Method of making carbonate PCD and sintering carbonate PCD on carbide substrate
A method of forming a polycrystalline diamond body includes mixing a sintering agent with diamond powder to form a premixed layer, the sintering agent including at least one alkaline eat mewl carbonate; forming an infiltration layer adjacent to the premixed layer, the infiltration layer including an infiltrant material including at least one alkaline earth metal carbonate; and subjecting the premixed layer and the infiltration layer to high pressure high temperature conditions.
1. A method of forming a polycrystalline diamond body, comprising:
providing a premixed layer of a sintering agent and diamond powder, wherein the sintering agent comprises at least one alkaline earth metal carbonate;
placing an infiltration layer adjacent to and in contact with the premixed layer, the infiltration layer comprising an infiltrant material comprising at least one alkaline earth metal carbonate; and
subjecting the premixed layer and the infiltration layer to high pressure high temperature conditions sufficient to infiltrate the infiltrant material throughout the entire premixed layer.
2. The method of claim 1 , wherein the sintering agent further comprises a carbon additive.
3. The method of claim 1 , wherein the sintering agent further comprises an alkali metal carbonate.
4. The method of claim 1 , wherein the infiltrant material further comprises an alkali metal carbonate.
5. The method of claim 1 , wherein during the step of subjecting, no transition metal catalyst is introduced into the premixed layer.
6. The method of claim 1 , wherein the amount of infiltrant material provided as the infiltration layer is greater than or equal to the amount of infiltrant material that infiltrates through the premixed layer during the step of subjecting.
7. A method of forming a polycrystalline diamond body, comprising:
providing a premixed layer of a sintering agent and diamond powder, wherein the sintering agent comprises at least one alkaline earth metal carbonate;
placing an infiltration layer adjacent to and in contact with a first surface of the premixed layer, the infiltration layer comprising an infiltrant material comprising at least one alkaline earth metal carbonate; and
sintering the premixed layer to form a carbonate-based polycrystalline diamond body, the sintering comprising subjecting the premixed layer and the infiltration layer to high pressure high temperature conditions sufficient to cause diamond-to-diamond bonding between the diamond powder in the premixed layer and to infiltrate the infiltrant material into the premixed layer,
wherein after sintering the premixed layer, the first surface of the premixed layer forms an outer exposed surface of the carbonate-based polycrystalline diamond body.
8. The method of claim 7 , further comprising removing a carbonate layer formed from remaining infiltrant material that did not infiltrate during the sintering to expose the outer exposed surface of the carbonate-based polycrystalline diamond body.
9. The method of claim 7 , wherein the sintering agent has a melting temperature lower than the infiltrant material.
10. The method of claim 7 , wherein the infiltrant material infiltrates an entire depth of the premixed layer during sintering.