Hydrogen generating system
The present invention relates to a solid fuel, a system and a method for generating hydrogen. The solid fuel comprises sodium borohydride, catalyst loaded fibers and a binder, wherein the catalyst loaded fibers and the binder form a scaffold structure within which the sodium borohydride is positioned. The system comprises a fuel cartridge containing the solid fuel of the present invention for generating hydrogen gas, a reactor configured to house the fuel cartridge, a tank for storing water, a pump and a liquid conduit for conveying water from the tank to the fuel cartridge housed within the reactor to induce a hydrolysis reaction of the solid fuel contained in the fuel cartridge and a controller for regulating flow of the water.
1. A solid fuel for generating hydrogen, comprising:
sodium borohydride particles, catalyst loaded fibres and a binder, wherein the sodium borohydride particles are loosely disposed within a scaffold structure formed by the catalyst loaded fibres and the binder; and
wherein the catalyst loaded fibres are pre-loaded with catalyst selected from the group consisting of cobalt chloride, nickel chloride, chloroplatinic acid and chloroiridic acid or powder of a precious metal selected from the group consisting of platinum, iridium and ruthenium; and wherein the fibres are selected from the group consisting of carbon, glass, ceramic and combinations thereof.
2. The solid fuel according to claim 1 , wherein fibres of the catalyst loaded fibres are carbon fibres.
3. The solid fuel according to claim 1 , wherein fibres of the catalyst loaded fibres are glass fibres.
4. The solid fuel according to claim 1 , wherein fibres of the catalyst loaded fibres are ceramic fibres.
5. The solid fuel according to claim 2 , wherein the carbon fibres each having a diameter from 1 to 20 microns.
6. The solid fuel according to claim 2 , wherein the carbon fibres each having a length from 20 to 200 microns.
7. The solid fuel according to claim 1 , wherein the binder is selected from the group consisting of copolyamide, polyester resins, poly(vinyl acetate), polyacrylates, polymethacrylates, polycarbonates, polyvinylacetoacetal, polyvinylpropional, polyvinylbutyral, phenoxy resins, epoxy resins, urethane resins, cellulose esters and cellulose ethers.
8. The solid fuel according to claim 7 , wherein the binder is copolyamide polymer.
9. The solid fuel according to claim 1 , wherein the binder is present in the mixture in an amount from 1 to 10 wt % based on the total weight of the solid fuel.