Formed body having a layer of thermoplastic resin
A formed body having a layer of a resin composition constituted by a thermoplastic resin and a barrier resin, wherein the layer of the resin composition forms, in a matrix of the thermoplastic resin, a layer structure in which the barrier resin is dispersed in the form of a lamellar dispersion phase stretching in one direction; and the ratio (a)/(b) of an aspect ratio (a) of the dispersion phase of the barrier resin near the surfaces of the layer and an aspect ratio (b) of the dispersion phase of the barrier resin in the central portion in the direction of thickness of the layer, is not more than 2.0. The formed body has the layer of the resin composition constituted by the thermoplastic resin and the barrier resin, and has a dispersion structure capable of exhibiting excellent barrier property despite of the single layer.
1. An injection-formed body having a layer of a resin composition constituted by a polyolefin resin and a barrier resin, wherein:
the barrier resin is an ethylene-vinyl alcohol copolymer;
the layer of said resin composition forms, in a matrix of the polyolefin resin, a layer structure in which the barrier resin is dispersed in the form of a lamellar dispersion phase stretching in one direction;
an aspect ratio (a) of the dispersion phase of the barrier resin in a surface portion near the surfaces of the layer is 2.5 to 4.0, an aspect ratio (b) of the dispersion phase of the barrier resin in the central portion in the direction of thickness of the layer is 1.6 to 3.0, a ratio (a)/(b) of the aspect ratio (a) and the aspect ratio (b) is 1.1 to not more than 2.0, the central portion in the direction of thickness of the layer stands for a range of 40 to 60% of the whole thickness of the layer that is regarded to be 100%, and the surface portion stands for the portions excluding the central portion;
the melt flow rate (MFRm) of said polyolefin resin is 0.1 to 1.8 g/10 min., while the melt flow rate (MFRb) of said barrier resin is 84.8 to 93.6 g/10 min., and the ratio (MFRb/MFRm) of the melt flow rate (MFRb) of said barrier resin and the melt flow rate (MFRm) of said polyolefin resin is 11 to 200.
2. The injection-formed body according to claim 1 , wherein said resin composition is blended with the barrier resin in an amount of 30 to 300 parts by weight per 100 parts by weight of the polyolefin resin.
3. The injection-formed body according to claim 1 , wherein said polyolefin resin is polypropylene resin.