IP Library Granted Patent US 10,359,076
Granted Patent B2
US 10,359,076 · App. 15/153,541 · Granted Jul 23, 2019

Method of forming a high strength low friction engineered material for bearings and other applications

Inventor: David Saxton (Ann Arbor, MI)
Assignee: Tenneco Inc
F16C33/145C25D3/30C25D3/38C25D5/10C25D7/00F16C33/04F16C33/1095F16C33/121F16C33/128F16C33/24F16C33/28B29C64/135B32B3/266B32B2307/746B33Y10/00B33Y80/00C23C18/32F16C2204/52Y10T156/10Y10T428/2462Y10T428/24322Y10T428/24331Y10T428/24339Y10T428/24942
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Quick Facts
Patent No.
US 10,359,076
App. No.
15/153,541
Granted
Jul 23, 2019
Kind
B2
Abstract

A method of forming an engineered material, for example a material for use in a bearing, is provided. The method includes forming a template polymer microlattice by disposing a perforated mask over a reservoir of ultra-violet (UV) curable resin in liquid form, conveying beams of light through the perforated mask and into the reservoir along paths, and transforming the liquid UV curable resin along the paths into a plurality of interconnected solid polymer fibers. The method further includes applying a metal material to the template polymer microlattice to form a microlattice of the metal material, and removing the template polymer microlattice from the metal microlattice. The method next includes disposing a low friction material in interstices of the metal microlattice, and sintering the low friction material disposed in the interstices of the metal microlattice.

Claims (45)

1. A method of forming an engineered material, comprising the steps of:

forming a template polymer microlattice by disposing a perforated mask over a reservoir of ultra-violet (UV) curable resin in liquid form, conveying beams of light through the perforated mask and into the reservoir along paths, and transforming the liquid UV curable resin along the paths into a plurality of interconnected solid polymer fibers;

the step of forming the template polymer microlattice being a continuous process and occurring at a rate greater than 1 mm 2 per minute;

applying a metal material to the template polymer microlattice to form a microlattice of the metal material, the metal microlattice presenting a plurality of interstices;

the step of applying the metal material to the template polymer microlattice including plating or electrodepositing the metal material onto the template polymer microlattice, and applying a greater amount of the metal material to one area of the template polymer microlattice relative to other areas of the template polymer microlattice;

the step of applying the metal material to the template polymer microlattice including forming a plurality of struts each surrounding one of the solid polymer fibers, the struts being interconnected to one another and presenting the plurality of interstices therebetween to form the metal microlattice;

removing the template polymer microlattice from the metal microlattice by heating the template polymer microlattice;

disposing a low friction material in the interstices of the metal microlattice, the low friction material having a coefficient of friction less than the coefficient of friction of the metal microlattice to form the engineered material; and

sintering the low friction material disposed in the interstices of the metal microlattice.

2. The method of claim 1 , wherein the metal microlattice is formed of nickel; the metal microlattice comprises a plurality of struts interconnected to one another and presenting the interstices; and each of the struts includes a hollow opening.

3. The method of claim 2 , wherein the metal microlattice is present in an amount of approximately 15 volume % and the interstices are present in an amount of approximately 85 volume %, based on the total volume of the metal microlattice and the interstices; and each of the struts is disposed at an angle of 50° to 90° relative to horizontal, has a diameter of about 50 micrometers, and a wall thickness of about 15 micrometers surrounding the hollow opening.

4. The method of claim 1 , wherein the low friction material includes at least one of polytetrafluoroethylene (PTFE), polyamide (PAI), polyetheretherketone (PEEK), polyethylene (PE), polyoxymethylene (POM), tin, and bismuth.

5. The method of claim 4 , wherein the low friction material includes particles selected from the group consisting of ceramic, graphite molybdenum disulfide, copper, and silver.

6. The method of claim 1 , wherein the step of disposing the low friction material in the interstices of the metal microlattice includes at least one of rolling and infiltrating the low friction material in the interstices.

7. The method of claim 1 , wherein the step of applying the metal material includes applying a plurality of layers formed of different metals; and heating the layers to alloy the different metals together.

8. The method of claim 1 , wherein the step of disposing a low friction material in the interstices of the metal microlattice includes filling the interstices of the metal microlattice.

9. The method of claim 1 , wherein the solid polymer fibers of the template polymer microlattice each extend at an angle of 50° to 90° relative to horizontal;

the struts of the metal microlattice each have a diameter of about 50 micrometers, a wall thickness of about 15 micrometers, and extend at an angle of 50° to 90° relative to horizontal;

the metal microlattice is present in an amount of approximately 15 volume percent and the interstices are present in an amount of approximately 85 volume percent, based on the total volume of the metal microlattice and the interstices;

the step of disposing the low friction material in the interstices of the metal microlattice includes at least one of rolling and infiltrating the low friction material into the interstices;

the low friction material includes at least one of polytetrafluoroethylene (PTFE), polyamide (PAI), polyetheretherketone (PEEK), polyethylene (PE), and polyoxymethylene (POM);

the low friction material includes particles selected from the group consisting of ceramic, graphite molybdenum disulfide, copper, and silver; and

the step of disposing the low friction material in the interstices of the metal microlattice includes filling the interstices.

10. A method of forming a bearing, comprising the steps of:

forming a template polymer microlattice by disposing a perforated mask over a reservoir of ultra-violet (UV) curable resin in liquid form, conveying beams of light through the perforated mask and into the reservoir along paths, and transforming the liquid UV curable resin along the paths into a plurality of interconnected solid polymer fibers;

the step of forming the template polymer microlattice being a continuous process and occurring at a rate greater than 1 mm 2 per minute;

applying a metal material to the template polymer microlattice to form a microlattice of the metal material, the metal microlattice presenting a plurality of interstices;

the step of applying the metal material to the template polymer microlattice including plating or electrodepositing the metal material onto the template polymer microlattice, and applying a greater amount of the metal material to one area of the template polymer microlattice relative to other areas of the template polymer microlattice,

the step of applying the metal material to the template polymer microlattice including forming a plurality of struts each surrounding one of the solid polymer fibers, the struts being interconnected to one another and presenting the plurality of interstices therebetween to form the metal microlattice;

removing the template polymer microlattice from the metal microlattice by heating the template polymer microlattice;

disposing a low friction material in the interstices of the metal microlattice, the low friction material having a coefficient of friction less than the coefficient of friction of the metal microlattice to form the engineered material; and

sintering the low friction material disposed in the interstices of the metal microlattice.

11. The method of claim 10 including attaching a backing to the engineered material.

12. The method of claim 10 , wherein the step of disposing the low friction material in the interstices of the metal microlattice includes at least one of rolling and infiltrating the low friction material in the interstices.

13. The method of claim 10 , wherein the step of applying the metal material includes applying a plurality of layers formed of different metals; and heating the layers to alloy the different metals together.

14. The method of claim 10 , wherein the step of disposing a low friction material in the interstices of the metal microlattice includes filling the interstices of the metal microlattice.

15. The method of claim 10 , wherein the metal microlattice is formed of nickel; the metal microlattice comprises a plurality of struts interconnected to one another and presenting the interstices; and each of the struts includes a hollow opening.

16. The method of claim 10 , wherein the low friction material includes at least one of polytetrafluoroethylene (PTFE), polyamide (PAI), polyetheretherketone (PEEK), polyethylene (PE), polyoxymethylene (POM), tin, and bismuth; and the low friction material includes particles selected from the group consisting of ceramic, graphite molybdenum disulfide, copper, and silver.

17. The method of claim 10 , wherein the solid polymer fibers of the template polymer microlattice each extend at an angle of 50° to 90° relative to horizontal;

the struts of the metal microlattice each have a diameter of about 50 micrometers, a wall thickness of about 15 micrometers, and extend at an angle of 50° to 90° relative to horizontal;

the metal microlattice is present in an amount of approximately 15 volume percent and the interstices are present in an amount of approximately 85 volume percent, based on the total volume of the metal microlattice and the interstices;

the step of disposing the low friction material in the interstices of the metal microlattice includes at least one of rolling and infiltrating the low friction material into the interstices;

the low friction material includes at least one of polytetrafluoroethylene (PTFE), polyamide (PAI), polyetheretherketone (PEEK), polyethylene (PE), and polyoxymethylene (POM);

the low friction material includes particles selected from the group consisting of ceramic, graphite molybdenum disulfide, copper, and silver; and

the step of disposing the low friction material in the interstices of the metal microlattice includes filling the interstices.

Assignments (18)
PATENT SECURITY AGREEMENT (ABL) Recorded Apr 7, 2023
From: TENNECO INC.; DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 063268/0506 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 22, 2022
From: DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 061989/0689 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 058392/0274 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 056886/0455 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
MERGER AND CHANGE OF NAME Recorded Jun 12, 2019
From: FEDERAL-MOGUL LLC; TENNECO INC.
To: TENNECO INC.
Reel/Frame 049444/0386 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0771 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT AGREEMENT Recorded Apr 3, 2018
From: CITIBANK, N.A., AS COLLATERAL TRUSTEE
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0765 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Sep 26, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, LLC
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 044013/0419 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Jun 23, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, INC.
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 042963/0662 →
CHANGE OF NAME Recorded Mar 28, 2017
From: FEDERAL-MOGUL CORPORATION
To: FEDERAL-MOGUL LLC
Reel/Frame 042107/0565 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 12, 2016
From: SAXTON, DAVID
To: FEDERAL-MOGUL CORPORATION
Reel/Frame 039128/0460 →
Continuity (4)
Division 14085181 · Nov 20, 2013
Provisional Application 61815480 · Apr 24, 2013
Provisional Application 61728315 · Nov 20, 2012
Related Publication 20160258486A1 · Sep 8, 2016