IP Library Granted Patent US 10,343,301
Granted Patent B2
US 10,343,301 · App. 14/768,533 · Granted Jul 9, 2019

Process for producing a moulding using a water-soluble casting mould and material system for the production thereof

Inventors: Daniel Günther (München, DE); Ingo Gnüchtel (Merching, DE); Beat Karrer (Zürich, CH)
Assignees: VOXELJET AG; FLUIDSOLIDS AG
B28B7/342B28B7/346B28B7/36B29C33/52B29C33/56B29C64/10B29C64/165B29C33/3842
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Quick Facts
Patent No.
US 10,343,301
App. No.
14/768,533
Granted
Jul 9, 2019
Kind
B2
Abstract

A method for producing molded parts ( 16 ), a water-soluble casting mold ( 6 ) being produced in a first step using a layering method, in particular using a powder bed-based layering method. In a second step, the surface of the casting mold ( 6 ) is sealed with the aid of a material ( 9; 10 ). A casting of the molded part ( 16 ) is then formed by filling the casting mold ( 6 ) with a free-flowing, hardenable material ( 13 ), in particular a hydraulically setting material. After the casting has solidified, the casting mold ( 6 ) is dissolved with the aid of an aqueous solution ( 18 ), in particular a heated aqueous solution ( 18 ). The present application furthermore relates to a material system for producing a water-soluble casting mold ( 6 ), comprising at least one water-soluble material for building a casting mold ( 6 ) in a layering method, as well as comprising at least one material ( 9; 10 ) for sealing the surface of the casting mold ( 6 ).

Claims (60)

1. A method for producing a molded part, comprising the following steps:

a) producing a water-soluble casting mold using a layering method, wherein the layering method is a powder bed-based layering method where particulate material is applied in thin layers and selectively printed upon with a computer-controlled print head;

b) sealing the surface of the casting mold with a sealing material including at least one water insoluble material;

c) generating a casting of the molded part by filling the casting mold with a free-flowing, hardenable material; and

d) dissolving the casting mold with the aid of an aqueous solution, characterized in that the casting mold is produced in a 3D printing method;

wherein the particulate material includes a sand, a gypsum, a metal, or a ceramic powder:

the sealing material penetrates pores between individual particles of the casting mold;

a material of the casting mold in the layering method includes a binder;

the hardenable material is capable of a binding action with the binder or the partiuclate material, and

the sealing material prevents the binding action.

2. The method according to claim 1 , characterized in that the surface of the casting mold is sealed by immersion in a bath, by being sprayed and/or by being brushed with the sealing material.

3. The method according to claim 1 , characterized in that an underpressure above an ambient pressure or an overpressure below the ambient pressure is applied to the casting mold when it is filled with the free-flowing, hardenable material, and/or the casting mold is subjected to a shaking motion or a temperature increase.

4. The method according to claim 1 , characterized in that the casting mold is dissolved by immersion in a bath containing the heated aqueous solution.

5. The method of claim 4 , wherein the dissolution is accelerated by:

movements of the casting mold within the bath; or

the application of ultrasound.

6. The method according to claim 1 , characterized in that the hardenable material includes a casting polyamide.

7. The method of claim 1 , wherein the free-flowing, hardenable material is a hydraulically setting material.

8. The method of claim 1 , wherein the aqueous solution is a heated aqueous solution.

9. The method of claim 7 , wherein the water-soluble casting mold includes at least one water-soluble binder.

10. The method of claim 9 , wherein the at least one water-soluble binder includes at least one inorganic compound.

11. The method of claim 10 , wherein the at least one water-soluble binder includes at least one polysaccharide, at least one salt and/or at least one water-soluble polymer, or a mixture thereof.

12. The method of claim 9 , wherein the sealing material includes a water-insoluble material including a wax or a water-insoluble polymer.

13. The method of claim 12 , wherein

the surface of the casting mold is sealed by immersion in a bath, by being sprayed and/or by being brushed with the sealing material;

an underpressure above an ambient pressure or an overpressure below the ambient pressure is applied to the casting mold when it is filled with the free-flowing, hardenable material, and/or

the casting mold is subjected to a shaking motion or a temperature increase; and

the casting mold is dissolved by immersion in a bath containing the aqueous solution, the dissolution being accelerated by movements of the casting mold within the bath or by a temperature increase and/or by the application of ultrasound.

14. The method of claim 1 , wherein the water-soluble casting mold is produced from a material system including

a) at least one water-soluble material for building a casting mold in a layering method, which comprises at least one particulate material as well as at least one water-soluble binder; and

b) the sealing material for sealing the surface of the casting mold.

15. The method of claim 14 , wherein the sealing material for sealing the surface of the casting mold includes a wax, at least one fatty acid, at least one water-insoluble polymer, stearyl alcohol and/or cetyl alcohol, or a mixture thereof.

16. The method of claim 15 , wherein

the surface of the casting mold is sealed by immersion in a bath, by being sprayed and/or by being brushed with the sealing material;

an underpressure above an ambient pressure or an overpressure below the ambient pressure is applied to the casting mold when it is filled with the free-flowing, hardenable material, and/or

the casting mold is subjected to a shaking motion or a temperature increase; and

the casting mold is dissolved by immersion in a bath containing the aqueous solution, the dissolution being accelerated by movements of the casting mold within the bath or by a temperature increase and/or by the application of ultrasound.

17. The method of claim 1 , wherein the dissolving of the casting mold is after the casting has solidified and the aqueous solution is temperature controlled.

18. The method of claim 1 , wherein the binding action includes a chemical reaction of the hardenable material with the binder or the partiuclate material, and wherein the sealing material prevents the chemical reaction.

19. The method of claim 1 , wherein the method includes a step of washing the water-insoluble material off of the molded part.

20. The method of claim 1 , wherein the hardenable material includes a free-flowing material that transitions to a hardened state by a polymerization reaction.

21. The method of claim 1 , wherein the casting mold has a rough surface and the sealing material smooths the surface.

22. The method of claim 1 , wherein the casting mold is cleaned and a surface is mechanically processed before the step of sealing.

23. The method of claim 1 , wherein the sealing material includes a wax, a fatty acid, a water-insoluble polymer, a stearyl alcohol, or a cetyl alcohol.

24. The method of claim 1 , wherein the binding action includes hardening by forming a crystalline structure.

25. A method of for producing a molded part, comprising the following steps:

a. producing a water-soluble casting mold using a layering method, wherein the layering method is a powder bed-based layering method where particulate material is applied in thin layers and selectively printed upon with a computer-controlled print head;

b. sealing the surface of the casting mold with a sealing material including a water insoluble material including at least one water insoluble material;

c. generating a casting of the molded part by filling the casting mold with a free-flowing, hardenable material; and

d. dissolving the casting mold with the aid of a heated aqueous solution, wherein the casting mold is produced in a 3D printing method;

the sealing material penetrates pores between individual particles of the casting mold;

a material of the casting mold in the layering method includes a binder;

the hardenable material is capable of a binding action with the binder or the partiuclate material, and

the sealing material prevents the binding action.

26. The method of claim 25 , wherein

the surface of the casting mold is sealed by immersion in a bath, by being sprayed and/or by being brushed with the sealing material;

an underpressure above an ambient pressure or an overpressure below the ambient pressure is applied to the casting mold when it is filled with the free-flowing, hardenable material, and/or

the casting mold is subjected to a shaking motion or a temperature increase; and

the casting mold is dissolved by immersion in a bath containing the aqueous solution, the dissolution being accelerated by movements of the casting mold within the bath or by a temperature increase and/or by the application of ultrasound;

and wherein the sealing material includes a wax, at least one fatty acid, at least one water-insoluble polymer, stearyl alcohol and/or cetyl alcohol, or a mixture thereof.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 7, 2021
From: FLUID SOLIDS AG
To: VOXELJET AG
Reel/Frame 056776/0266 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 20, 2017
From: KARRER, BEAT
To: FLUIDSOLIDS AG
Reel/Frame 042084/0244 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 20, 2017
From: GUNTHER, DANIEL; GNUCHTEL, INGO
To: VOXELJET AG
Reel/Frame 042084/0315 →
Priority Claims (1)
DE 10 2013 003 303 · Feb 28, 2013 · national
Continuity (1)
Related Publication 20150375419A1 · Dec 31, 2015
Cited By (2)
US 12,285,798 US 12,420,151