Heterocyclic compound and organic light emitting element comprising same
The present specification provides a heterocyclic compound and an organic light emitting device including the same.
1. A compound represented by any one of the following Chemical Formula 2 to Chemical Formula 4:
wherein, in Chemical Formula 2 to Chemical Formula 4,
L is a direct bond; a substituted or unsubstituted arylene group; or a substituted or unsubstituted heteroarylene group;
X 1 to X 6 are N or CH;
at least one of X 1 to X 3 is N;
at least one of X 4 to X 6 is N; and
Z 1 to Z 4 are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a nitrile group; a nitro group; a hydroxyl group; a carbonyl group; an ester group; an imide group; an amino group; a substituted or unsubstituted silyl group; a substituted or unsubstituted boron group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted alkoxy group; a substituted or unsubstituted heteroarylamine group; a substituted or unsubstituted arylamine group; a substituted or unsubstituted arylphosphine group; a substituted or unsubstituted phosphine oxide group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heterocyclic group.
2. The compound of claim 1 , wherein the compound of Chemical Formula 2 is represented by any one of the following Chemical Formula 5 to Chemical Formula 8:
wherein, in Chemical Formula 5 to Chemical Formula 8,
definitions of L, X 1 to X 6 and Z 1 to Z 4 are the same as in Chemical Formula 2.
3. The compound of claim 1 , wherein the compound of Chemical Formula 3 is represented by any one of the following Chemical Formula 9 to Chemical Formula 12:
wherein, in Chemical Formula 9 to Chemical Formula 12,
definitions of L, X 1 to X 3 , Z 1 and Z 2 are the same as in Chemical Formula 3.
4. The compound of claim 1 , wherein the compound of Chemical Formula 4 is represented by any one of the following Chemical Formula 13 to Chemical Formula 16:
wherein, in Chemical Formula 13 to Chemical Formula 16,
definitions of L, X 4 to X 6 , Z 3 and Z 4 are the same as in Chemical Formula 4.
5. A compound selected from among the following structures:
6. An organic light emitting device comprising:
a first electrode;
a second electrode; and
one or more organic material layers disposed between the first electrode and the second electrode,
wherein one or more layers of the organic material layers comprise the compound of claim 1 .
7. The organic light emitting device of claim 6 , wherein the organic material layer comprises at least one layer of an electron injection layer and an electron transfer layer, and one or more layers of the layers comprise the compound.
8. The organic light emitting device of claim 6 , wherein the organic material layer comprises a light emitting layer, and the light emitting layer comprises the compound as a host of the light emitting layer.
9. The organic light emitting device of claim 6 , wherein the organic material layer comprises one or more layers of a hole injection layer, a hole transfer layer, and a layer carrying out hole injection and hole transfer at the same time, and one or more layers of the layers comprise the compound.
10. The organic light emitting device of claim 6 , wherein the organic material layer comprises the compound as a host, and comprises other organic compounds, metals or metal compounds as a dopant.
11. The organic light emitting device of claim 6 , wherein the organic material layer comprises a light emitting layer, and the light emitting layer comprises a compound represented by the following Chemical Formula 17:
wherein, in Chemical Formula 17,
r is an integer of 1 or greater;
Ar1 is a substituted or unsubstituted monovalent or higher benzofluorene group; a substituted or unsubstituted monovalent or higher fluoranthene group; a substituted or unsubstituted monovalent or higher pyrene group; or a substituted or unsubstituted monovalent or higher chrysene group;
L1 is a direct bond; a substituted or unsubstituted arylene group; or a substituted or unsubstituted heteroarylene group;
Ar2 and Ar3 are the same as or different from each other, and each independently a substituted or unsubstituted aryl group; a substituted or unsubstituted silyl group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted arylalkyl group; or a substituted or unsubstituted heteroaryl group, or may bond to each other to form a substituted or unsubstituted ring; and
when r is 2 or greater, the structures in the parentheses are the same as or different from each other.
12. The organic light emitting device of claim 11 , wherein L1 is a direct bond, Ar1 is a substituted or unsubstituted divalent pyrene group, Ar2 and Ar3 are the same as or different from each other and each independently an aryl group, and r is 2.