IP Library Granted Patent US 10,334,874
Granted Patent B2
US 10,334,874 · App. 15/099,971 · Granted Jul 2, 2019

Method for producing microcrystalline cellulose from tobacco and related tobacco product

Inventors: Medwick Vaughan Byrd, Jr. (Raleigh, NC); Paul Stuart Chapman (Winston-Salem, NC); Samuel Mark Debusk (Lexington, NC); Grady Lance Dooly (Winston-Salem, NC); Anthony Richard Gerardi (Winston-Salem, NC); David Neil McClanahan (Winston-Salem, NC)
Assignees: R. J. Reynolds Tobacco Company; North Carolina State University
A24B15/302A24B13/00A24B15/12A24B15/241C08H8/00C08L1/04C08L97/02C09J101/04D21C3/02D21H11/02D21H11/12
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Quick Facts
Patent No.
US 10,334,874
App. No.
15/099,971
Granted
Jul 2, 2019
Kind
B2
Abstract

Methods for producing dissolving grade pulp and microcrystalline cellulose from tobacco are provided. The methods include chemical pulping a tobacco input to form a tobacco pulp. Chemical pulping the tobacco input includes combining the tobacco input with a strong base defining a weight from about 5% to about 50% of the tobacco input, and heating the tobacco input and the strong base with an H-factor from about 500 to about 3,300. Further, the methods include bleaching the tobacco pulp to produce a dissolving grade pulp. Bleaching the tobacco pulp may include chlorination of the tobacco pulp with a chlorine dioxide solution, and caustic extraction of the tobacco pulp with a second strong base. A related tobacco-derived microcrystalline cellulose product is also provided, which can be used as a binder, a filler, and/or a texturizer in a tobacco product, such as a smokeless tobacco product.

Claims (18)

1. A dissolving grade pulp derived from tobacco, the dissolving grade pulp characterized by a brightness of at least about 83%, an alpha-cellulose concentration of at least about 88% by weight, a beta and a gamma cellulose content, and a degree of polymerization of about 100 to about 750, wherein the dissolving grade pulp is characterized by a kappa number between about 20 and about 30.

2. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is formed by subjecting a tobacco input to the following operations:

chemical pulping the tobacco input to form a tobacco pulp; and

bleaching the tobacco pulp.

3. The dissolving grade pulp of claim 2 , wherein chemical pulping the tobacco input comprises:

combining the tobacco input with a strong base; and

heating the tobacco input and the strong base.

4. The dissolving grade pulp of claim 2 , wherein bleaching the tobacco pulp comprises:

chlorination of the tobacco pulp with a chlorine dioxide solution; and

caustic extraction of the tobacco pulp with a second strong base.

5. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by a quantity of hemicelluloses of about 0.5% to about 10% by weight of the dissolving grade pulp.

6. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by a quantity of lignin of about 0% to about 0.2% by weight of the dissolving grade pulp.

7. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by a quantity of pentosan of about 0% to about 5% by weight of the dissolving grade pulp.

8. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by a quantity of ash of about 0% to about 0.15% by weight of the dissolving grade pulp.

9. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by a quantity of alcohol-benzene extractives of about 0% to about 0.5% by weight of the dissolving grade pulp.

10. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by a viscosity of about 2 centipoise to about 15 centipoise, the viscosity being measured by a capillary viscometer in a 0.5 wt-% cupriethylenediamine solution.

11. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by a copper number of about 0.1 to about 1.2.

12. The dissolving grade pulp of claim 1 , wherein the dissolving grade pulp is characterized by between about 5% and about 15% of the dissolving grade pulp having a particle size of less than about 10 μm, the particles of the dissolving grade pulp being sized to pass through a screen mesh.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 18, 2016
From: BYRD, MEDWICK VAUGHAN, JR
To: NORTH CAROLINA STATE UNIVERSITY
Reel/Frame 038307/0352 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 18, 2016
From: CHAPMAN, PAUL STUART; DEBUSK, SAMUEL MARK; DOOLY, GRADY LANCE; GERARDI, ANTHONY RICHARD; MCCLANAHAN, DAVID NEIL
To: R. J. REYNOLDS TOBACCO COMPANY
Reel/Frame 038307/0548 →
Continuity (2)
Division 13451032 · Apr 19, 2012
Related Publication 20160227834A1 · Aug 11, 2016