Method for producing moulded articles
A method for producing molded articles from a base substance which is mixed with a solvent to produce a molding solution, and subsequently this solvent is at least partially removed from the molding solution and the molding solution is supplied to a device ( 8 ) for molding, the molding solution is supplied to a vertical cylindrical thin-film evaporator ( 2 ) and a horizontal cylindrical thick-film dissolver ( 4 ).
1. A method for preparing a spinning solution for producing lyocell fibers, comprising the steps of:
providing a base substance of cellulose;
mixing the base substance with a solvent to produce a solution;
subsequently removing at least a portion of the solvent from the solution to produce a spinning solution by feeding the solution to a vertical cylindrical thin-film evaporator ( 2 ) wherein evaporation takes place and thereafter a horizontal cylindrical thick-layer dissolver ( 4 ) wherein further evaporation takes place.
2. The method as claimed in claim 1 , wherein the solvent is an aqueous tertiary amine oxide.
3. The method as claimed in claim 2 , including concentrating the spinning solution in the thin-film evaporator ( 2 ) by water evaporation to a pre-dissolution state corresponding to an approximately 2.5 hydrate of a tertiary amine oxide.
4. The method as claimed in claim 3 , wherein the spinning solution of the thin-film evaporator ( 2 ) is concentrated to about 0.8 to 1.0 hydrate, dissolved and homogenized into a final spinning solution in the thick-layer dissolver ( 4 ) by water evaporation.
5. The method as claimed in claim 1 , wherein at least one of the thin-film evaporator ( 2 ) and the thick-layer dissolver ( 4 ) is operated at 80° to 180° C.
6. The method as claimed in claim 1 , wherein at least one of the thin-film evaporator ( 2 ) and the thick-layer dissolver ( 4 ) is operated at 100° to 150° C.
7. The method as claimed in claim 5 , wherein at least one of the thin-film evaporator ( 2 ) and the thick-layer dissolver ( 4 ) is operated under a vacuum of 20 to 200 mbar absolute.
8. The method as claimed in claim 5 , wherein at least one of the thin-film evaporator ( 2 ) and the thick-layer dissolver ( 4 ) is operated under a vacuum of 30 to 100 mbar absolute.
9. The method as claimed in claim 6 , including permanently monitoring the temperatures along the axes of at least one of the thin-film evaporator ( 2 ) and of the thick-layer dissolver ( 4 ).
10. The method as claimed in claim 9 , wherein the monitoring is carried out using an optical index, which is between 1.47 and 1.52.
11. The method as claimed in claim 9 , wherein the monitoring is carried out using an optical index, which is between 1.48 and 1.50.
12. The method as claimed in claim 2 , wherein the spinning solution is back-diluted with a thinner to the viscosity required for spinning.
13. The method as claimed in claim 12 , wherein the thinner is an aqueous tertiary amine oxide.
14. The method of claim 1 , wherein the step of feeding the solution thereafter to the horizontal cylindrical thick-layer dissolver ( 4 ) results in dissolving, homogenization and concentration of the solution from the thin-film evaporator ( 2 ) in the thick-layer dissolver ( 4 ).
15. A device for carrying out the method as claimed in claim 1 , wherein the thin-film evaporator ( 2 ) and the thick-layer dissolver ( 4 ) are in direct communication with each other and, through evaporation lines from each of the thin-film evaporator ( 2 ) and the thick-layer dissolver ( 4 ), are in communication with a gas space connector ( 9 ).
16. The device as claimed in claim 15 , further comprising a condenser ( 10 ) in communication with the gas space connector ( 9 ).