Series of capsules comprising at least one drop of internal phase in a drop of intermediate phase and manufacturing method thereof

1. A method for manufacturing a series of capsules, each capsule comprising a liquid core and a gelled shell completely encapsulating the liquid core, the method comprising of the following steps:

separate conveying in a double wall of an intermediate phase intended to form the liquid core and a first solution containing a polyelectrolyte liquid capable of gelling intended for forming the gelled shell;

forming at the outlet of the double wall of a series of liquid bodies including one drop of intermediate phase coated with a peripheral film formed by the first solution, the first solution containing at least one surfactant prior to its contact with the intermediate phase;

detaching each liquid body away from the double wall and falling of each liquid body in a volume of air;

immersing each liquid body into a gelling solution containing a reagent capable of reacting with the polyelectrolyte of the film in order to make it pass from a liquid state to a gelled state and thereby form the gelled shell;

recovering the capsules formed with a ratio of the volume of the core to the volume of the shell being greater than 2;

the method comprising a step of forming at least one internal macroscopic drop of one internal phase in the intermediate phase, each liquid body formed at the outlet of the double wall comprising one internal macroscopic drop of an internal phase disposed in the intermediate phase;

wherein the intermediate phase is aqueous and the internal phase is oily.

2. The method of claim 1 wherein an internal pipe conveys the internal phase in an internal tube, the internal pipe defining an opening and the internal tube defining an opening for drop formation;

wherein the internal pipe is withdrawn in the internal tube such that the distance taken along the axis between the opening of the internal pipe and the opening for drop formation is between 10 times and 1000 times the diameter of the internal pipe taken at a downstream opening.

3. The method of claim 1 , wherein each intermediate drop of the intermediate phase formed at the outlet of the double wall comprises at least two internal drops placed in the intermediate phase.

4. The method of claim 1 , wherein the step of formation includes injection of the internal phase in a current of the intermediate phase flowing in the double wall so as to form internal macroscopic drops.

5. The method of claim 1 , wherein the injection of the internal phase is achieved through an internal duct arranged in the double wall, the internal duct opening advantageously at exit of the double wall.

6. The method of claim 1 , comprising the adjusting of the rate of injection of the internal phase in the intermediate phase relative to the rate of injection of the intermediate phase in order to adjust the number of internal macroscopic drops present in each intermediate drop formed at the outlet of the double wall.

7. The method of claim 1 , wherein the step of formation includes injection of the internal phase in a current of the intermediate phase flowing in the double wall so as to form internal macroscopic drops.

8. The method of claim 1 , comprising the adjusting of the rate of injection of the internal phase in the intermediate phase relative to the rate of injection of the intermediate phase in order to adjust the number of internal macroscopic drops present in each intermediate drop formed at the outlet of the double wall.

9. The method of claim 1 , wherein the viscosity of the internal phase forming the internal macroscopic drop is less than 10% of the viscosity of the intermediate phase during the formation of the internal macroscopic drop.