Dental materials based on hybrid monomers
The invention relates to dental materials which contain at least one compound of Formula I The materials are characterized by very good mechanical properties after curing.
1. Dental material which comprises at least one compound of Formula I
in which the variables have the following meanings:
A is an aliphatic linear or branched C 1 -C 15 hydrocarbon radical which can be interrupted by one or more O;
X, Y independently of each other in each case are absent or are —NH—CO—O—, wherein X and Y are not absent at the same time,
R 1 , R 2 independently of each other in each case are absent or are an aliphatic linear or branched C 1 -C 10 alkylene radical which can be interrupted by one or more O, wherein A, R 1 and R 2 together contain at least 3 C atoms,
R 3 is an aliphatic linear C 1 -C 3 alkyl radical,
R 4 , R 5 independently of each other in each case are hydrogen, methyl or ethyl, and
m, p independently of each other in each case are an integer from 1 to 3.
2. Dental material according to claim 1 , wherein the variables of Formula I have the following meanings:
A is an aliphatic linear or branched C 1 -C 8 hydrocarbon radical which can be interrupted by one or more O,
X is absent or is —NH—CO—O—,
Y is absent or is —NH—CO—O—, wherein X and Y are not absent at the same time,
R 1 is absent,
R 2 is absent or is an aliphatic linear C 1 -C 2 alkylene radical,
R 3 is methyl or ethyl,
R 4 , R 5 independently of each other are hydrogen or methyl, and
m, p independently of each other in each case are 1 or 2.
3. Material according to claim 1 which additionally comprises at least one radically polymerizable monomer for the radical polymerization.
4. Material according to claim 3 which comprises at least one multifunctional (meth)acrylate or a mixture of mono- and multifunctional (meth)acrylates.
5. Material according to claim 1 which comprises at least one filler.
6. Material according to claim 1 which comprises
a) 0.1 to 50 wt.-% of at least one compound of general formula I,
b) 0.01 to 10 wt.-% of at least one initiator,
c) 0 to 80 wt.-% other monomer(s),
d) 0 to 80 wt.-% filler(s) and
e) 0 to 70 wt.-% solvent,
in each case relative to the total mass of the material.
7. Material according to claim 6 for use as dental cement or dental filling composite which comprises
a) 0.1 to 40 wt.-% of at least one compound of general formula I,
b) 0.01 to 10 wt.-% of at least one initiator,
c) 0 to 50 wt.-% other monomer(s),
d) 10 to 80 wt.-% filler(s).
8. Material according to claim 6 for use as dental adhesive or coating material which comprises
a) 0.1 to 50 wt.-% of at least one compound of general formula I,
b) 0.01 to 10 wt.-% of at least one initiator,
c) 0 to 80 wt.-% other monomer(s),
d) 0 to 20 wt.-% filler(s),
e) 0 to 70 wt.-% solvents.
9. Material according to claim 6 for the manufacture of dental prostheses or artificial teeth which comprises
a) 0.1 to 50 wt.-% of at least one compound of general formula I,
b) 0.01 to 10 wt.-% of at least one initiator, and
c) 0 to 80 wt.-% other monomer(s),
d) 0 to 40 wt.-% filler(s).
10. Material according to claim 6 for the manufacture of inlays, onlays, crowns or bridges which contains
a) 0.1 to 50 wt.-% of at least one compound of general formula I,
b) 0.01 to 10 wt.-% of at least one initiator, and optionally
c) 0 to 60 wt.-% other monomer(s), and optionally
d) 10 to 80 wt.-% filler(s).
11. Material according to claim 1 for intraoral use to restore damaged teeth.
12. Material according to claim 11 for use as dental cement, dental filling composite, dental adhesive or veneering material.
13. Method of using the material according to claim 1 for the extraoral manufacture or repair of dental restorations.
14. Method of using the material according to claim 13 for the manufacture of artificial teeth, prostheses, inlays, onlays, crowns or bridges.
15. Material according to claim 3 which additionally comprises at least one initiator for the radical polymerization.
16. Material according to claim 6 , which comprises
a) 1 to 40 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator,
c) 0 to 60 wt.-% other monomer(s),
d) 0 to 80 wt.-% filler(s) and
e) 0 to 70 wt.-% solvent,
in each case relative to the total mass of the material.
17. Material according to claim 6 , which comprises
a) 2 to 30 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator,
c) 5 to 50 wt.-% other monomer(s),
d) 0 to 80 wt.-% filler(s) and
e) 0 to 70 wt.-% solvent,
in each case relative to the total mass of the material.
18. Material according to claim 7 for use as dental cement or dental filling composite which comprises
a) 1 to 30 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator,
c) 0 to 40 wt.-% other monomer(s),
d) 20 to 80 wt.-% filler(s).
19. Material according to claim 7 for use as dental cement or dental filling composite which comprises
a) 5 to 30 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator,
c) 5 to 40 wt.-% other monomer(s),
d) 30 to 80 wt.-% filler(s).
20. Material according to claim 8 for use as dental adhesive or coating material which comprises
a) 1 to 40 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator,
c) 5 to 60 wt.-% other monomer(s),
d) 0 to 20 wt.-% filler(s),
e) 0 to 60 wt.-% solvents.
21. Material according to claim 8 for use as dental adhesive or coating material which comprises
a) 2 to 30 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator,
c) 5 to 50 wt.-% other monomer(s),
d) 0 to 20 wt.-% filler(s),
e) 0 to 50 wt.-% solvents.
22. Material according to claim 8 wherein the solvents comprise water and/or ethanol.
23. Material according to claim 9 for the manufacture of dental prostheses or artificial teeth which comprises
a) 1 to 40 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator, and
c) 0 to 60 wt.-% other monomer(s),
d) 0 to 40 wt.-% filler(s).
24. Material according to claim 9 for the manufacture of dental prostheses or artificial teeth which comprises
a) 2 to 30 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator, and
c) 5 to 50 wt.-% other monomer(s),
d) 0 to 40 wt.-% filler(s).
25. Material according to claim 10 for the manufacture of inlays, onlays, crowns or bridges which contains
a) 1 to 40 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator, and optionally
c) 0 to 50 wt.-% other monomer(s), and optionally
d) 15 to 80 wt.-% filler(s).
26. Material according to claim 10 for the manufacture of inlays, onlays, crowns or bridges which contains
a) 2 to 30 wt.-% of at least one compound of general formula I,
b) 0.1 to 3.0 wt.-% of at least one initiator, and optionally
c) 5 to 50 wt.-% other monomer(s), and optionally
d) 20 to 80 wt.-% filler(s).