Sealed nonaqueous electrolyte secondary battery
The present invention provides a sealed nonaqueous electrolyte secondary battery which is equipped with a current interrupt device that is actuated by a rise in internal pressure of a battery case and in which the current interrupt device is actuated in a speedy and stable manner during an overcharge. In the sealed nonaqueous electrolyte secondary battery, an electrode body formed by a positive electrode 10 and a negative electrode that oppose each other via a separator, an electrolyte, and an overcharge inhibitor are housed in the battery case. The positive electrode 10 includes a positive electrode current collector 12 and a positive electrode active material layer 14 which is formed on the current collector and which mainly contains a positive electrode active material. In addition, a conductive material layer 16 which mainly contains a conductive material is formed between the positive electrode active material layer 14 and the separator. A porosity of the conductive material layer 16 is 35% or more and 55% or less.
1. A sealed nonaqueous electrolyte secondary battery in which an electrode body having a positive electrode and a negative electrode that oppose each other via a separator, an electrolyte, and an overcharge inhibitor made of a compound that generates gas when a prescribed battery voltage is exceeded are housed in a battery case, this sealed nonaqueous electrolyte secondary battery including a current interrupt device that is actuated when pressure inside the battery case rises as a result of generation of the gas, wherein
the positive electrode includes a positive electrode current collector and a positive electrode active material layer disposed on the positive electrode current collector
the positive electrode active material layer mainly contains a positive electrode active material,
the positive electrode also includes a conductive material layer which mainly contains a conductive material,
the conductive material layer defines an outermost surface of the positive electrode located between the positive electrode active material layer and the separator, the conductive material is at least one of conductive carbon materials,
the positive electrode active material is at least one of compounds containing lithium and a transition metal element,
the conductive material layer has a porosity of 35% or higher and 55% or lower,
the overcharge inhibitor is infiltrated into the conductive material layer,
the sealed nonaqueous electrolyte secondary battery is configured to generate the gas in an amount necessary for operating the current interrupt device when the prescribed battery voltage is exceeded, and
an average particle diameter of the conductive carbon materials is 5 μm or more and 15 μm or less.
2. The sealed nonaqueous electrolyte secondary battery according to claim 1 , wherein the positive electrode has a two-layered structure including the positive electrode active material layer disposed on the positive electrode current collector and the conductive material layer disposed on a surface of at least a part of the positive electrode active material layer.
3. The sealed nonaqueous electrolyte secondary battery according to claim 1 , wherein a specific surface area of the conductive material as measured by a nitrogen gas adsorption method is 1 m 2 /g or more and 30 m 2 /g or less.
4. The sealed nonaqueous electrolyte secondary battery according to claim 1 , wherein the conductive material includes at least graphite.
5. The sealed nonaqueous electrolyte secondary battery according to claim 1 , wherein the overcharge inhibitor includes cyclohexylbenzene and/or biphenyl.
6. The sealed nonaqueous electrolyte secondary battery according to claim 1 , wherein the overcharge inhibitor is in an amount of 0.5% by mass or more and 5% by mass or less with respect to 100% by mass of the electrolyte.
7. An assembled battery comprising a plurality of the sealed nonaqueous electrolyte secondary batteries according to claim 1 .
8. A vehicle equipped with the assembled battery according to claim 7 as a driving power supply.
9. The sealed nonaqueous electrolyte secondary battery according to claim 1 , wherein the conductive material layer does not contain the positive electrode active material.
10. The sealed nonaqueous electrolyte secondary battery according to claim 9 , wherein the conductive material layer further includes a binder.