Method of development and use of catalyst-functionalized catalytic particles to increase the mass transfer rate of solvents used in acid gas cleanup
The present invention relates to methods for improving carbon capture using entrained catalytic-particles within an amine solvent. The particles are functionalized and appended with a CO 2 hydration catalyst to enhance the kinetics of CO 2 hydration and improve overall mass transfer of CO 2 from an acid gas.
1. A biphasic scrubbing solution comprising an amine solvent with catalyst-appended particles suspended therein, wherein the particles comprise a surface-appended carbon dioxide (CO 2 ) adsorption catalyst and a particle, wherein the catalyst is appended to a surface of a particle through a particle linker and a catalyst linker, the catalyst linker being selected from:
and
further wherein the particles have a width of less than about 500 microns.
2. The biphasic scrubbing solution of claim 1 , wherein the catalyst linker comprises an electrophile or electrophile salt.
3. The biphasic scrubbing solution of claim 1 , wherein the catalyst-appended particles are selected from the group consisting of:
or mixtures thereof, and further wherein
represents the particle.
4. The biphasic scrubbing solution of claim 1 , wherein the particles have a width of between about 0.1 and 500 microns.
5. The biphasic scrubbing solution of claim 1 , wherein the particles have a width of less than 100 nanometers.
6. The biphasic scrubbing solution of claim 1 , wherein the amine solvent is selected from the group consisting of monoethanolamine (MEA), 1-amino-2-propanol (1A2P), 3-amino-1-propanol, 2-amino-1-propanol, 2-amino-1-butanol, 1-amino-2-butanol, 3-amino-2-butanol, 2-(methylamino)ethanol (MAE), 2-(ethylamino)ethanol, morpholine, piperazine (PZ), 1-methylpiperazine (NMP), 2-methylpiperazine, hydroxypiperidine, 2-piperidineethanol, N-aminoethylpiperazine (AEP), aminopropylmorpholine, 4-aminopiperidine, 2-amino-2-methyl-1-propanol (AMP), diethanolamine (DEA), diisopropanolamine (DIPA), glycine, alanine, β-alanine, sarcosine, ethylene diamine (EDA), 1,3-propanediamine, 1,4-butanediamine, 1,5-pentanediamine, 1,6-hexanediamine, methyldiethanolamine (MDEA), triethanolamine (TEA), dimethylethanolamine (DMEA), N,N,N′,N′-tetramethyl-1,8-naphthalenediamine, diethylmonoethanolamine, dipropylmonoethanolamine, 1,4-dimethylpiperazine, N N,N′,N′-tetramethyl-1,6-hexanediamine, N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine, N,N,N′,N′,N″-pentamethyldiethylenetriamine, N,N,N′,N′-tetramethylethylenediamine, N,N,N′,N′-tetramethylpropane-1,3-diamine, N,N,N′,N′-tetramethylbutane-1,4-diamine, N,N,N′,N′-tetramethyl-1,5-pentanediamine, alkali carbonate, and mixtures thereof.
7. The biphasic scrubbing solution of claim 1 , wherein the particles comprise between about 0.5 to 2.5 percent by weight of the biphasic scrubbing solution.
8. The biphasic scrubbing solution of claim 1 , wherein the amine solvent comprises an amine dissolved in water, wherein the amine comprises between about 15 to about 50 weight percent of the amine solvent.
9. The biphasic scrubbing solution of claim 1 , wherein the amine solvent has a viscosity of between about 3 to about 10 cP.
10. The biphasic scrubbing solution of claim 1 , wherein the particles are hydrophobic.
11. The biphasic scrubbing solution of claim 1 , wherein the particles comprise activated carbon particles.
12. The biphasic scrubbing solution of claim 1 , wherein the particles are functionalized to increase positive zeta potential.
13. The biphasic scrubbing solution of claim 12 , wherein the particles are functionalized by oxidation.
14. The biphasic scrubbing solution of claim 12 , wherein the particles are functionalized by surface-appending with a functional group selected from the group consisting of an alcohol, a primary amine, a tertiary amine, and an amino silane.
15. The biphasic scrubbing solution of claim 14 , wherein the catalyst of the catalyst-appended particles comprises a carbonic anhydrase mimic catalyst of a bidentate transition-metal ligand complex.
16. The biphasic scrubbing solution of claim 15 , wherein the carbonic anhydrase mimic catalyst comprises a structure of:
where:
(a) M is any group VII B through XII B element;
(b) x=neutral sigma donor or monovalent anion; and
(C)
R 1 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ] repeats;
OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q]+[A]-; and
where A=monovalent anion: Cl, Br, I, F, PF 6 , BF 4 , acetate, trifluoroacetate, ClO 4 , NO 3 , and
Q=monovalent cation: P(R) 3 , R=alkyl, cyclic alkyl, Aryl, O-alkyl, O-Aryl; and
N(R) 3 , R=alkyl, cyclic alkyl, N-heterocyclic ring, imidazole; and
R 2 =CE; where C=any alkyl, cyclic alkyl, aryl, and E=OH, NH 2 , N(R) 3 , R=alkyl, cyclic alkyl, N-heterocyclic ring, imidazole, morpholine.
17. The biphasic scrubbing solution of claim 15 , wherein the carbonic anhydrase mimic catalyst comprises a structure selected from the group consisting of:
where:
(a) M is any group VII B through XII B element;
(b) x=neutral sigma donor or monovalent anion;
(c)
where R 1 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO; NO 2 ; amine, amide, carbonyl, Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] −
R 2 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] −
R 3 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] −
R 4 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] −
R 5 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] −
R 6 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] −
R 7 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] −
R 8 =H, any alkyl, RCOOH (R=alkyl ranging from 0-10 carbons); OligoPEG, phosphate, ROH (R=alkyl ranging from 0-5 carbons), —[OCH 2 CH 2 ]— repeats; OH; SO 3 ; NO 2 ; amine, amide, carbonyl Cl, Br, I, F, BH 3 , [CH 2 Q] + [A] − ; and
where A=monovalent anion: Cl, Br, I, F, PF 6 , BF 4 , acetate, trifluoroacetate, ClO 4 , NO 3 , and
Q=monovalent cation: P(R) 3 , R=alkyl, cyclic alkyl, Aryl, O-alkyl, O-Aryl;
N(R) 3 , R=alkyl, cyclic alkyl, N-heterocyclic ring, imidazole; and
(d)
where
E 1 =N, P, S, B;
E 2 =N, P, S, O, B; n=1-10; and wherein E in C-E-M is O.
18. The biphasic scrubbing solution of claim 15 , wherein the carbonic anhydrase mimic catalyst comprises a bidentate transition-metal ligand complex selected from the group consisting of:
19. A method for increasing carbon capture from a gas comprising contacting the gas with the biphasic scrubbing solution of claim 1 .
20. A biphasic scrubbing solution comprising an amine solvent with catalyst-appended particles suspended therein, wherein the catalyst-appended particles are selected from the group consisting of:
or mixtures thereof, and further wherein
represents the particle.