Liquid crystal display device and method for manufacturing liquid crystal display device
The present invention provides a liquid crystal display device that is less prone to display defects and a decrease in the voltage holding ratio regardless of the presence or absence of an alignment film. The liquid crystal display device includes: a pair of substrates; a liquid crystal layer containing a liquid crystal material between the substrates; and a polymer layer for controlling alignment of liquid crystal molecules on a surface of at least one of the substrates, the substrates being substantially free of an alignment film in outermost surfaces thereof, the polymer layer being formed by polymerization of at least two kinds of radical polymerizable monomers in the liquid crystal layer, at least one of the radical polymerizable monomers being a compound having a structure that creates a ketyl radical as a result of hydrogen abstraction induced by light radiation.
1. A liquid crystal display device comprising:
a pair of substrates;
a liquid crystal layer containing a liquid crystal material between the substrates; and
a polymer layer for controlling alignment of liquid crystal molecules on a surface of at least one of the substrates,
the substrates being substantially free of an alignment film in outermost surfaces thereof,
the polymer layer being formed by polymerization of at least two kinds of radical polymerizable monomers in the liquid crystal layer,
at least one of the at least two kinds of radical polymerizable monomers being a compound having a structure that creates a ketyl radical as a result of hydrogen abstraction induced by light radiation and is represented by any of the formulas (2-2), (2-3), (2-4), and (2-6):
wherein each of R1 and R2 is -Sp1-P1;
P1 is acryloyloxy, methacryloyloxy, vinyl, vinyloxy, acryloylamino or methacryloylamino; and
Sp1 is C1 to C6 linear, branched or cyclic alkylene or alkyleneoxy, or a direct bond; and
another of the at least two kinds of radical polymerizable monomers is represented by the following formula (12):
wherein the at least one of the substrates includes a silane coupling layer on the outermost surface thereof, and the silane coupling layer is directly under and in contact with the polymer layer.
2. The liquid crystal display device according to claim 1 ,
wherein the silane coupling layer comprises a silane coupling compound having at least one functional group selected from the group consisting of vinyl, epoxy, amino, methacryl, acryl, mercapto, and isocyanato.
3. The liquid crystal display device according to claim 1 ,
wherein the liquid crystal material has negative dielectric constant anisotropy.
4. A method for producing a liquid crystal display device, comprising the steps of:
disposing a liquid crystal composition containing a liquid crystal material and at least two kinds of radical polymerizable monomers between a pair of substrates that are substantially free of an alignment film in outermost surfaces thereof; and
polymerizing the radical polymerizable monomers by irradiating the liquid crystal composition with light, thereby forming a polymer layer for controlling alignment of liquid crystal molecules on the surface of at least one of the substrates, at least one of the at least two kinds of radical polymerizable monomers being a compound having a structure that creates a ketyl radical as a result of hydrogen abstraction induced by the light radiation and is represented by any of the formulas (2-2), (2-3), (2-4), and (2-6):
wherein each of R1 and R2 is -Sp1-P1;
P1 is acryloyloxy, methacryloyloxy, vinyl, vinyloxy, acryloylamino or methacryloylamino; and
Sp1 is C1 to C6 linear, branched or cyclic alkylene or alkyleneoxy, or a direct bond; and
another of the at least two kinds of radical polymerizable monomers is represented by the following formula (12):
and further, forming a silane coupling layer on the outermost surface of the at least one of the substrates, before the step of disposing the liquid crystal composition between the substrates, such that the silane coupling layer is directly under and in contact with the polymer layer.
5. The method for producing a liquid crystal display device according to claim 4 ,
wherein the silane coupling layer comprises a silane coupling compound having at least one functional group selected from the group consisting of vinyl, epoxy, amino, methacryl, acryl, mercapto, and isocyanato.
6. The method for producing a liquid crystal display device according to claim 4 ,
wherein the liquid crystal material has negative dielectric constant anisotropy.