Exhaust gas purification material
An exhaust gas purification material according to the present invention is provided with a particulate filter 10 that traps particulate matter in exhaust gas and contains an SCR catalyst for adsorbing ammonia and reducing NOx in the exhaust gas. A maximum allowable adsorption amount of ammonia adsorbable by the filter 10 differs between an upstream portion 10 a of the filter 10 including an exhaust gas inlet-side end 10 c , and a downstream portion 10 b of the filter 10 including an exhaust gas outlet-side end 10 d . The SCR catalyst contained in the upstream portion 10 a and the SCR catalyst contained in the downstream portion 10 b are qualitatively different. A ratio (B/A) of a maximum allowable adsorption amount of ammonia A in the upstream portion 10 a and a maximum allowable adsorption amount of ammonia B in the downstream portion 10 b satisfies the relationship 1.1≤(B/A)≤2.
1. An exhaust gas purification material that is disposed in an exhaust passage of an internal combustion engine, and purifies exhaust gas emitted by the internal combustion engine, the exhaust gas purification material comprising:
a particulate filter that traps particulate matter in the exhaust gas and contains an SCR catalyst for adsorbing ammonia and reducing NOx in the exhaust gas,
wherein an upstream portion of the filter including an exhaust gas inlet-side end, and a downstream portion of the filter including an exhaust gas outlet-side end, each contain a zeolite catalyst as the SCR catalyst,
the upstream portion and the downstream portion each comprise a different type of the zeolite catalyst, wherein the zeolite catalyst contained in the upstream portion is β-zeolite and the zeolite catalyst contained in the downstream portion is SAPO-based zeolite, and
a ratio (B/A) of a maximum allowable adsorption amount of ammonia A in the upstream portion and a maximum allowable adsorption amount of ammonia B in the downstream portion satisfies the relationship 1.1≤(B/A)≤2.
2. The exhaust gas purification material according to claim 1 , wherein a value of ratio (B/A) of the maximum allowable adsorption amount of ammonia A in the upstream portion and the maximum allowable adsorption amount of ammonia B in the downstream portion satisfies 1.1≤(B/A)≤1.5.
3. The exhaust gas purification material according to claim 1 , wherein
the upstream portion includes a portion corresponding to at least 20% of the length of the filter from the exhaust gas inlet-side end of the filter towards the exhaust gas outlet, and
the downstream portion includes a portion corresponding to at least 20% of the length of the filter from the exhaust gas outlet-side end of the filter towards the exhaust gas inlet.
4. The exhaust gas purification material according to claim 1 , wherein the filter includes:
a substrate of wall flow structure, having inlet cells in which only an exhaust gas inflow end is open, outlet cells adjacent to the inlet cells and in which only an exhaust gas outflow end is open, and a porous partition wall that separates the inlet cells and the outlet cells;
an upstream catalyst layer provided within the partition wall in the upstream portion and containing an SCR catalyst; and
a downstream catalyst layer provided within the partition wall in the downstream portion and containing an SCR catalyst,
wherein the upstream catalyst layer is formed in such a manner that 80 mass % or more of the total amount of the SCR catalyst is present in a portion corresponding to up to 80% of the thickness of the partition wall, from a surface of the partition wall in contact with the inlet cells towards the outlet cells, and
the downstream catalyst layer is formed in such a manner that 80 mass % or more of the total amount of the SCR catalyst is present in a portion corresponding to up to 80% of the thickness of the partition wall, from the surface of the partition wall in contact the outlet cells towards the inlet cells.
5. An exhaust gas purification device, comprising:
the exhaust gas purification material according to claim 1 ; and
reducing agent solution supply part for supplying a reducing agent solution for generating ammonia, from upstream of the exhaust gas purification material in the exhaust passage.