High entropy alloy having TWIP/TRIP property and manufacturing method for the same
The present invention relates to a high entropy alloy having more improved mechanical properties by controlling contents of additive elements in a NiCoFeMnCr 5-element alloy to control stacking fault energy, thereby controlling stability of a γ austenite phase to control a transformation mechanism, wherein the stacking fault energy is controlled in a composition range of Ni a Co b Fe c Mn d Cr e (a+b+c+d+e=100, 1≤a≤50, 1≤b≤50, 1≤c≤50, 1≤d≤50, 10≤e≤25, and 77a−42b−22c+73d−100e+2186≤1500), and thus, the γ austenite phase exhibits a twin-induced plasticity (TWIP) property or a transformation induced-plasticity (TRIP) property in which the γ austenite phase is subjected to phase transformation into an ε martensite phase or an α′ martensite phase, under stress, thereby having improved strength and elongation at the same time to have excellent mechanical properties.
1. A high entropy alloy having TWIP (twin induced plasticity)/TRIP (transformation induced plasticity) property, which is represented by the following Chemical Formula:
Ni a Co b Fe c Mn d Cr e [Chemical Formula]
(a+b+c+d+e=100, 1≤a≤50, 1≤b≤50, 1≤c≤50, 17.5≤d≤50, 10≤e≤25, and 77a−42b−22c+73d−100e+2186≤1500).
2. The high entropy alloy having TWIP/TRIP property of claim 1 , wherein:
the high entropy alloy includes 10 at. % or less of at least one element of C, N, Al, Ti, V, Cu, Zr, Nb, or Mo.
3. The high entropy alloy having TWIP/TRIP property of claim 1 , wherein:
in Chemical Formula above, 77a−42b−22c+73d−100e+2186≤500.
4. The high entropy alloy having TWIP/TRIP property of claim 1 , wherein:
in Chemical Formula above, 77a−42b−22c+73d−100e+2186≤200.
5. The high entropy alloy having TWIP/TRIP property of claim 1 , wherein:
the high entropy alloy includes a γ austenite single phase.
6. The high entropy alloy having TWIP/TRIP property of claim 1 , wherein:
the high entropy alloy simultaneously includes a γ austenite phase and an ε martensite phase.
7. The high entropy alloy having TWIP/TRIP property of claim 1 , wherein:
a γ austenite phase in the high entropy alloy is subjected to multi-stage phase transformation into an α′ martensite phase through an ε martensite phase during strain.
8. The high entropy alloy having TWIP/TRIP property of claim 1 , wherein:
a free energy change (ΔG hcp-fcc ) when a γ austenite phase in the high entropy alloy is phase-transformed into an ε martensite phase during strain is 1500 J/mol or less.
9. The high entropy alloy having TWIP/TRIP property of claim 8 , wherein:
when the free energy change (ΔG hcp-fcc ) is 1500 J/mol or less, the high entropy alloy exhibits the TWIP property, and when the free energy change (ΔG hcp-fcc ) is 500 J/mol or less, the high entropy alloy exhibits the TRIP property.
10. The high entropy alloy having TWIP/TRIP property of claim 8 , wherein:
when the free energy change (ΔG hcp-fcc ) is 200 J/mol or less, the high entropy alloy simultaneously includes the γ austenite phase and the ε martensite phase.
11. The high entropy alloy having TWIP/TRIP property of claim 8 , wherein:
the free energy change (ΔG hcp-fcc ) is 500 J/mol or less, and a free energy change (ΔG hcp-fcc ) at the time of phase transformation when the γ austenite phase in the high entropy alloy is phase-transformed into the α′ martensite phase is −2500 J/mol or less to −5000 J/mol or more.
12. A high entropy alloy having TWIP (twin induced plasticity)/TRIP (transformation induced plasticity) property, which is represented by the following Chemical Formula:
Ni a Co b Fe c Mn d Cr e [Chemical Formula]
(a+b+c+d+e=100, 1≤a≤7, 32≤b≤50, 32≤c≤50, 1≤d≤7, 15≤e≤25, and 77a−42b−22c+73d−100e+2186≤1500).
13. A manufacturing method for a high entropy alloy having TWIP (twin induced plasticity)/TRIP (transformation induced plasticity) property comprising:
preparing a raw material; and
manufacturing the high entropy alloy by alloying the raw material,
wherein in the preparing of the raw material, the raw material is prepared to satisfy the following Chemical Formula, and
a free energy change (ΔG hcp-fcc ) when a γ austenite phase (fcc) in the manufactured high entropy alloy is phase-transformed into an ε martensite phase (hcp) is 1500 J/mol or less:
Ni a Co b Fe c Mn d Cr e [Chemical Formula]
(a+b+c+d+e=100, 1≤a≤50, 1≤b≤50, 1≤c≤50, 17.5≤d≤50, 10≤e≤25, and 77a−42b−22c+73d−100e+2186≤1500).
14. The manufacturing method of claim 13 , further comprising:
after the manufacturing of the high entropy alloy, performing homogenization treatment by hot rolling a manufactured ingot to 80% or less of an original thickness, and annealing in an Ar atmosphere at 1200±300° C. for 48 hours or less, followed by quenching.
15. The manufacturing method of claim 14 , further comprising:
controlling a microstructure size of the high entropy alloy by cold rolling the homogenized high entropy alloy to 10% or more of an original thickness, and annealing in an Ar atmosphere at 900±200° C. for 24 hours or less, followed by quenching.
16. The manufacturing method of claim 13 , wherein:
the free energy change (ΔG hcp-fcc ) is 500 J/mol or less.
17. The manufacturing method of claim 13 , wherein:
the free energy change (ΔG hcp-fcc ) is 200 J/mol or less.
18. The manufacturing method of claim 13 , wherein:
a free energy change (ΔG bcc-fcc ) at the time of phase transformation when the γ austenite phase in the high entropy alloy is phase-transformed into an α′ martensite phase is −2500 J/mol or less to −5000 J/mol or more.