is injected to allow a portion of the off-gas to combust to generate heat and steam, wherein the steam is used as a reaction medium to reform the tar into carbon-monoxide and hydrogen components;

a water scrubber positioned downstream of the steam reformer and configured to counter-currently contact the off-gas by water to cool off the off-gas to a temperature below 100 degrees Celsius to remove water from the off-gas;

a methanation stage including a compressor and a catalyst bed reactor, the methanation stage configured to compress the off-gas in the compressor and pass the compressed off-gas through the catalyst bed reactor where it is reacted with hydrogen to produce methane from the off-gas;

a carbon dioxide scrubbing stage configured to remove carbon dioxide from the off-gas; and

splitting means for splitting the off-gas into portions and directing at least one portion of the split off-gas to the kiln.

2. The system according to claim 1 , wherein the splitting means is provided downstream of the water scrubber and the steam reformer.

3. The system according to claim 1 , wherein the proportion of the off-gas split off and directed to the kiln is 30% or less by volume.

4. The system according to claim 1 , wherein the proportion of the off-gas split off and directed to the kiln is 20% or less by volume.

5. The system according to claim 1 , wherein the off-gas directed by the splitting means to the kiln is combusted by the kiln.

6. The system according to claim 1 , wherein the splitting means is positioned downstream of the methanation stage.

7. The system according to claim 1 , wherein the splitting means is positioned downstream of the carbon dioxide scrubbing stage.

8. The system according to claim 1 , wherein the primary output from the kiln is gas rather than liquid.

9. The system according to claim 1 , wherein the moisture content of the off-gas that exits the kiln is sufficiently high such that steam for the steam reformer is self generated.

10. The system according to claim 1 , wherein the kiln is mounted to rotate about a horizontal axis.

11. The system according to claim 1 , wherein the carbon dioxide scrubbing stage is positioned downstream of the methanation stage.

12. The system according to claim 1 , wherein the carbonaceous material is held in the kiln for a pyrolyzation time of between 1 and 60 minutes.

13. The system according to claim 1 , wherein the steam reformer operates at a temperature in the range of 900 C to 1400 C.

14. The system according to claim 1 , wherein Oxygen is supplied to the steam reformer.

15. The system according to claim 1 , wherein before entering the kiln, in-feed gas is passed through a pre-dryer stage.

16. The system according to claim 1 , wherein the kiln includes a gas/solid separator in which the char and gas fractions are separated.

17. A method for processing carbonaceous in-feed material, the method comprising:

feeding the carbonaceous in-feed material into an indirect fired horizontal rotary pyrolyzer kiln, wherein the kiln is configured to generate a pyrolyzing temperature between 600 C to 950 C;

pyrolyzing, at the pyrolyzing temperature, the in-feed material in the kiln for a period of minutes to produce an off-gas that includes dust and tar components;

directing the off-gas from the kiln to a steam reformer positioned downstream of the kiln, and injecting oxygen to allow a portion of the off-gas to combust to generate heat and steam, wherein the steam is used as a reaction medium to reform the tar into carbon-monoxide and hydrogen components;

subsequently directing the off-gas through a water scrubber stage, a methanation stage, and a carbon dioxide scrubbing stage, each stage being positioned downstream of the steam reformer, wherein the water scrubber stage includes counter-currently contacting the off-gas by water to cool the off-gas to a temperature below 100 degrees Celsius to remove water from the the off-gas, and wherein the methanation stage includes compressing the off-gas in a compressor and passing the compressed off-gas through a catalyst bed reactor where it is reacted with hydrogen to produce methane; and

splitting the off-gas into portions and directing at least one portion of the split off-gas to the kiln.

18. The method according to claim 17 , wherein the pyrolyzing temperature in the kiln is in the range of 750 C to 850 C and the in-feed material is pyrolyzed in the kiln in the temperature range of 750 to 850 degrees Celsius.

19. The method according to claim 18 , wherein the period of minutes is between 1 and 60 minutes.

20. The system according to claim 1 , wherein the water scrubber is configured to further remove from the off-gas at least one unwanted component selected from the group consisting of tar, hydrogen chloride, ammonia, and hydrogen sulfide.

21. The method according to claim 17 , wherein the proportion of the off-gas split off and directed to the kiln is 30% or less by volume.

22. The method according to claim 17 , wherein the primary output from the kiln is gas rather than liquid.

23. The method according to claim 17 , further comprising supplying oxygen to the steam reformer.

24. The method according to claim 17 , further comprising before entering the kiln, passing the in-feed material through a pre-dryer stage.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 10, 2024
From: ANERGY LIMITED
To: ACTINON PTE LTD
Reel/Frame 067946/0438 →
CHANGE OF ADDRESS Recorded May 8, 2024
From: ANERGY LIMITED
To: ANERGY LIMITED
Reel/Frame 067932/0309 →
CHANGE OF ASSIGNEE'S ADDRESS Recorded Aug 26, 2019
From: ANERGY LIMITED
To: ANERGY LIMITED
Reel/Frame 050167/0951 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2014
From: MARTELLA, MICHAEL; MARTELLA, MATTHEW
To: ANERGY LIMITED
Reel/Frame 033390/0256 →
Priority Claims (1)
GB 1202537.5 · Feb 14, 2012 · national
Continuity (1)
Related Publication 20150027054A1 · Jan 29, 2015
Cited By (1)
US 12,735,642