Laminated film and packaging bag
A laminated film including a resin substrate, and a coating layer on the resin substrate. The coating layer contains a water-soluble polymer, at least one of a silane coupling agent and a hydrolysate thereof, at least one of a metal alkoxide and a hydrolysate thereof, and an inorganic layered compound.
1. A laminated film, comprising:
a resin substrate;
a coating layer on the resin substrate; and,
a deposited thin film layer in between the resin substrate and the coating layer, the deposited thin film layer contains a silicon oxide and has a thickness of 5 to 100 nm,
wherein the coating layer contains a water-soluble polymer, at least one of a silane coupling agent and a hydrolysate thereof, at least one of a metal alkoxide and a hydrolysate thereof, and an inorganic layered compound, and
wherein the content of the inorganic layered compound in the coating layer is 2 to 10 mass %.
2. The laminated film of claim 1 , wherein the resin substrate has a biaxially oriented polypropylene film.
3. The laminated film of claim 1 , wherein the laminated film includes an underlayer between the resin substrate and the coating layer.
4. The laminated film of claim 3 , wherein
the underlayer contains an organic polymer as a main component, and
the organic polymer contains at least one of polyols, organosilane compounds, water-based polyurethane resins, and reaction products of the polyols and the organosilane compounds.
5. The laminated film of claim 1 , wherein at least one of the silane coupling agent and the hydrolysate thereof has an epoxy group.
6. The laminated film of claim 1 , wherein the content of the silane coupling agent and the hydrolysate thereof in the coating layer is 1 to 15 mass % in total.
7. The laminated film of claim 1 , wherein the laminated film has a lamination strength of 2 N/15 mm or more.
8. The laminated film of claim 1 , wherein the laminated film has a moisture permeation rate of 2 g/m 2 /day or less.
9. The laminated film of claim 1 , wherein the laminated film has an oxygen permeation rate of 2 ml/m 2 /day or less.
10. A packaging bag
comprising the laminated film of claim 1 .
11. The laminated film of claim 1 , wherein the content of the inorganic layered material in the coating layer is from 2 mass % to 5 mass %.
12. The laminated film of claim 11 , wherein the content of the inorganic layered material in the coating layer is from 3 mass % to 5 mass %.
13. The laminated film of claim 11 , wherein the inorganic layered material is montmorillonite.
14. A laminated film, comprising:
a resin substrate having a biaxially oriented polypropylene film;
a deposited thin film layer, which contains a silicon oxide and has a thickness of 5 to 100 nm;
an underlayer containing an organic polymer as a main component, the underlayer being located between the resin substrate and the deposited thin film layer; and
a coating layer on a side opposite to the underlayer side of the deposited thin film layer, the coating layer contains a water-soluble polymer, at least one of a silane coupling agent and a hydrolysate thereof, at least one of a metal alkoxide and a hydrolysate thereof, and an inorganic layered compound, wherein the content of the inorganic layered compound in the coating layer is 2 to 10 mass %.
15. The laminated film of claim 14 , wherein the organic polymer in the underlayer contains at least one of polyols, organosilane compounds, water-based polyurethane resins, and reaction products of the polyols and the organosilane compounds.
16. The laminated film of claim 14 , wherein the laminated film has a lamination strength of 2 N/15 mm or more.
17. The laminated film of claim 14 , wherein the laminated film has a moisture permeation rate of 2 g/m 2 /day or less.
18. The laminated film of claim 14 , wherein the laminated film has an oxygen permeation rate of 2 ml/m 2 /day or less.
19. A packaging bag
comprising the laminated film of claim 14 .
20. The laminated film of claim 14 , wherein the content of the inorganic layered material in the coating layer is from 2 mass % to 5 mass %.
21. The laminated film of claim 20 , wherein the inorganic layered material is montmorillonite.