Organic electroluminescent materials and devices

1. A compound having the formula:

wherein R 1 and R 2 are optionally linked;

wherein R 1 and R 2 are independently selected from the group consisting of hydrogen, deuterium, partially or fully deuterated alkyl, partially or fully deuterated cycloalkyl, and combinations thereof;

wherein the sum of the number of carbon atoms in R 1 and R 2 is at least 2;

wherein R 3 , R 4 , R 5 , R 6 are optionally linked;

wherein R a and R b represent mono-, di-, tri- or tetra-substitution;

wherein X is selected from the group consisting of BR, NR, PR, O, S, Se, S═O, SO 2 , SiRR′, and GeRR′;

wherein R a , R b , R, R′, R 3 , R 4 , R 5 , and R 6 are independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;

wherein the compound is heteroleptic; and

wherein n is 1 or 2.

2. The compound of claim 1 , wherein X is O.

3. The compound of claim 1 , wherein R 1 is hydrogen and R 2 is selected from the group consisting of partially or fully deuterated alkyl, partially or fully deuterated cycloalkyl, and combinations thereof.

4. A compound having the formula:

wherein the sum of the number of carbon atoms in R 1 is at least 2;

wherein R 3 , R 4 , R 5 , R 6 are optionally linked;

wherein R a and R b represent mono-, di-, tri- or tetra-substitution;

wherein X is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO 2 , CRR′, SiRR′, and GeRR′;

wherein R a , R b , R, R′, R 3 , R 4 , R 5 , and R 6 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;

wherein n is 1 or 2, and

wherein R 1 is selected from the group consisting of alkyl, cycloalkyl, partially or fully deuterated variations thereof, and combinations thereof and R 2 is hydrogen.

5. The compound of claim 1 , wherein R 1 and R 2 are partially or fully deuterated alkyl.

6. The compound of claim 1 , wherein R 1 or R 2 are independently selected from the group consisting of partially or fully deuterated branched alkyl, partially or fully deuterated cyclic alkyl, partially or fully deuterated bicyclic alkyl, and partially or fully deuterated multicyclic alkyl.

7. The compound of claim 1 , wherein R 1 or R 2 is partially or fully deuterated iso-propyl.

8. The compound of claim 1 , wherein R 3 , R 4 , R 5 and R 6 are independently selected from the group consisting of hydrogen, deuterium, alkyl, arylalkyl, and combinations thereof.

9. The compound of claim 1 , wherein at least one of R 3 , R 4 , R 5 and R 6 comprises a branched alkyl, cyclic alkyl, bicyclic alkyl, a multicyclic alkyl, or a partially or fully deuterated variant thereof.

10. The compound of claim 1 , wherein R 3 , R 4 , R 5 or R 6 contain one or more deuterium atoms.

11. A first device comprising a first organic light emitting device, comprising:

an anode;

a cathode; and

an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:

wherein R 1 and R 2 are optionally linked;

wherein R 1 and R 2 are independently selected from the group consisting of hydrogen, deuterium, partially or fully deuterate alkyl, partially or fully deuterated cycloalkyl, and combinations thereof;

wherein the sum of the number of carbon atoms in R 1 and R 2 is at least 2;

wherein R 3 , R 4 , R 5 , R 6 are optionally linked;

wherein R a and R b represent mono-, di-, tri- or tetra-substitution;

wherein X is selected from the group consisting of BR, NR, PR, O, S, Se, S═O, SO 2 , SiRR′, and GeRR′;

wherein R a , R b , R, R′, R 3 , R 4 , R 5 , and R 6 are independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;

wherein the compound is heteroleptic; and

wherein n is 1 or 2.

12. The first device of claim 11 , wherein the first device is selected from the group consisting of a consumer product, an organic light-emitting device, a lighting panel, and a combination thereof.

13. The first device of claim 11 , wherein the organic layer is an emissive layer and the compound is a non-emissive dopant.

14. The first device of claim 11 , wherein the organic layer comprises a host, and the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan;

wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C n H 2n+1 , OC n H 2n+1 , OAr 1 , N(C n H 2n+1 ) 2 , N(Ar 1 )(Ar 2 ), CH═CH—C n H 2n+1 , C≡CC n H 2n+1 , Ar 1 , Ar 1 —Ar 2 , C n H 2n —Ar 1 ;

wherein n is from 1 to 10; and

wherein Ar 1 and Ar 2 are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.

15. The first device of claim 14 , wherein the host has the formula:

16. The first device of claim 11 , wherein the organic layer comprises a host, and the host is selected from the group consisting of:

and combinations thereof.

17. The compound of claim 1 , wherein the compound is selected from the group consisting of:

18. The compound of claim 4 , wherein the compound is selected from the group consisting of: