Reactors and systems for oxidative coupling of methane
In an aspect, the present disclosure provides a method for the oxidative coupling of methane to generate hydrocarbon compounds containing at least two carbon atoms (C 2+ compounds). The method can include mixing a first gas stream comprising methane with a second gas stream comprising oxygen to form a third gas stream comprising methane and oxygen and performing an oxidative coupling of methane (OCM) reaction using the third gas stream to produce a product stream comprising one or more C 2+ compounds.
1. A process for production of hydrocarbons, the process comprising the steps of:
converting at least a feed stream comprising methane (CH 4 ) and oxygen (O 2 ) feed into a conversion effluent by oxidative coupling of methane (OCM);
directing said conversion effluent to at least one product retrieval stage to produce one or more product streams and a remaining conversion effluent;
directing at least a portion of said remaining conversion effluent to a hydrogenation stage to produce a hydrogenation effluent, and directing said hydrogenation effluent to a methanation stage to produce a recycle stream; and
adding at least part of said recycle stream to said feed stream.
2. The method of claim 1 , wherein said hydrogenation stage and methanation stage are comprised in a recycle loop.
3. The process according to claim 2 , wherein said recycle loop further comprises a CO 2 addition stage.
4. The process according to claim 1 , wherein CO 2 is added upstream said methanation step at said CO 2 addition stage and/or directly into said methanation stage.
5. The process according to claim 1 , wherein H 2 O is at least partially removed upstream and/or downstream one or more of said product retrieval steps.
6. The process according to claim 2 , wherein said recycle loop comprises a pre-methanation step.
7. The process according to claim 6 , wherein CO, CO 2 is pre-methanated and/or higher alkanes are reformed in said pre-methanation step.
8. The process according to claim 6 , wherein said pre-methanation step is carried out at T<400° C. or >400° C.
9. The process according to claim 6 , wherein at least part of effluent from said pre-methanation is recycled to upstream said pre-methanation step.
10. The process according to claim 1 , wherein said one or more product streams obtained at said one or more product retrieval stages comprise ethylene, CO 2 , aromatics and/or raw gasoline.
11. The process according to claim 1 , wherein said recycle stream comprises 90-99% CH 4 .
12. The process according to claim 1 , wherein said recycle stream comprises H 2 and/or CO at a concentration below 5%, below 1%, below 0.5%, such as below 10 ppm when added to said feed stream.
13. The process according to claim 1 , wherein said one or more product streams is obtained by separation from said conversion effluent through pressure swing adsorption, condensation, N 2 wash and/or distillation or other separation technologies.
14. The process according to claim 6 , wherein said pre-methanation step is carried out over a nickel-based catalyst at a pressure between 0.1 and 80 bars.
15. The process according to claim 1 , wherein said methanation stage is carried out over a nickel-based catalyst at a pressure between 0.1 and 80 bars.
16. The process according to claim 1 , wherein said methanation stage is carried out at T<400° C. or T>400° C., depending on if said unsaturated hydrogenation is desired or not.
17. The process according to claim 6 , wherein said hydrogenation, pre-methanation and/or methanation is carried out in a boiling water reactor preferably in a single boiling water reactor.
18. A method for producing hydrocarbon compounds, comprising:
(a) directing a feed stream comprising methane (CH 4 ) and an oxidizing agent into an oxidative coupling of methane (OCM) unit to generate from at least a portion of said CH 4 and said oxidizing agent an OCM effluent comprising said hydrocarbon compounds;
(b) recovering a portion of said OCM effluent in one or more product streams;
(c) directing an additional portion of said OCM effluent into a recycle loop that comprises (i) a hydrogenation unit that hydrogenates at least a portion of unsaturated hydrocarbons from said additional portion of said OCM effluent, and (ii) a methanation unit that reacts hydrogen (H 2 ) with carbon monoxide (CO) or carbon dioxide (CO 2 ) from said additional portion of said OCM effluent in a methanation reaction to form CH 4 , wherein said recycle loop outputs a recycle stream comprising said CH 4 generated by said methanation unit; and
(d) directing at least a portion of said recycle stream into said OCM unit.
19. The method of claim 18 , wherein said one or more product streams comprise ethylene (C 2 H 4 ), CO 2 , and/or hydrocarbon compounds having three or more carbon atoms (C 3+ compounds).
20. The method of claim 18 , further comprising directing a CO 2 stream into said methanation unit.
21. The method of claim 18 , further comprising removing water from said OCM effluent.
22. The method of claim 18 , further comprising reducing a concentration of hydrocarbon compounds having carbon-carbon double bonds or triple bonds in said OCM effluent prior to said methanation reaction.
23. The method of claim 18 , wherein said recycle stream comprises at least about 90% CH 4 .
24. The method of claim 18 , wherein said one or more product streams are recovered using pressure swing adsorption (PSA), condensation, and/or membrane separation.
25. The method of claim 18 , further comprising removing water from said recycle stream prior to (d).
26. The method of claim 25 , wherein at least about 70% of said water is removed from said recycle stream.
27. The method of claim 18 , wherein said additional portion of said OCM effluent is a part of said portion of said OCM effluent.
28. The method of claim 18 , wherein said methanation unit comprises a catalyst comprising one or more of ruthenium, cobalt, nickel and iron.
29. The method of claim 18 , wherein said methanation unit operates at a pressure between about 2 bar (absolute) and 60 bar, and a temperature between about 150° C. and about 400° C.
30. The method of claim 18 , wherein said carbon efficiency is at least about 50%.